• Accepted Paper

Landau theory applied to antiferroelectric ordering in ferroelectric nematic liquid crystals

Manisha Badu, Arjun Ghimire, Milon, Priyanka Kumari, Hari Krishna Bisoyi, Oleg D. Lavrentovich, James Gleeson, Antal Jakli, and Samuel Sprunt

Phys. Rev. Research - Accepted 22 September, 2026

DOI: https://doi.org/10.1103/136n-hykb

Abstract

The polarization and mass density modulation associated with antiferroelectric ordering in two ferroelectric nematic liquid crystals, a prototypical single compound (DIO) and a commercial mixture (FNLC919), is studied experimentally as a function of temperature. The wavenumber of the polarization modulation, qA, is determined by small angle X-ray diffraction from the weak, accompanying density wave (wavenumber qS=2qA) using a conventional laboratory source. Combined results for qS and the saturated value of the polarization are analyzed in terms of Landau theory previously developed to describe the para-/antiferro-/ferroelectric sequence of phase transitions in solid ferroelectrics. The analysis of qS indicates that the polarization modulation can be reasonably well approximated by a simple sinusoid in DIO, whereas in FNLC919 a sharp decrease in qS close to the antiferro- to ferroelectric transition indicates development of a soliton-like profile.

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