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Unifying quantum stochastic methods using Wick's theorem on the Keldysh contour
Phys. Rev. Research 7, 043262 – Published 8 December, 2025
DOI: https://doi.org/10.1103/cnvm-w8cy
Abstract
We present a method, based on the Keldysh formalism, for deriving stochastic master equations that describe the non-Markovian dynamics of a quantum system coupled to a Gaussian environment. This approach yields a compact expression for the system's propagator, which we show to be equivalent to existing formulations, such as the stochastic von Neumann equation (SVNE). A key advantage of our method is its generality: It can be extended to describe any open-system evolution defined on a suitable ordering contour. As a result, we adapt it to derive generalized versions of the SVNE that account for initial system-environment correlations, as well as stochastic equations that incorporate information about the statistics of energy flows in the environment. The insights offered by our technique further allow us to examine the nature of the noise processes appearing in the SVNE. We prove that its solution can be expressed in terms of a single physical noise, without any loss of information. Finally, we propose a semiclassical scenario in which this noise can be interpreted as arising from an initial measurement process on the environment.
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References (61)
- H.-P. Breuer and F. Petruccione, The Theory of Open Quantum Systems (Oxford University Press, Oxford, 2007).
- G. Lindblad, On the generators of quantum dynamical semigroups, Commun. Math. Phys. 48, 119 (1976).
- V. Gorini, A. Kossakowski, and E. C. G. Sudarshan, Completely positive dynamical semigroup of -level systems, J. Math. Phys. 17, 821 (1976).
- F. Nathan and M. S. Rudner, Universal lindblad equation for open quantum systems, Phys. Rev. B 102, 115109 (2020).
- E. Mozgunov and D. Lidar, Completely positive master equation for arbitrary driving and small level spacing, Quantum 4, 227 (2020).
- G. McCauley, B. Cruikshank, D. I. Bondar, and K. Jacobs, Accurate Lindblad-form master equation for weakly damped quantum systems across all regimes, npj Quantum Inf. 6, 74 (2020).
- A. D’Abbruzzo, V. Cavina, and V. Giovannetti, A time-dependent regularization of the Redfield equation, SciPost Phys. 15, 117 (2023).
- A. D'Abbruzzo, D. Farina, and V. Giovannetti, Recovering complete positivity of non-Markovian quantum dynamics with Choi-proximity regularization, Phys. Rev. X 14, 031010 (2024).
- I. de Vega and D. Alonso, Dynamics of non-Markovian open quantum systems, Rev. Mod. Phys. 89, 015001 (2017).
- G. Stefanucci and R. van Leeuwen, Nonequilibrium Many-Body Theory of Quantum Systems (Cambridge University Press, Cambridge, 2013).
- A. Kamenev, Field Theory of Non-Equilibrium Systems (Cambridge University Press, 2011).
- J. Schwinger, Brownian motion of a quantum oscillator, J. Math. Phys. 2, 407 (1961).
- L. V. Keldysh, Diagram technique for nonequilibrium processes, Sov. Phys. JETP 20, 1018 (1965).
- L. M. Sieberer, M. Buchhold, and S. Diehl, Keldysh field theory for driven open quantum systems, Rep. Prog. Phys. 79, 096001 (2016).
- C. Müller and T. M. Stace, Deriving lindblad master equations with Keldysh diagrams: Correlated gain and loss in higher perturbation theory, Phys. Rev. A 95, 013847 (2017).
- K. Funo and H. T. Quan, Path integral approach to quantum thermodynamics, Phys. Rev. Lett. 121, 040602 (2018).
- V. Reimer and M. R. Wegewijs, Density-operator evolution: Complete positivity and the Keldysh real-time expansion, SciPost Phys. 7, 012 (2019).
- A. McDonald and A. A. Clerk, Third quantization of open quantum systems: Dissipative symmetries and connections to phase-space and Keldysh field-theory formulations, Phys. Rev. Res. 5, 033107 (2023).
- V. Cavina, S. S. Kadijani, M. Esposito, and T. L. Schmidt, A convenient Keldysh contour for thermodynamically consistent perturbative and semiclassical expansions, SciPost Phys. 15, 209 (2023).
- F. Reyes-Osorio, F. Garcia-Gaitan, D. J. Strachan, P. Plechac, S. R. Clark, and B. K. Nikolic, Schwinger-Keldysh nonequilibrium quantum field theory of open quantum systems beyond the Markovian regime: Application to the spin-boson model, arXiv:2405.00765.
- V. Cavina and M. Esposito, Quantum thermodynamics of the Caldeira-Leggett model with non-equilibrium Gaussian reservoirs, arXiv:2405.00215.
- R. P. Feynman and F. L. Vernon, The theory of a general quantum system interacting with a linear dissipative system, Ann. Phys. 24, 118 (1963).
- L. Diósi, N. Gisin, and W. T. Strunz, Non-Markovian quantum state diffusion, Phys. Rev. A 58, 1699 (1998).
- J. T. Stockburger and H. Grabert, Non-Markovian quantum state diffusion, Chem. Phys. 268, 249 (2001).
- R. Kubo, A stochastic theory of line shape, in Advances in Chemical Physics (John Wiley & Sons, Ltd., New York, 1969), pp. 101–127.
- J. T. Stockburger and H. Grabert, Exact -number representation of non-Markovian quantum dissipation, Phys. Rev. Lett. 88, 170407 (2002).
- J. T. Stockburger, Simulating spin-boson dynamics with stochastic Liouville-von Neumann equations, Chem. Phys. 296, 159 (2004).
- Y. Tanimura, Stochastic Liouville, Langevin, Fokker-Planck, and master equation approaches to quantum dissipative systems, J. Phys. Soc. Jpn. 75, 082001 (2006).
- A. Tilloy, Time-local unraveling of non-Markovian stochastic Schrödinger equations, Quantum 1, 29 (2017).
- P. Hedegård and A. O. Caldeira, Quantum dynamics of a particle in a fermionic environment, Phys. Scr. 35, 609 (1987).
- L. Diósi and L. Ferialdi, General non-Markovian structure of Gaussian master and stochastic Schrödinger equations, Phys. Rev. Lett. 113, 200403 (2014).
- M. Cirio, P.-C. Kuo, Y.-N. Chen, F. Nori, and N. Lambert, Canonical derivation of the fermionic influence superoperator, Phys. Rev. B 105, 035121 (2022).
- H. Grabert, P. Schramm, and G.-L. Ingold, Quantum brownian motion: The functional integral approach, Phys. Rep. 168, 115 (1988).
- J. Gambetta and H. M. Wiseman, Non-Markovian stochastic Schrödinger equations: Generalization to real-valued noise using quantum-measurement theory, Phys. Rev. A 66, 012108 (2002).
- L. Diósi, Non-Markovian continuous quantum measurement of retarded observables, Phys. Rev. Lett. 100, 080401 (2008).
- H. M. Wiseman and J. M. Gambetta, Pure-state quantum trajectories for general non-Markovian systems do not exist, Phys. Rev. Lett. 101, 140401 (2008).
- N. Megier, W. T. Strunz, and K. Luoma, Continuous quantum measurement for general Gaussian unravelings can exist, Phys. Rev. Res. 2, 043376 (2020).
- S. Krönke and W. T. Strunz, Non-Markovian quantum trajectories, instruments and time-continuous measurements, J. Phys. A: Math. Theor. 45, 055305 (2012).
- Note that this is the opposite of what is commonly done in many-body physics [10, 11], due to the fact that here we are interested in the evolution of the density operator instead of the system observables.
- A. Serafini, Quantum Continuous Variables: A Primer of Theoretical Methods (CRC Press, Berlin, 2017).
- C. Gardiner and P. Zoller, Quantum Noise: A Handbook of Markovian and Non-Markovian Quantum Stochastic Methods with Applications to Quantum Optics (Springer Science & Business Media, 2004).
- A. O. Caldeira and A. J. Leggett, Path integral approach to quantum Brownian motion, Physica A 121, 587 (1983).
- K. Hepp and E. H. Lieb, On the superradiant phase transition for molecules in a quantized radiation field: The Dicke maser model, Ann. Phys. 76, 360 (1973).
- L. Ferialdi and L. Diósi, General Wick's theorem for bosonic and fermionic operators, Phys. Rev. A 104, 052209 (2021).
- L. Ferialdi, Exact closed master equation for Gaussian non-Markovian dynamics, Phys. Rev. Lett. 116, 120402 (2016).
- Y.-A. Yan and J. Shao, Equivalence of stochastic formulations and master equations for open systems, Phys. Rev. A 97, 042126 (2018).
- M. A. Lane, D. Matos, I. J. Ford, and L. Kantorovich, Exactly thermalized quantum dynamics of the spin-boson model coupled to a dissipative environment, Phys. Rev. B 101, 224306 (2020).
- A. Rivas, A. D. K. Plato, S. F. Huelga, and M. B. Plenio, Markovian master equations: A critical study, New J. Phys. 12, 113032 (2010).
- G. M. G. McCaul, C. D. Lorenz, and L. Kantorovich, Partition-free approach to open quantum systems in harmonic environments: An exact stochastic Liouville equation, Phys. Rev. B 95, 125124 (2017).
- P. Calabrese and J. Cardy, Time dependence of correlation functions following a quantum quench, Phys. Rev. Lett. 96, 136801 (2006).
- A. Silva, Statistics of the work done on a quantum critical system by quenching a control parameter, Phys. Rev. Lett. 101, 120603 (2008).
- M. Esposito, U. Harbola, and S. Mukamel, Nonequilibrium fluctuations, fluctuation theorems, and counting statistics in quantum systems, Rev. Mod. Phys. 81, 1665 (2009).
- Y. Zhou, Y. Yan, and J. Shao, Stochastic simulation of quantum dissipative dynamics, Europhys. Lett. 72, 334 (2005).
- F. Albarelli and M. G. Genoni, A pedagogical introduction to continuously monitored quantum systems and measurement-based feedback, Phys. Lett. A 494, 129260 (2024).
- G. Manzano, J. M. Horowitz, and J. M. R. Parrondo, Quantum fluctuation theorems for arbitrary environments: Adiabatic and nonadiabatic entropy production, Phys. Rev. X 8, 031037 (2018).
- J. Watrous, The Theory of Quantum Information (Cambridge University Press, Cambridge, 2018).
- A. Polkovnikov, Phase space representation of quantum dynamics, Ann. Phys. 325, 1790 (2010).
- Note that gives no sensible contributions to the fluctuations, still we cannot eliminate it from the equations since it contributes through its coupling with in the second of Eq. (71).
- C. Aron, G. Biroli, and L. F. Cugliandolo, (Non) equilibrium dynamics: A (broken) symmetry of the Keldysh generating functional, SciPost Phys. 4, 008 (2018).
- L. M. Sieberer, A. Chiocchetta, A. Gambassi, U. C. Täuber, and S. Diehl, Thermodynamic equilibrium as a symmetry of the schwinger-Keldysh action, Phys. Rev. B 92, 134307 (2015).
- A. D'Abbruzzo, V. Giovannetti, and V. Cavina, Exact non-Markovian master equations: A generalized derivation for quadratic systems, arXiv:2502.14364.