- Open Access
Synchronous manipulation of nuclear spins via boron-vacancy centers in hexagonal boron nitride
Phys. Rev. Applied 24, 024036 – Published 14 August, 2025
DOI: https://doi.org/10.1103/vlqs-h75g
Abstract
We develop a method for entangling operations on nuclear spins surrounding a negatively charged boron-vacancy (V-center) point defect in hexagonal boron nitride (h). To this end, we propose to employ the electron spin of a V center as a control qubit. We show that, in the presence of a background magnetic field and by applying control pulses, one can collectively manipulate the state of the nuclei with and rotations. These rotations can serve for implementing the synchronous three-qubit , , and Hadamard gates. Through our numerical analyses considering realistic system parameters and decoherence effects, we demonstrate that these gates can be executed with high fidelities. Furthermore, as an example for the application of our toolbox, we use these collective gates to prepare the highly entangled Greenberger-Horne-Zeilinger states among the three nuclear spins with a fidelity of 0.99. By including electron decoherence effects, we find that the relative deviations of the gate fidelities from the noisy terms are negligibly small, demonstrating the noise resilience of our protocols. Our work can serve as the foundation for exploiting the nuclear spins in h in future quantum technological applications.
Physics Subject Headings (PhySH)
Article Text
References (76)
- J. J. L. Morton, A. M. Tyryshkin, R. M. Brown, S. Shankar, B. W. Lovett, A. Ardavan, T. Schenkel, E. E. Haller, J. W. Ager, and S. A. Lyon, Solid-state quantum memory using the nuclear spin, Nature 455, 1085 (2008).
- D. R. McCamey, J. Van Tol, G. W. Morley, and C. Boehme, Electronic spin storage in an electrically readable nuclear spin memory with a lifetime s, Science 330, 1652 (2010).
- J. T. Muhonen, J. P. Dehollain, A. Laucht, F. E. Hudson, R. Kalra, T. Sekiguchi, K. M. Itoh, D. N. Jamieson, J. C. McCallum, A. S. Dzurak, and A. Morello, Storing quantum information for 30 seconds in a nanoelectronic device, Nat. Nanotechnol. 9, 986 (2014).
- W. M. Witzel and S. Das Sarma, Nuclear spins as quantum memory in semiconductor nanostructures, Phys. Rev. B 76, 045218 (2007).
- M. J. A. Schuetz, E. M. Kessler, L. M. K. Vandersypen, J. I. Cirac, and G. Giedke, Nuclear spin dynamics in double quantum dots: Multistability, dynamical polarization, criticality, and entanglement, Phys. Rev. B 89, 195310 (2014).
- X. Rong, J. Geng, F. Shi, Y. Liu, K. Xu, W. Ma, F. Kong, Z. Jiang, Y. Wu, and J. Du, Experimental fault-tolerant universal quantum gates with solid-state spins under ambient conditions, Nat. Commun. 6, 8748 (2015).
- M. H. Abobeih, Y. Wang, J. Randall, S. J. H. Loenen, C. E. Bradley, M. Markham, D. J. Twitchen, B. M. Terhal, and T. H. Taminiau, Fault-tolerant operation of a logical qubit in a diamond quantum processor, Nature 606, 884 (2022).
- E. V. Denning, D. A. Gangloff, M. Atature, J. Mork, and C. Le Gall, Collective quantum memory activated by a driven central spin, Phys. Rev. Lett. 123, 140502 (2019).
- S. K. Parthasarathy, B. Kallinger, F. Kaiser, P. Berwian, D. B. Dasari, J. Friedrich, and R. Nagy, Scalable quantum memory nodes using nuclear spins in silicon carbide, Phys. Rev. Appl. 19, 034026 (2023).
- N. Zhao, J.-L. Hu, S.-W. Ho, J. T. K. Wan, and R. B. Liu, Atomic-scale magnetometry of distant nuclear spin clusters via nitrogen-vacancy spin in diamond, Nat. Nanotechnol. 6, 242 (2011).
- S. Kolkowitz, Q. P. Unterreithmeier, S. D. Bennett, and M. D. Lukin, Sensing distant nuclear spins with a single electron spin, Phys. Rev. Lett. 109, 137601 (2012).
- T. H. Taminiau, J. J. T. Wagenaar, T. van der Sar, F. Jelezko, V. V. Dobrovitski, and R. Hanson, Detection and control of individual nuclear spins using a weakly coupled electron spin, Phys. Rev. Lett. 109, 137602 (2012).
- B. Smeltzer, J. McIntyre, and L. Childress, Robust control of individual nuclear spins in diamond, Phys. Rev. A 80, 050302 (2009).
- L. Busaite, R. Lazda, A. Berzins, M. Auzinsh, R. Ferber, and F. Gahbauer, Dynamic nuclear spin polarization in nitrogen-vacancy centers in diamond, Phys. Rev. B 102, 224101 (2020).
- Q. Chen, I. Schwarz, and M. B. Plenio, Dissipatively stabilized quantum sensor based on indirect nuclear-nuclear interactions, Phys. Rev. Lett. 119, 010801 (2017).
- J. F. Haase, Z.-Y. Wang, J. Casanova, and M. B. Plenio, Soft quantum control for highly selective interactions among joint quantum systems, Phys. Rev. Lett. 121, 050402 (2018).
- M. A. Perlin, Z.-Y. Wang, J. Casanova, and M. B. Plenio, Noise-resilient architecture of a hybrid electron-nuclear quantum register in diamond, Quantum Sci. Technol. 4, 015007 (2018).
- M. H. Abobeih, J. Randall, C. E. Bradley, H. P. Bartling, M. A. Bakker, M. J. Degen, M. Markham, D. J. Twitchen, and T. H. Taminiau, Atomic-scale imaging of a 27-nuclear-spin cluster using a quantum sensor, Nature 576, 411 (2019).
- M. L. Goldman, T. L. Patti, D. Levonian, S. F. Yelin, and M. D. Lukin, Optical control of a single nuclear spin in the solid state, Phys. Rev. Lett. 124, 153203 (2020).
- B. Tratzmiller, J. F. Haase, Z. Wang, and M. B. Plenio, Parallel selective nuclear-spin addressing for fast high-fidelity quantum gates, Phys. Rev. A 103, 012607 (2021).
- V. V. Soshenko, S. V. Bolshedvorskii, O. Rubinas, V. N. Sorokin, A. N. Smolyaninov, V. V. Vorobyov, and A. V. Akimov, Nuclear spin gyroscope based on the nitrogen vacancy center in diamond, Phys. Rev. Lett. 126, 197702 (2021).
- J. Jiang and Q. Chen, Selective nuclear-spin interaction based on a dissipatively stabilized nitrogen-vacancy center, Phys. Rev. A 105, 042426 (2022).
- C. Munuera-Javaloy, A. Tobalina, and J. Casanova, High-resolution NMR spectroscopy at large fields with nitrogen vacancy centers, Phys. Rev. Lett. 130, 133603 (2023).
- K. Zeng, X. Yu, M. B. Plenio, and Z.-Y. Wang, Wide-band unambiguous quantum sensing via geodesic evolution, Phys. Rev. Lett. 132, 250801 (2024).
- S. Xu, C. Xie, and Z.-Y. Wang, Enhancing electron-nuclear resonances by dynamical control switching, Phys. Rev. A 109, L020601 (2024).
- K. Mizuno, I. Fujisaki, H. Tomioka, H. Ishiwata, S. Onoda, T. Iwasaki, K. Arai, and M. Hatano, Fast coherent control of nitrogen-14 spins associated with nitrogen-vacancy centers in diamonds using dynamical decoupling, J. Phys. Commun. 8, 035002 (2024).
- H. Bartling, J. Yun, K. Schymik, M. van Riggelen, L. Enthoven, H. van Ommen, M. Babaie, F. Sebastiano, M. Markham, D. Twitchen, and T. Taminiau, Universal high-fidelity quantum gates for spin qubits in diamond, Phys. Rev. Appl. 23, 034052 (2025).
- T. Jaeger, M. Kwon, M. Keller, R. Maier, N. Bronn, R. Finsterhoelzl, G. Burkard, L. Buettner, R. Eberle, D. Haehnel, V. Vorobyov, and J. Wrachtrup, Modeling quantum volume using randomized benchmarking of room-temperature V center quantum registers, ArXiv:2412.12959.
- D. Dulog and M. B. Plenio, Towards quantum error correction with two-body gates for quantum registers based on nitrogen-vacancy centers in diamond, ArXiv:2411.18450.
- W. Lee, V. Liu, Z. Zhang, S. Kim, R. Gong, X. Du, K. Pham, T. Poirier, Z. Hao, J. Edgar, P. Kim, C. Zu, E. Davis, and N. Yao, Intrinsic high-fidelity spin polarization of charged vacancies in hexagonal boron nitride, Phys. Rev. Lett. 134, 096202 (2025).
- T. T. Tran, K. Bray, M. J. Ford, M. Toth, and I. Aharonovich, Quantum emission from hexagonal boron nitride monolayers, Nat. Nanotechnol. 11, 37 (2015).
- A. Gottscholl, M. Diez, V. Soltamov, C. Kasper, A. Sperlich, M. Kianinia, C. Bradac, I. Aharonovich, and V. Dyakonov, Room temperature coherent control of spin defects in hexagonal boron nitride, Sci. Adv. 7, eabf3630 (2021).
- H. L. Stern, Q. Gu, J. Jarman, S. Eizagirre Barker, N. Mendelson, D. Chugh, S. Schott, H. H. Tan, H. Sirringhaus, I. Aharonovich, and M. Atatüre, Room-temperature optically detected magnetic resonance of single defects in hexagonal boron nitride, Nat. Commun. 13, 618 (2022).
- Z. Mu, H. Cai, D. Chen, J. Kenny, Z. Jiang, S. Ru, X. Lyu, T. S. Koh, X. Liu, I. Aharonovich, and W. Gao, Excited-state optically detected magnetic resonance of spin defects in hexagonal boron nitride, Phys. Rev. Lett. 128, 216402 (2022).
- M. Abdi, J.-P. Chou, A. Gali, and M. B. Plenio, Color centers in hexagonal boron nitride monolayers: A group theory and ab initio analysis, ACS Photonics 5, 1967 (2018).
- A. Sajid, M. J. Ford, and J. R. Reimers, Single-photon emitters in hexagonal boron nitride: A review of progress, Rep. Prog. Phys. 83, 044501 (2020).
- A. Gottscholl, M. Kianinia, V. Soltamov, S. Orlinskii, G. Mamin, C. Bradac, C. Kasper, K. Krambrock, A. Sperlich, M. Toth, I. Aharonovich, and V. Dyakonov, Initialization and read-out of intrinsic spin defects in a van der Waals crystal at room temperature, Nat. Mater. 19, 540 (2020).
- A. Çakan, C. Cholsuk, A. Gale, M. Kianinia, S. Paçal, S. Ateş, I. Aharonovich, M. Toth, and T. Vogl, Quantum optics applications of hexagonal boron nitride defects, Adv. Opt. Mater. 13, 2402508 (2025).
- G. Wolfowicz, F. J. Heremans, C. P. Anderson, S. Kanai, H. Seo, A. Gali, G. Galli, and D. D. Awschalom, Quantum guidelines for solid-state spin defects, Nat. Rev. Mater. 6, 906 (2021).
- N. Chejanovsky, M. Rezai, F. Paolucci, Y. Kim, T. Rendler, W. Rouabeh, F. Fávaro de Oliveira, P. Herlinger, A. Denisenko, S. Yang, I. Gerhardt, A. Finkler, J. H. Smet, and J. Wrachtrup, Structural attributes and photodynamics of visible spectrum quantum emitters in hexagonal boron nitride, Nano Lett. 16, 7037 (2016).
- N. V. Proscia, Z. Shotan, H. Jayakumar, P. Reddy, C. Cohen, M. Dollar, A. Alkauskas, M. Doherty, C. A. Meriles, and V. M. Menon, Near-deterministic activation of room-temperature quantum emitters in hexagonal boron nitride, Optica 5, 1128 (2018).
- A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature, Nat. Commun. 10, 222 (2019).
- F. T. Tabesh, Q. Hassanzada, M. Hadian, A. Hashemi, I. Abdolhosseini Sarsari, and M. Abdi, Strain induced coupling and quantum information processing with hexagonal boron nitride quantum emitters, Quantum Sci. Technol. 7, 015002 (2021).
- X. Liu and M. C. Hersam, 2D materials for quantum information science, Nat. Rev. Mater. 4, 669 (2019).
- M. Abdi, Continuous-variable multipartite vibrational entanglement, Phys. Rev. A 103, 043520 (2021).
- M. Kianinia, S. White, J. E. Fröch, C. Bradac, and I. Aharonovich, Generation of spin defects in hexagonal boron nitride, ACS Photonics 7, 2147 (2020).
- A. B. Shaik and P. Palla, Optical quantum technologies with hexagonal boron nitride single photon sources, Sci. Rep. 11, 12285 (2021).
- X. Gao, B. Jiang, A. E. Llacsahuanga Allcca, K. Shen, M. A. Sadi, A. B. Solanki, P. Ju, Z. Xu, P. Upadhyaya, Y. P. Chen, S. A. Bhave, and T. Li, High-contrast plasmonic-enhanced shallow spin defects in hexagonal boron nitride for quantum sensing, Nano Lett. 21, 7708 (2021).
- N. Mendelson, R. Ritika, M. Kianinia, J. Scott, S. Kim, J. E. Fröch, C. Gazzana, M. Westerhausen, L. Xiao, S. S. Mohajerani, S. Strauf, M. Toth, I. Aharonovich, and Z. Xu, Coupling spin defects in a layered material to nanoscale plasmonic cavities, Adv. Mater. 34, 2106046 (2021).
- N.-J. Guo, W. Liu, Z.-P. Li, Y.-Z. Yang, S. Yu, Y. Meng, Z.-A. Wang, X.-D. Zeng, F.-F. Yan, Q. Li, J.-F. Wang, J.-S. Xu, Y.-T. Wang, J.-S. Tang, C.-F. Li, and G.-C. Guo, Generation of spin defects by ion implantation in hexagonal boron nitride, ACS Omega 7, 1733 (2022).
- S. Vaidya, X. Gao, S. Dikshit, I. Aharonovich, and T. Li, Quantum sensing and imaging with spin defects in hexagonal boron nitride, Adv. Phys.: X 8, 2206049 (2023).
- S. Das, A. L. Melendez, I.-H. Kao, J. A. García-Monge, D. Russell, J. Li, K. Watanabe, T. Taniguchi, J. H. Edgar, J. Katoch, F. Yang, P. C. Hammel, and S. Singh, Quantum sensing of spin dynamics using boron-vacancy centers in hexagonal boron nitride, Phys. Rev. Lett. 133, 166704 (2024).
- D. Wong, J. Velasco, L. Ju, J. Lee, S. Kahn, H.-Z. Tsai, C. Germany, T. Taniguchi, K. Watanabe, A. Zettl, F. Wang, and M. F. Crommie, Characterization and manipulation of individual defects in insulating hexagonal boron nitride using scanning tunnelling microscopy, Nat. Nanotechnol. 10, 949 (2015).
- V. Ivády, G. Barcza, G. Thiering, S. Li, H. Hamdi, J.-P. Chou, O. Legeza, and A. Gali, Ab initio theory of the negatively charged boron vacancy qubit in hexagonal boron nitride, npj Comput. Mater. 6, 41 (2020).
- X. Gao, S. Vaidya, K. Li, P. Ju, B. Jiang, Z. Xu, A. E. L. Allcca, K. Shen, T. Taniguchi, K. Watanabe, S. A. Bhave, Y. P. Chen, Y. Ping, and T. Li, Nuclear spin polarization and control in hexagonal boron nitride, Nat. Mater. 21, 1024 (2022).
- F. T. Tabesh, M. Fani, J. S. Pedernales, M. B. Plenio, and M. Abdi, Active hyperpolarization of the nuclear spin lattice: Application to hexagonal boron nitride color centers, Phys. Rev. B 107, 214307 (2023).
- F. F. Murzakhanov, G. V. Mamin, S. B. Orlinskii, U. Gerstmann, W. G. Schmidt, T. Biktagirov, I. Aharonovich, A. Gottscholl, A. Sperlich, V. Dyakonov, and V. A. Soltamov, Electron–nuclear coherent coupling and nuclear spin readout through optically polarized -spin states in h, Nano Lett. 22, 2718 (2022).
- M. W. Doherty, N. B. Manson, P. Delaney, F. Jelezko, J. Wrachtrup, and L. C. Hollenberg, The nitrogen-vacancy colour centre in diamond, Phys. Rep. 528, 1 (2013).
- W. Liu, et al., Coherent dynamics of multi-spin center in hexagonal boron nitride, Nat. Commun. 13, 5713 (2022).
- M. A. Nielsen and I. L. Chuang, Quantum Computation and Quantum Information: 10th Anniversary Edition (Cambridge University Press, Cambridge, 2010).
- A. Gilchrist, N. K. Langford, and M. A. Nielsen, Distance measures to compare real and ideal quantum processes, Phys. Rev. A 71, 062310 (2005).
- J. Johansson, P. Nation, and F. Nori, QuTiP: An open-source Python framework for the dynamics of open quantum systems, Comput. Phys. Commun. 183, 1760 (2012).
- J. Johansson, P. Nation, and F. Nori, QuTiP 2: A Python framework for the dynamics of open quantum systems, Comput. Phys. Commun. 184, 1234 (2013).
- D. M. Greenberger, M. A. Horne, A. Shimony, and A. Zeilinger, Bell’s theorem without inequalities, Am. J. Phys. 58, 1131 (1990).
- R. Jozsa, Fidelity for mixed quantum states, J. Mod. Opt. 41, 2315 (1994).
- F. T. Tabesh, S. Rahimi-Keshari, and M. Abdi, Decoherence time of the ground state spin of centers in hexagonal boron nitride, ArXiv:2501.08055.
- M. Ye, H. Seo, and G. Galli, Spin coherence in two-dimensional materials, npj Comput. Mater. 5, 44 (2019).
- J. Lee, H. Park, and H. Seo, First-principles theory of extending the spin qubit coherence time in hexagonal boron nitride, npj 2D Mater. Appl. 6, 60 (2022).
- N. Zhao, S.-W. Ho, and R.-B. Liu, Decoherence and dynamical decoupling control of nitrogen vacancy center electron spins in nuclear spin baths, Phys. Rev. B 85, 115303 (2012).
- H. Park, J. Lee, S. Han, S. Oh, and H. Seo, Author correction: Decoherence of nitrogen-vacancy spin ensembles in a nitrogen electron-nuclear spin bath in diamond, npj Quantum Inf. 8, 95 (2022).
- D. Radishev, M. Lobaev, S. Bogdanov, A. Gorbachev, A. Vikharev, and M. Drozdov, Investigation of V centers charge states in CVD diamond layers doped by nitrogen and phosphorous, J. Lumin. 239, 118404 (2021).
- P. Chrostoski, P. Kehayias, and D. H. Santamore, Surface roughness noise analysis and comprehensive noise effects on depth-dependent coherence time of V centers in diamond, Phys. Rev. B 106, 235311 (2022).
- C. P. Anderson, E. O. Glen, C. Zeledon, A. Bourassa, Y. Jin, Y. Zhu, C. Vorwerk, A. L. Crook, H. Abe, J. Ul-Hassan, T. Ohshima, N. T. Son, G. Galli, and D. D. Awschalom, Five-second coherence of a single spin with single-shot readout in silicon carbide, Sci. Adv. 8, eabm5912 (2022).
- A. J. Ramsay, R. Hekmati, C. J. Patrickson, S. Baber, D. R. M. Arvidsson-Shukur, A. J. Bennett, and I. J. Luxmoore, Coherence protection of spin qubits in hexagonal boron nitride, Nat. Commun. 14, 461 (2023).
- J. J. Pla, K. Y. Tan, J. P. Dehollain, W. H. Lim, J. J. L. Morton, F. A. Zwanenburg, D. N. Jamieson, A. S. Dzurak, and A. Morello, High-fidelity readout and control of a nuclear spin qubit in silicon, Nature 496, 334 (2013).
- Parameters for Numerical Calculations, Binary Data, and Ploting Script corresponding to Figures in the Article Synchronous manipulation of nuclear spins via boron-vacancy centers in hexagonal boron nitride, https://github.com/fsakuldee/Sync-VB-hBN.