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Ensemble inequivalence in long-range quantum spin systems

Daniel Arrufat-Vicente1,*, David Mukamel2, Stefano Ruffo3,4,5, and Nicolò Defenu1

  • *Contact author: darrufat@phys.ethz.ch

Phys. Rev. Research 8, 013333 – Published 27 March, 2026

DOI: https://doi.org/10.1103/hmhz-4g46

Abstract

Ensemble inequivalence, where a system's thermodynamic properties depend on the statistical ensemble used to describe it, is a well-established phenomenon in classical systems with long-range interactions. Here, we present a detailed analysis of a quantum ferromagnet spin model that exhibits this same behavior. We find that the microcanonical and canonical phase diagrams are identical at zero temperature (T=0), but differ significantly at finite temperatures. Our results highlight a breakdown of ensemble equivalence in this quantum long-range model, contrasting with what is observed for short range. These findings have important implications for the study and manipulation of long-range interacting quantum platforms, such as those used in atomic, molecular, and optical physics.

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References (80)

  1. M. D. Lukin, Colloquium: Trapping and manipulating photon states in atomic ensembles, Rev. Mod. Phys. 75, 457 (2003).
  2. M. Saffman, T. G. Walker, and K. Mølmer, Quantum information with Rydberg atoms, Rev. Mod. Phys. 82, 2313 (2010).
  3. J. W. Britton, B. C. Sawyer, A. C. Keith, C. C. J. Wang, J. K. Freericks, H. Uys, M. J. Biercuk, and J. J. Bollinger, Engineered two-dimensional Ising interactions in a trapped-ion quantum simulator with hundreds of spins, Nature (London) 484, 489 (2012).
  4. I. Bloch, J. Dalibard, and W. Zwerger, Many-body physics with ultracold gases, Rev. Mod. Phys. 80, 885 (2008).
  5. R. Blatt and C. F. Roos, Quantum simulations with trapped ions, Nat. Phys. 8, 277 (2012).
  6. C. Monroe, W. C. Campbell, L.-M. Duan, Z.-X. Gong, A. V. Gorshkov, P. W. Hess, R. Islam, K. Kim, N. M. Linke, G. Pagano, P. Richerme, C. Senko, and N. Y. Yao, Programmable quantum simulations of spin systems with trapped ions, Rev. Mod. Phys. 93, 025001 (2021).
  7. F. Mivehvar, F. Piazza, T. Donner, and H. Ritsch, Cavity QED with quantum gases: New paradigms in many-body physics, Adv. Phys. 70, 1 (2021).
  8. N. Defenu, T. Donner, T. Macrì, G. Pagano, S. Ruffo, and A. Trombettoni, Long-range interacting quantum systems, Rev. Mod. Phys. 95, 035002 (2023).
  9. J. Sak, Recursion relations and fixed points for ferromagnets with long-range interactions, Phys. Rev. B 8, 281 (1973).
  10. M. E. Fisher, S.-K. Ma, and B. G. Nickel, Critical exponents for long-range interactions, Phys. Rev. Lett. 29, 917 (1972).
  11. E. Luijten and H. W. J. Blöte, Classical critical behavior of spin models with long-range interactions, Phys. Rev. B 56, 8945 (1997).
  12. M. C. Angelini, G. Parisi, and F. Ricci-Tersenghi, Relations between short-range and long-range Ising models, Phys. Rev. E 89, 062120 (2014).
  13. N. Defenu, A. Trombettoni, and A. Codello, Fixed-point structure and effective fractional dimensionality for O(N) models with long-range interactions, Phys. Rev. E 92, 052113 (2015).
  14. N. Defenu, A. Trombettoni, and S. Ruffo, Anisotropic long-range spin systems, Phys. Rev. B 94, 224411 (2016).
  15. N. Defenu, A. Trombettoni, and S. Ruffo, Criticality and phase diagram of quantum long-range O(N) models, Phys. Rev. B 96, 104432 (2017).
  16. N. Defenu, A. Codello, S. Ruffo, and A. Trombettoni, Criticality of spin systems with weak long-range interactions, J. Phys. A 53, 143001 (2020).
  17. T. Dauxois, V. Latora, A. Rapisarda, S. Ruffo, and A. Torcini, Nonextensivity From Low-Dimensional Maps to Hamiltonian Systems, Dynamics and Thermodynamics of Systems with Long-Range Interactions, edited by T. Dauxois, S. Ruffo, E. Arimondo, and M. Wilkens (Springer, Berlin, 2002), pp. 458–487.
  18. A. Campa, T. Dauxois, and S. Ruffo, Statistical mechanics and dynamics of solvable models with long-range interactions, Phys. Rep. 480, 57 (2009).
  19. A. Campa, T. Dauxois, D. Fanelli, and S. Ruffo, Physics of Long-Range Interacting Systems (Oxford University Press, Oxford, 2014).
  20. Y. Levin, R. Pakter, F. B. Rizzato, T. N. Teles, and F. P. Benetti, Nonequilibrium statistical mechanics of systems with long-range interactions, Phys. Rep. 535, 1 (2014).
  21. J. Barré, D. Mukamel, and S. Ruffo, Inequivalence of ensembles in a system with long-range interactions, Phys. Rev. Lett. 87, 030601 (2001).
  22. W. Thirring, Systems with negative specific heat, Z. Phys. 235, 339 (1970).
  23. M. Kastner, Diverging equilibration times in long-range quantum spin models, Phys. Rev. Lett. 106, 130601 (2011).
  24. S. Schütz and G. Morigi, Prethermalization of atoms due to photon-mediated long-range interactions, Phys. Rev. Lett. 113, 203002 (2014).
  25. S. Schütz, S. B. Jäger, and G. Morigi, Dissipation-assisted prethermalization in long-range interacting atomic ensembles, Phys. Rev. Lett. 117, 083001 (2016).
  26. D. Mukamel, S. Ruffo, and N. Schreiber, Breaking of ergodicity and long relaxation times in systems with long-range interactions, Phys. Rev. Lett. 95, 240604 (2005).
  27. F. Borgonovi, G. L. Celardo, M. Maianti, and E. Pedersoli, Broken ergodicity in classically chaotic spin systems, J. Stat. Phys. 116, 1435 (2004).
  28. M. Kastner, Nonequivalence of ensembles for long-range quantum spin systems in optical lattices, Phys. Rev. Lett. 104, 240403 (2010).
  29. M. Kastner, Nonequivalence of ensembles in the Curie–Weiss anisotropic quantum Heisenberg model, J. Stat. Phys. 2010, P07006 (2010).
  30. N. Defenu, Metastability and discrete spectrum of long-range systems, Proc. Nat. Acad. Sci. USA 118, e2101785118 (2021).
  31. A. Lerose, T. Parolini, R. Fazio, D. A. Abanin, and S. Pappalardi, Theory of robust quantum many-body scars in long-range interacting systems, Phys. Rev. X 15, 011020 (2025).
  32. D. Arrufat-Vicente and N. Defenu, Freezing and shielding under global quenches for long-range interacting many-body systems, arXiv:2407.06072.
  33. N. Defenu, D. Mukamel, and S. Ruffo, Ensemble inequivalence in long-range quantum systems, Phys. Rev. Lett. 133, 050403 (2024).
  34. V. Bapst and G. Semerjian, On quantum mean-field models and their quantum annealing, J. Stat. Mech. (2012) P06007..
  35. F. Krzakala, A. Rosso, G. Semerjian, and F. Zamponi, Path-integral representation for quantum spin models: Application to the quantum cavity method and Monte Carlo simulations, Phys. Rev. B 78, 134428 (2008).
  36. T. Jörg, F. Krzakala, J. Kurchan, A. C. Maggs, and J. Pujos, Energy gaps in quantum first-order mean-field–like transitions: The problems that quantum annealing cannot solve, Europhys. Lett. 89, 40004 (2010).
  37. D. S. Petrov, Elastic multibody interactions on a lattice, Phys. Rev. A 90, 021601(R) (2014).
  38. A. Goban, R. B. Hutson, G. E. Marti, S. L. Campbell, M. A. Perlin, P. S. Julienne, J. P. D'Incao, A. M. Rey, and J. Ye, Emergence of multi-body interactions in a fermionic lattice clock, Nature (London) 563, 369 (2018).
  39. W. Zwerger, Quantum-unbinding near a zero temperature liquid–gas transition, J. Stat. Mech. (2019) 103104.
  40. A. Griesmaier, J. Werner, S. Hensler, J. Stuhler, and T. Pfau, Bose-Einstein condensation of chromium, Phys. Rev. Lett. 94, 160401 (2005).
  41. A. Micheli, G. K. Brennen, and P. Zoller, A toolbox for lattice-spin models with polar molecules, Nat. Phys. 2, 341 (2006).
  42. K.-K. Ni, S. Ospelkaus, M. H. G. de Miranda, A. Pe'er, B. Neyenhuis, J. J. Zirbel, S. Kotochigova, P. S. Julienne, D. S. Jin, and J. Ye, A high phase-space-density gas of polar molecules, Science 322, 231 (2008).
  43. S. Morrison and A. S. Parkins, Dynamical quantum phase transitions in the dissipative Lipkin-Meshkov-Glick model with proposed realization in optical cavity QED, Phys. Rev. Lett. 100, 040403 (2008).
  44. J. Larson, Circuit QED scheme for the realization of the Lipkin-Meshkov-Glick model, Europhys. Lett. 90, 54001 (2010).
  45. Z. Wu, J. Fan, X. Zhang, J. Qi, and H. Wu, Signatures of prethermalization in a quenched cavity-mediated long-range interacting Fermi gas, Phys. Rev. Lett. 131, 243401 (2023).
  46. T. Albash and D. A. Lidar, Adiabatic quantum computation, Rev. Mod. Phys. 90, 015002 (2018).
  47. H. J. Lipkin, N. Meshkov, and A. J. Glick, Validity of many-body approximation methods for a solvable model, Nucl. Phys. 62, 188 (1965).
  48. N. Meshkov, A. J. Glick, and H. J. Lipkin, Validity of many-body approximation methods for a solvable model. (II). Linearization procedures, Nucl. Phys. 62, 199 (1965).
  49. A. J. Glick, H. J. Lipkin, and N. Meshkov, Validity of many-body approximation methods for a solvable model. (III). Diagram summations, Nucl. Phys. 62, 211 (1965).
  50. R. H. Dicke, Coherence in spontaneous radiation processes, Phys. Rev. 93, 99 (1954).
  51. K. Baumann, C. Guerlin, F. Brennecke, and T. Esslinger, Dicke quantum phase transition with a superfluid gas in an optical cavity, Nature (London) 464, 1301 (2010).
  52. R. Landig, F. Brennecke, R. Mottl, T. Donner, and T. Esslinger, Measuring the dynamic structure factor of a quantum gas undergoing a structural phase transition, Nat. Commun. 6, 7046 (2015).
  53. J. Reslen, L. Quiroga, and N. F. Johnson, Direct equivalence between quantum phase transition phenomena in radiation-matter and magnetic systems: Scaling of entanglement, Europhys. Lett. 69, 8 (2005).
  54. S. Schütz, S. B. Jäger, and G. Morigi, Thermodynamics and dynamics of atomic self-organization in an optical cavity, Phys. Rev. A 92, 063808 (2015).
  55. I. D. Leroux, M. H. Schleier-Smith, and V. Vuletić, Implementation of cavity squeezing of a collective atomic spin, Phys. Rev. Lett. 104, 073602 (2010).
  56. G. Bentsen, I.-D. Potirniche, V. B. Bulchandani, T. Scaffidi, X. Cao, X.-L. Qi, M. Schleier-Smith, and E. Altman, Integrable and chaotic dynamics of spins coupled to an optical cavity, Phys. Rev. X 9, 041011 (2019).
  57. E. J. Davis, G. Bentsen, L. Homeier, T. Li, and M. H. Schleier-Smith, Photon-mediated spin-exchange dynamics of spin-1 atoms, Phys. Rev. Lett. 122, 010405 (2019).
  58. E. J. Davis, A. Periwal, E. S. Cooper, G. Bentsen, S. J. Evered, K. Van Kirk, and M. H. Schleier-Smith, Protecting spin coherence in a tunable Heisenberg model, Phys. Rev. Lett. 125, 060402 (2020).
  59. A. Gallemí, G. Queraltó, M. Guilleumas, R. Mayol, and A. Sanpera, Quantum spin models with mesoscopic Bose-Einstein condensates, Phys. Rev. A 94, 063626 (2016).
  60. T.-L. Ho, Spinor Bose condensates in optical traps, Phys. Rev. Lett. 81, 742 (1998).
  61. J. Stenger, S. Inouye, D. M. Stamper-Kurn, H. J. Miesner, A. P. Chikkatur, and W. Ketterle, Spin domains in ground-state Bose-Einstein condensates, Nature (London) 396, 345 (1998).
  62. M.-S. Chang, C. D. Hamley, M. D. Barrett, J. A. Sauer, K. M. Fortier, W. Zhang, L. You, and M. S. Chapman, Observation of spinor dynamics in optically trapped Rb87 Bose-Einstein condensates, Phys. Rev. Lett. 92, 140403 (2004).
  63. H. Schmaljohann, M. Erhard, J. Kronjäger, M. Kottke, S. van Staa, L. Cacciapuoti, J. J. Arlt, K. Bongs, and K. Sengstock, Dynamics of f=2 spinor Bose-Einstein condensates, Phys. Rev. Lett. 92, 040402 (2004).
  64. T. M. Hoang, M. Anquez, B. A. Robbins, X. Y. Yang, B. J. Land, C. D. Hamley, and M. S. Chapman, Parametric excitation and squeezing in a many-body spinor condensate, Nat. Commun. 7, 11233 (2016).
  65. H. Weimer, M. Müller, I. Lesanovsky, P. Zoller, and H. P. Büchler, A Rydberg quantum simulator, Nat. Phys. 6, 382 (2010).
  66. N. Henkel, R. Nath, and T. Pohl, Three-dimensional roton excitations and supersolid formation in Rydberg-excited Bose-Einstein condensates, Phys. Rev. Lett. 104, 195302 (2010).
  67. L. I. R. Gil, R. Mukherjee, E. M. Bridge, M. P. A. Jones, and T. Pohl, Spin squeezing in a Rydberg lattice clock, Phys. Rev. Lett. 112, 103601 (2014).
  68. J. Zeiher, P. Schauß, S. Hild, T. Macrì, I. Bloch, and C. Gross, Microscopic characterization of scalable coherent Rydberg superatoms, Phys. Rev. X 5, 031015 (2015).
  69. Y. Y. Jau, A. M. Hankin, T. Keating, I. H. Deutsch, and G. W. Biedermann, Entangling atomic spins with a Rydberg-dressed spin-flip blockade, Nat. Phys. 12, 71 (2016).
  70. S. Will, T. Best, U. Schneider, L. Hackermüller, D.-S. Lühmann, and I. Bloch, Time-resolved observation of coherent multi-body interactions in quantum phase revivals, Nature (London) 465, 197 (2010).
  71. H. P. Büchler, A. Micheli, and P. Zoller, Three-body interactions with cold polar molecules, Nat. Phys. 3, 726 (2007).
  72. L. Del Re, M. Fabrizio, and E. Tosatti, Nonequilibrium and nonhomogeneous phenomena around a first-order quantum phase transition, Phys. Rev. B 93, 125131 (2016).
  73. L. Landau and E. Lifshits, Statistical Physics, 3rd ed. (Addison-Wesley, Reading, MA, 1958), pp. 21–24.
  74. R. B. Griffiths, Microcanonical ensemble in quantum statistical mechanics, J. Math. Phys. 6, 1447 (1965).
  75. P. Sierant, M. Lewenstein, A. Scardicchio, L. Vidmar, and J. Zakrzewski, Many-body localization in the age of classical computing, Rep. Prog. Phys. 88, 026502 (2025).
  76. L. D. Landau and E. M. Lifshitz, Statistical Physics. Pt.1 (Butterworth-Heinemann, Oxford, 1969).
  77. S. Morrison and A. S. Parkins, Collective spin systems in dispersive optical cavity QED: Quantum phase transitions and entanglement, Phys. Rev. A 77, 043810 (2008).
  78. J. G. Cosme, J. Skulte, and L. Mathey, Bridging closed and dissipative discrete time crystals in spin systems with infinite-range interactions, Phys. Rev. B 108, 024302 (2023).
  79. F. Finger, R. Rosa-Medina, N. Reiter, P. Christodoulou, T. Donner, and T. Esslinger, Spin- and momentum-correlated atom pairs mediated by photon exchange and seeded by vacuum fluctuations, Phys. Rev. Lett. 132, 093402 (2024).
  80. E. H. Lieb, The classical limit of quantum spin systems, Commun. Math. Phys. 31, 327 (1973).

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