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    Disorder-induced spin excitation continuum and spin-glass ground state in the inverse spinel CuGa2O4

    Zhentao Huang1,*, Zhijun Xu2,*, Shuaiwei Li3, Qingchen Duan4, Junbo Liao1, Song Bao1, Yanyan Shangguan1, Bo Zhang1, Hao Xu1 et al.

    Shufan Cheng1, Zihang Song1, Shuai Dong1, Maofeng Wu1, M. B. Stone5, Yiming Qiu2, Ruidan Zhong4, Guangyong Xu2, Zhen Ma1,3,†, G. D. Gu6,‡, J. M. Tranquada6,§, and Jinsheng Wen1,7,∥

    • *These authors contributed equally to this work.
    • †Contact author: zma@hbnu.edu.cn
    • ‡Contact author: ggu@bnl.gov
    • §Contact author: jtran@bnl.gov
    • ∥Contact author: jwen@nju.edu.cn

    Phys. Rev. B 112, 035128 – Published 10 July, 2025

    DOI: https://doi.org/10.1103/1xtf-wg3q

    Abstract

    Spinel-structured compounds serve as prototypical examples of highly frustrated systems and are promising candidates for realizing the long-sought quantum spin liquid (QSL) state. However, structural disorder is inevitable in many real QSL candidates and its impact remains a topic of intense debate. In this work, we conduct comprehensive investigations on CuGa2O4, a spinel compound with significant structural disorder, focusing on its thermodynamic properties and spectroscopic behaviors. No long-range magnetic order is observed down to ∼80 mK, as evidenced by magnetic susceptibility, specific-heat, and elastic neutron scattering measurements. More intriguingly, inelastic neutron scattering experiments reveal a broad gapless continuum of magnetic excitations around the Brillouin zone boundary, resembling the magnetic excitation spectra expected for a QSL. Nevertheless, a spin-freezing transition at Tf≈0.88 K is identified from the cusp in the dc susceptibility curves, where a bifurcation between zero-field-cooling and field-cooling curves occurs. Furthermore, ac susceptibility measurements show a peak close to Tf at low frequency, which shifts to higher temperature with increasing frequency. These results show that CuGa2O4 has a spin-glass ground state, consistent with the establishment of short-range order inferred from the specific-heat measurements. Collectively, these results illustrate the crucial role of disorder in defining the excitation spectrum out of the disordered ground state. Our findings shed light onto the broader class of AB2O4 spinels and advance our understanding of the spin dynamics in magnetically disordered systems.

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