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Incommensurate broken helix induced by nonstoichiometry in the axion insulator candidate EuIn2As2

Masaki Gen1,2,*, Yukako Fujishiro1,3, Kazuki Okigami4, Satoru Hayami5, Max T. Birch1, Kiyohiro Adachi6, Daisuke Hashizume6, Takashi Kurumaji7,8, Hajime Sagayama9 et al.

Hironori Nakao9, Yoshinori Tokura1,3,10, and Taka-hisa Arima1,7

  • *Contact author: gen@issp.u-tokyo.ac.jp

Phys. Rev. B 111, L081109 – Published 18 February, 2025

DOI: https://doi.org/10.1103/PhysRevB.111.L081109

Abstract

Zintl phase EuIn2As2 has garnered growing attention as an axion insulator candidate, triggered by the identification of a commensurate double-Q broken-helix state in previous studies, however, its periodicity and symmetry remain subjects of debate. Here, we perform resonant x-ray scattering experiments on EuIn2As2, revealing an incommensurate nature of the broken-helix state, where both the wave number and the amplitude of the helical modulation exhibit systematic sample dependence. Furthermore, the application of an in-plane magnetic field brings about a fanlike state that appears to preserve the double-Q nature, which might be attributed to multiple-spin interactions in momentum space. We propose that the itinerant character of EuIn2As2, most likely induced by Eu deficiency, gives rise to the helical modulation and impedes the realization of a theoretically predicted axion state with the collinear antiferromagnetic order.

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