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Universally nondiverging Grüneisen parameter at critical points

Samuel M. Soares1, Lucas Squillante1, Henrique S. Lima2, Constantino Tsallis3,4,5, and Mariano de Souza1,6,*

  • *Contact author: mariano.souza@unesp.br

Phys. Rev. B 111, L060409 – Published 26 February, 2025

DOI: https://doi.org/10.1103/PhysRevB.111.L060409

Abstract

According to Boltzmann-Gibbs (BG) statistical mechanics, the thermodynamic response, such as the isothermal susceptibility, at critical points (CPs) presents a divergent-like behavior. An appropriate parameter to probe both classical and quantum CPs is the so-called Grüneisen ratio Γ. Motivated by the results reported in [Phys. Rev. B 108, L140403 (2023)], we extend the quantum version of Γ to the nonadditive q-entropy Sq. Our findings indicate that using Sq at the unique value of q restoring the extensivity of the entropy, Γ is universally nondiverging at CPs. We unprecedentedly introduce Γ in terms of Sq, being BG recovered for q→1. We thus solve a long-standing problem related to the illusory diverging susceptibilities at CPs.

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