- Open Access
Revealing the nonclassicality of a molecular nanomagnet
Phys. Rev. Research 8, 033207 – Published 19 August, 2026
DOI: https://doi.org/10.1103/rx1v-3cpc
Abstract
Molecular nanomagnets are compounds characterized by a high-spin magnetic core that is protected by organic ligands. They have recently gained attention as potential quantum information carriers in solid-state quantum computing platforms, simultaneously exhibiting classical macroscopic properties and quantum features in light of their complex nature and configuration. Addressing the condition when they manifest unquestionable quantum behavior is key to guarantee their effectiveness as resources for quantum information processing. We address the quantumness of molecular nanomagnets using a recently formulated criterion [T. Krisnanda et al., Phys. Rev. Lett. 119, 120402 (2017)] demonstrating that these systems exhibit an intrinsic quantum nature, as evidenced by their ability to generate and enhance quantum correlations between two noninteracting probes. Our analysis, which is performed addressing various dynamical regimes, paves the way to the design of experimentally viable tests of nonclassicality in multipartite registers consisting of ensembles of molecular nanomagnets.
Physics Subject Headings (PhySH)
Corrections
8 September, 2026
Correction: Errors in the author lists of Refs. [2], [8], [12], and [21] have been fixed.
Article Text
References (36)
- A. Chiesa, P. Santini, E. Garlatti, F. Luis, and S. Carretta, Molecular nanomagnets: A viable path toward quantum information processing? Rep. Prog. Phys. 87, 034501 (2024).
- M. Soler, W. Wernsdorfer, K. Folting, M. Pink, and G. Christou, Single-molecule magnets: A large molecular nanomagnet exhibiting quantum tunneling of magnetization, J. Am. Chem. Soc. 126, 2156 (2004).
- A. Chiesa, E. Macaluso, F. Petiziol, S. Wimberger, P. Santini, and S. Carretta, Molecular nanomagnets as qubits with embedded quantum-error correction, J. Phys. Chem. Lett. 11, 8610 (2020).
- J. Emerson-King, G. K. Gransbury, B. E. Atkinson, W. J. A. Blackmore, G. F. S. Whitehead, N. F. Chilton, and D. P. Mills, Soft magnetic hysteresis in a dysprosium amide–alkene complex up to 100 kelvin, Nature (London) 643, 125 (2025).
- K. Hymas and A. Soncini, Molecular spintronics using single-molecule magnets under irradiation, Phys. Rev. B 99, 245404 (2019).
- G. Latino, F. Brero, A. Cini, M. Fittipaldi, E. Giroletti, A. Lascialfari, F. Santanni, P. Santini, L. Sorace, and M. Mariani, Quantum sensing for particle physics using single molecule magnets, Nucl. Instrum. Methods Phys. Res. Sect. A 1079, 170621 (2025).
- T. Krisnanda, M. Zuppardo, M. Paternostro, and T. Paterek, Revealing nonclassicality of inaccessible objects, Phys. Rev. Lett. 119, 120402 (2017).
- T. Krisnanda, C. Marletto, V. Vedral, M. Paternostro, and T. Paterek, Probing quantum features of photosynthetic organisms, npj Quantum Inf. 4, 60 (2018).
- T. Krisnanda, G. Y. Tham, M. Paternostro, and T. Paterek, Observable quantum entanglement due to gravity, npj Quantum Inf. 6, 12 (2020).
- The cluster consists of eight Fe(iii) ions, each with spin . The total spin can be regarded as the vector sum of the individual spins. However, due to the competing ferromagnetic and antiferromagnetic interactions within the molecule, the spins arrange themselves so that the cluster attains a total spin of , corresponding to the minimum-energy configuration.
- W. Wernsdorfer, Quantum dynamics in molecular nanomagnets, C. R. Chim. Magn. Mol. : Nouv. Tendances 11, 1086 (2008).
- Y. Duan, L. E. Rosaleny, J. T. Coutinho, S. Giménez-Santamarina, A. Scheie, J. J. Baldoví, S. Cardona-Serra, and A. Gaita-Ariño, Data-driven design of molecular nanomagnets, Nat. Commun. 13, 7626 (2022).
- S. G. Tabrizi, A. V. Arbuznikov, and M. Kaupp, Exact mapping from many-spin Hamiltonians to giant-spin Hamiltonians, Chem. A Eur. J. 24, 4689 (2018).
- F. Troiani, V. Bellini, and M. Affronte, Decoherence induced by hyperfine interactions with nuclear spins in antiferromagnetic molecular rings, Phys. Rev. B 77, 054428 (2008).
- EPR spectroscopy: Fundamentals and Methods, eMagRes Books, edited by D. Goldfarb and S. Stoll (John Wiley & Sons, Chichester, UK, 2018), Chap. 5, p. 656.
- Alternatively, one could also exploit the polarization degree of freedom of light to generate two noninteracting sets of modes.
- A. Chiesa, S. Roca, S. Chicco, M. de Ory, A. Gómez-León, A. Gomez, D. Zueco, F. Luis, and S. Carretta, Blueprint for a molecular-spin quantum processor, Phys. Rev. Appl. 19, 064060 (2023).
- N. Samkharadze, G. Zheng, N. Kalhor, D. Brousse, A. Sammak, U. C. Mendes, A. Blais, G. Scappucci, and L. M. K. Vandersypen, Strong spin-photon coupling in silicon, Science 359, 1123 (2018).
- For : , and .
- S. Takahashi, J. van Tol, C. C. Beedle, D. N. Hendrickson, L.-C. Brunel, and M. S. Sherwin, Coherent manipulation and decoherence of single-molecule magnets, Phys. Rev. Lett. 102, 087603 (2009).
- F. Petiziol, A. Chiesa, S. Wimberger, P. Santini, and S. Carretta, Counteracting dephasing in molecular nanomagnets by optimized qudit encodings, npj Quantum Inf. 7, 133 (2021).
- Z. Kurucz and K. Mølmer, Multilevel Holstein-Primakoff approximation and its application to atomic spin squeezing and ensemble quantum memories, Phys. Rev. A 81, 032314 (2010).
- T. Holstein and H. Primakoff, Field dependence of the intrinsic domain magnetization of a ferromagnet, Phys. Rev. 58, 1098 (1940).
- R.-C. Shen, J. Li, Z.-Y. Fan, Y.-P. Wang, and J. You, Mechanical bistability in Kerr-modified cavity magnomechanics, Phys. Rev. Lett. 129, 123601 (2022).
- R. Horodecki, P. Horodecki, M. Horodecki, and K. Horodecki, Quantum entanglement, Rev. Mod. Phys. 81, 865 (2009).
- M. B. Plenio, Logarithmic negativity: A full entanglement monotone that is not convex, Phys. Rev. Lett. 95, 090503 (2005).
- G. Lindblad, On the generators of quantum dynamical semigroups, Commun. Math. Phys. 48, 119 (1976).
- W. Zhong, Z. Sun, J. Ma, X. Wang, and F. Nori, Fisher information under decoherence in Bloch representation, Phys. Rev. A 87, 022337 (2013).
- For some exceptions to this, see, e.g., Refs. [21, 31].
- M. Chizzini, L. Crippa, A. Chiesa, F. Tacchino, F. Petiziol, I. Tavernelli, P. Santini, and S. Carretta, Molecular nanomagnets with competing interactions as optimal units for qudit-based quantum computation, Phys. Rev. Res. 4, 043135 (2022).
- W. A. Coish, J. Fischer, and D. Loss, Exponential decay in a spin bath, Phys. Rev. B 77, 125329 (2008).
- A. Cammarata, Data for “Revealing the nonclassicality of a molecular nanomagnet”, Zenodo, 2026,, https://doi.org/10.5281/zenodo.21158509.
- M. Vogl, P. Laurell, H. Zhang, S. Okamoto, and G. A. Fiete, Resummation of the Holstein-Primakoff expansion and differential equation approach to operator square roots, Phys. Rev. Res. 2, 043243 (2020).
- M. A. Yurischev, S. Haddadi, and M. Ghominejad, A comparative study of LQU and LQFI in general qubit-qutrit axially symmetric states, Sci. Rep. 15, 1828 (2025).
- Arvind, B. Dutta, N. Mukunda, and R. Simon, The real symplectic groups in quantum mechanics and optics, Pramana 45, 471 (1995).
- R. Simon, Peres-Horodecki separability criterion for continuous variable systems, Phys. Rev. Lett. 84, 2726 (2000).