• Accepted Paper

Direct observation of thermal spin depolarization in a type I$_{\rm{B}}$ half-metal NiCo2O4 by spin-resolved photoemission

Hirokazu Fujiwara, Tomoki Higashikawa, Enda Xiao, Terumasa Tadano, Lingling Xie, Daisuke Kan, Yuichi Shimakawa, Kaishu Kawaguchi, Ryo Mori, Ayumi Harasawa, Takeshi Kondo, and Takayoshi Yokoya

Phys. Rev. Research - Accepted 2 October, 2026

DOI: https://doi.org/10.1103/9hsj-vmwn

Abstract

Half-metals (HMs), characterized by 100% spin polarization at the Fermi level (EF), are ideal candidates for future spintronic memory devices. However, their spin polarization rapidly decreases with temperature, limiting their practical implementation. While this degradation has been theoretically attributed to nonquasiparticle (NQP) states— many-body electronic states arising from electron–magnon interactions which reduce spin polarization near EF— experimental verification remains limited. Here, we report the temperature evolution of the electronic states in epitaxial NiCo2O4 (NCO) thin films, a predicted Type IB HM where the main spectral weight of NQP states lies below EF. Using high-resolution bulk-sensitive laser-based spin-resolved photoemission spectroscopy, we reveal that at 20 K, a metallic Fermi edge is observed in the minority spin states but is absent in the majority spin states, providing spectroscopic evidence for the half-metallicity of NCO. As temperature increases, majority spin spectral weight emerges at EF, and spin polarization near EF decreases—consistent with the emergence of NQP states. The onset of this behavior occurs around 100 K. Our results suggest that NCO provides a promising platform for investigating NQP-related many-body effects in Type IB HMs, guiding the design of spintronic materials with robust high-temperature spin polarization.

Export citation

Export citation

Choose format for download:

Download Citation

If the author has provided any supplemental materials with this article they will be available upon publication of the version of record.

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation