Fock-space relativistic coupled-cluster two-valence calculations of clock transition properties, dipole polarizability, and isotope shifts in fermionic and bosonic Sr
Palki Gakkhar, D. Angom, and B. K. Mani
Phys. Rev. A 113, 032817 (2026) - Published 23 March, 2026
We employ an all-particle multireference Fock-space relativistic coupled-cluster (FSRCC) theory to study the clock transition in both fermionic and bosonic isotopes of Sr. We compute the excitation energies for several low-lying states, E1 and M1 transition amplitudes, hyperfine reduced matrix elements, and isotope shifts using FSRCC theory. Further, using our results on E1, M1, and hyperfine structure (HFS) reduced matrix elements, we calculate the lifetime of the metastable clock states for and . Furthermore, we employ perturbed relativistic coupled-cluster (PRCC) theory to compute the ground state electric dipole polarizability of Sr. To improve the accuracy of our results, we incorporate the corrections from the relativistic and quantum electrodynamical (QED) effects, and perturbative triples to all our calculations. Moreover, we employ large bases to ensure the convergence of the computed properties. Our computed excitation energies are in good agreement with the experimental data for low-lying excited states. Our results for E1, M1, and HFS reduced matrix elements are within the experimental error bars, however, with slight difference from the previous calculations due to more accurate treatment of electron correlations in FSRCC theory. Our computed lifetime of the clock state for is within the error bars of the available experimental results, whereas for it is an order of magnitude smaller than the only available calculation [R. Santra et al., Phys. Rev. A 69, 042510 (2004)] using model potential. Our PRCC result for the ground state polarizability is in good agreement with the experiment, and smaller than previous calculations. Our results on isotope shift factors are consistent with available experimental results for intercombination transitions. From detailed analysis of the results, we find that the corrections from the Breit interaction, QED effects, and perturbative triples are crucial to get accurate clock transition properties in Sr. Moreover, valence-valence electron correlation is important to get accurate energies and properties of Sr.


