- Open Access
Formation of bosonic Feshbach molecules
Phys. Rev. Research 8, 023307 – Published 17 June, 2026
DOI: https://doi.org/10.1103/s4bx-31b6
Abstract
Ultracold Feshbach molecules are a crucial intermediate step for the creation of quantum degenerate gases of strongly dipolar molecules. After coherent transfer to the rovibrational ground state, these dimers can realize stable dipolar gases with strong, tunable long-range interactions. Here, we report the creation of bosonic Feshbach molecules by radio-frequency (RF) association. An RF pulse applied on the molecular side of an interspecies Feshbach resonance at 73.6(1) G associates up to molecules from a thermal mixture of and atoms. Measurements of the binding energy reveal a broad resonance width of 5.1(2) G, facilitating robust control over interspecies interactions. The molecule lifetime in the presence of background atoms exceeds 2 ms and increases to approximately 7 ms after removal of . These results constitute a key step toward the production of ultracold ground-state molecules and for pursuing shielded evaporative cooling in the dipolar regime.
Physics Subject Headings (PhySH)
Article Text
References (45)
- L. D. Carr, D. DeMille, R. V. Krems, and J. Ye, Cold and ultracold molecules: Science, technology and applications, New J. Phys. 11, 055049 (2009).
- J. L. Bohn, A. M. Rey, and J. Ye, Cold molecules: Progress in quantum engineering of chemistry and quantum matter, Science 357, 1002 (2017).
- T. Langen, G. Valtolina, D. Wang, and J. Ye, Quantum state manipulation and cooling of ultracold molecules, Nat. Phys. 20, 702 (2024).
- S. L. Cornish, M. R. Tarbutt, and K. R. A. Hazzard, Quantum computation and quantum simulation with ultracold molecules, Nat. Phys. 20, 730 (2024).
- H. P. Büchler, E. Demler, M. Lukin, A. Micheli, N. Prokof’ev, G. Pupillo, and P. Zoller, Strongly correlated 2D quantum phases with cold polar molecules: Controlling the shape of the interaction potential, Phys. Rev. Lett. 98, 060404 (2007).
- N. Y. Yao, M. P. Zaletel, D. M. Stamper-Kurn, and A. Vishwanath, A quantum dipolar spin liquid, Nat. Phys. 14, 405 (2018).
- B. Capogrosso-Sansone, C. Trefzger, M. Lewenstein, P. Zoller, and G. Pupillo, Quantum phases of cold polar molecules in 2D optical lattices, Phys. Rev. Lett. 104, 125301 (2010).
- A. Micheli, G. K. Brennen, and P. Zoller, A toolbox for lattice-spin models with polar molecules, Nat. Phys. 2, 341 (2006).
- D. DeMille, Quantum computation with trapped polar molecules, Phys. Rev. Lett. 88, 067901 (2002).
- K.-K. Ni, T. Rosenband, and D. D. Grimes, Dipolar exchange quantum logic gate with polar molecules, Chem. Sci. 9, 6830 (2018).
- L. R. B. Picard, A. J. Park, G. E. Patenotte, S. Gebretsadkan, D. Wellnitz, A. M. Rey, and K.-K. Ni, Entanglement and iswap gate between molecular qubits, Nature (London) 637, 821 (2025).
- D. DeMille, N. R. Hutzler, A. M. Rey, and T. Zelevinsky, Quantum sensing and metrology for fundamental physics with molecules, Nat. Phys. 20, 741 (2024).
- J. J. Zirbel, K.-K. Ni, S. Ospelkaus, J. P. D’Incao, C. E. Wieman, J. Ye, and D. S. Jin, Collisional stability of fermionic Feshbach molecules, Phys. Rev. Lett. 100, 143201 (2008).
- K.-K. Ni, S. Ospelkaus, M. H. G. de Miranda, A. Pe’er, B. Neyenhuis, J. J. Zirbel, S. Kotochigova, P. S. Julienne, D. S. Jin, and J. Ye, A high phase-space density gas of polar molecules, Science 322, 231 (2008).
- T. Takekoshi, L. Reichsöllner, A. Schindewolf, J. M. Hutson, C. R. Le Sueur, O. Dulieu, F. Ferlaino, R. Grimm, and H.-C. Nägerl, Ultracold dense samples of dipolar molecules in the rovibrational and hyperfine ground state, Phys. Rev. Lett. 113, 205301 (2014).
- P. K. Molony, P. D. Gregory, Z. Ji, B. Lu, M. P. Köppinger, C. R. Le Sueur, C. L. Blackley, J. M. Hutson, and S. L. Cornish, Creation of ultracold molecules in the rovibrational ground state, Phys. Rev. Lett. 113, 255301 (2014).
- J. W. Park, S. A. Will, and M. W. Zwierlein, Ultracold dipolar gas of fermionic molecules in their absolute ground state, Phys. Rev. Lett. 114, 205302 (2015).
- M. Guo, B. Zhu, B. Lu, X. Ye, F. Wang, R. Vexiau, N. Bouloufa-Maafa, G. Quéméner, O. Dulieu, and D. Wang, Creation of an ultracold gas of ground-state dipolar molecules, Phys. Rev. Lett. 116, 205303 (2016).
- T. M. Rvachov, H. Son, A. T. Sommer, S. Ebadi, J. J. Park, M. W. Zwierlein, W. Ketterle, and A. O. Jamison, Long-lived ultracold molecules with electric and magnetic dipole moments, Phys. Rev. Lett. 119, 143001 (2017).
- K. K. Voges, P. Gersema, M. M. z. A. Borgloh, T. A. Schulze, T. Hartmann, A. Zenesini, and S. Ospelkaus, Ultracold gas of bosonic ground-state molecules, Phys. Rev. Lett. 125, 083401 (2020).
- W. B. Cairncross, J. T. Zhang, L. R. B. Picard, Y. Yu, K. Wang, and K.-K. Ni, Assembly of a rovibrational ground state molecule in an optical tweezer, Phys. Rev. Lett. 126, 123402 (2021).
- I. Stevenson, A. Z. Lam, N. Bigagli, C. Warner, W. Yuan, S. Zhang, and S. Will, Ultracold gas of dipolar ground state molecules, Phys. Rev. Lett. 130, 113002 (2023).
- C. He, X. Nie, V. Avalos, S. Botsi, S. Kumar, A. Yang, and K. Dieckmann, Efficient creation of ultracold ground state polar molecules, Phys. Rev. Lett. 132, 243401 (2024).
- K. P. Zamarski, C. Beulenkamp, Y. Zeng, M. Landini, and H.-C. Nägerl, Spectroscopy and ground-state transfer of ultracold bosonic molecules, Phys. Rev. Lett. 135, 203401 (2025).
- L. D. Marco, G. Valtolina, K. Matsuda, W. G. Tobias, J. P. Covey, and J. Ye, A degenerate Fermi gas of polar molecules, Science 363, 853 (2019).
- A. Schindewolf, R. Bause, X.-Y. Chen, M. Duda, T. Karman, I. Bloch, and X.-Y. Luo, Evaporation of microwave-shielded polar molecules to quantum degeneracy, Nature (London) 607, 677 (2022).
- N. Bigagli, W. Yuan, S. Zhang, B. Bulatovic, T. Karman, I. Stevenson, and S. Will, Observation of Bose–Einstein condensation of dipolar molecules, Nature (London) 631, 289 (2024).
- Z. Shi, Z. Huang, F. Deng, W.-J. Jin, S. Yi, T. Shi, and D. Wang, Bose-Einstein condensate of ultracold sodium-rubidium molecules with tunable dipolar interactions, arXiv:2508.20518.
- A. Gerdes, O. Dulieu, H. Knöckel, and E. Tiemann, Stark effect measurements on the molecule, Eur. Phys. J. D 65, 105 (2011).
- M. Schmidt, L. Lassablière, G. Quéméner, and T. Langen, Self-bound dipolar droplets and supersolids in molecular Bose-Einstein condensates, Phys. Rev. Res. 4, 013235 (2022).
- P. S. Żuchowski and J. M. Hutson, Reactions of ultracold alkali-metal dimers, Phys. Rev. A 81, 060703(R) (2010).
- Y.-X. Liu, L. Zhu, J. Luke, J. J. A. Houwman, M. C. Babin, M.-G. Hu, and K.-K. Ni, Quantum interference in atom-exchange reactions, Science 384, 1117 (2024).
- P. Gersema, K. K. Voges, M. M. z. A. Borgloh, L. Koch, T. Hartmann, A. Zenesini, S. Ospelkaus, J. Lin, J. He, and D. Wang, Probing photoinduced two-body loss of ultracold nonreactive bosonic and molecules, Phys. Rev. Lett. 127, 163401 (2021).
- K. K. Voges, P. Gersema, T. Hartmann, T. A. Schulze, A. Zenesini, and S. Ospelkaus, Formation of ultracold weakly bound dimers of bosonic , Phys. Rev. A 101, 042704 (2020).
- J. Chang, S. Lee, Y. Kim, Y. Lim, and J. W. Park, Dual-species Bose-Einstein condensates of and with tunable interactions, Phys. Rev. Res. 6, 013183 (2024).
- J. Chang, S. Lee, Y. Kim, S. Jang, J. Kim, S. Kim, and J. W. Park (unpublished).
- C. Chin, R. Grimm, P. Julienne, and E. Tiesinga, Feshbach resonances in ultracold gases, Rev. Mod. Phys. 82, 1225 (2010).
- A. Derevianko, J. F. Babb, and A. Dalgarno, High-precision calculations of van der Waals coefficients for heteronuclear alkali-metal dimers, Phys. Rev. A 63, 052704 (2001).
- A. Viel and A. Simoni, Feshbach resonances and weakly bound molecular states of boson-boson and boson-fermion NaK pairs, Phys. Rev. A 93, 042701 (2016).
- A. Z. Lam, N. Bigagli, C. Warner, W. Yuan, S. Zhang, E. Tiemann, I. Stevenson, and S. Will, High phase-space density gas of NaCs Feshbach molecules, Phys. Rev. Res. 4, L022019 (2022).
- M. Hans, F. Schmutte, C. Viermann, N. Liebster, M. Sparn, M. K. Oberthaler, and H. Strobel, High signal to noise absorption imaging of alkali atoms at moderate magnetic fields, Rev. Sci. Instrum. 92, 023203 (2021).
- C. Klempt, T. Henninger, O. Topic, M. Scherer, L. Kattner, E. Tiemann, W. Ertmer, and J. J. Arlt, Radio-frequency association of heteronuclear Feshbach molecules, Phys. Rev. A 78, 061602 (2008).
- C.-H. Wu, J. W. Park, P. Ahmadi, S. Will, and M. W. Zwierlein, Ultracold fermionic Feshbach molecules of , Phys. Rev. Lett. 109, 085301 (2012).
- C. Chin and P. S. Julienne, Radio-frequency transitions on weakly bound ultracold molecules, Phys. Rev. A 71, 012713 (2005).
- T. Hartmann, T. A. Schulze, K. K. Voges, P. Gersema, M. W. Gempel, E. Tiemann, A. Zenesini, and S. Ospelkaus, Feshbach resonances in mixtures and refined molecular potentials for the NaK molecule, Phys. Rev. A 99, 032711 (2019).