The asymmetric Fano profile, which is caused by the two-channel interference between discrete states and relevant continuum states, presents a great challenge to atomic and molecular physics. This study investigates the inner-valence excitations of argon electrons in the energy range 24.5–29.5 eV using an electron energy-loss spectrometer. The absolute generalized oscillator strength densities of the excitations and the Fano profile parameters (i.e., , , , , ) in a.u. for the ( and 5), ( and 5), and autoionization states are determined. For the same Rydberg series, similar momentum-transfer-dependence behaviors are observed for the Fano profile parameters , , , , and . The magnitudes of and are found to be nearly equal for the same Rydberg series, while the corresponding and parameters decrease as the principal quantum number increases, confirming the theoretical predictions of Fano and Cooper [U. Fano and J. W. Cooper, Phys. Rev. 137, A1364 (1965)]. Moreover, the typical dipole-allowed or dipole-forbidden -dependence behaviors of the Fano profile parameters are used to elucidate the properties of electric transition multipolarities. The parameters of the Fano profile derived in a large region offer an opportunity to understand the wave functions far away from the nucleus.