- Letter
- Open Access
Uniaxial versus biaxial pathways in one-dimensional cholesteric liquid crystals
Phys. Rev. Research 4, L032018 – Published 2 August, 2022
DOI: https://doi.org/10.1103/PhysRevResearch.4.L032018
Abstract
Cholesteric liquid crystals exhibit great morphological richness of static metastable states. Understanding the transitions between such states is key for the development of switchable devices. We show, using a quasi-one-dimensional model, that cholesterics exhibit distinct uniaxial and biaxial pathways between distinct minima. We study transitions between different layer numbers and prove, and show, that transition states are distinguished either through splay-mediated untwisting, understood through contact topology, or the presence of biaxiality. Furthermore we characterize a menagerie of additional saddle points that dictate the connectivity of the solution landscape.
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References (60)
- I. M. Tambovtsev, A. O. Leonov, I. S. Lobanov, A. D. Kiselev, and V. M. Uzdin, Topological structures in chiral media: Effects of confined geometry, Phys. Rev. E 105, 034701 (2022).
- U. Tkalec, M. Ravnik, S. Čopar, S. Žumer, and I. Muševič, Reconfigurable knots and links in chiral nematic colloids, Science 333, 62 (2011).
- J.-S. B. Tai and I. I. Smalyukh, Three-dimensional crystals of adaptive knots, Science 365, 1449 (2019).
- T. Machon and G. P. Alexander, Knotted Defects in Nematic Liquid Crystals, Phys. Rev. Lett. 113, 027801 (2014).
- T. Machon and G. P. Alexander, Knots and nonorientable surfaces in chiral nematics, Proc. Natl. Acad. Sci. USA 110, 14174 (2013).
- I. I. Smalyukh, Y. Lansac, N. A. Clark, and R. P. Trivedi, Three-dimensional structure and multistable optical switching of triple-twisted particle-like excitations in anisotropic fluids, Nat. Mater. 9, 139 (2010).
- B. G.-ge Chen, P. J. Ackerman, G. P. Alexander, R. D. Kamien, and I. I. Smalyukh, Generating the Hopf Fibration Experimentally in Nematic Liquid Crystals, Phys. Rev. Lett. 110, 237801 (2013).
- P. J. Ackerman and I. I. Smalyukh, Diversity of Knot Solitons in Liquid Crystals Manifested by Linking of Preimages in Torons and Hopfions, Phys. Rev. X 7, 011006 (2017).
- J. Eun, J. Pollard, S.-J. Kim, T. Machon, and J. Jeong, Layering transitions and metastable structures of cholesteric liquid crystals in cylindrical confinement, Proc. Natl. Acad. Sci. USA 118, e2102926118 (2021).
- G. Posnjak, S. Čopar, and I. Muševič, Hidden topological constellations and polyvalent charges in chiral nematic droplets, Nat. Commun. 8, 14594 (2017).
- J. Pollard, G. Posnjak, S. Čopar, I. Muševič, and G. P. Alexander, Point Defects, Topological Chirality, and Singularity Theory in Cholesteric Liquid-Crystal Droplets, Phys. Rev. X 9, 021004 (2019).
- A. Darmon, M. Benzaquen, S. Čopar, O. Dauchot, and T. Lopez-Leon, Topological defects in cholesteric liquid crystal shells, Soft Matter 12, 9280 (2016).
- Y. Bouligand and F. Livolant, The organization of cholesteric spherulites, J. Phys. France 45, 1899 (1984).
- A. Darmon, M. Benzaquen, D. Seč, S. Čopar, O. Dauchot, and T. Lopez-Leon, Waltzing route toward double-helix formation in cholesteric shells, Proc. Natl. Acad. Sci. USA 113, 9469 (2016).
- L. Tran, M. O. Lavrentovich, G. Durey, A. Darmon, M. F. Haase, N. Li, D. Lee, K. J. Stebe, R. D. Kamien, and T. Lopez-Leon, Change in Stripes for Cholesteric Shells via Anchoring in Moderation, Phys. Rev. X 7, 041029 (2017).
- D. B. Emerson, P. E. Farrell, J. H. Adler, S. P. MacLachlan, and T. J. Atherton, Computing equilibrium states of cholesteric liquid crystals in elliptical channels with deflation algorithms, Liq. Cryst. 45, 341 (2018).
- J.-i. Fukuda and S. Žumer, Quasi-two-dimensional skyrmion lattices in a chiral nematic liquid crystal, Nat. Commun. 2, 246 (2011).
- E. C. Gartland Jr., H. Huang, O. Lavrentovich, P. Palffy-Muhoray, I. Smalyukh, T. Kosa, and B. Taheri, Electric-field induced transitions in a cholesteric liquid-crystal film with negative dielectric anisotropy, J. Comput. Theor. Nanosci. 7, 709 (2010).
- Y. Han, J. Yin, P. Zhang, A. Majumdar, and L. Zhang, Solution landscape of a reduced Landau–de Gennes model on a hexagon, Nonlinearity 34, 2048 (2021).
- N. D. Mermin, The topological theory of defects in ordered media, Rev. Mod. Phys. 51, 591 (1979).
- G. P. Alexander, B. G.-ge Chen, E. A. Matsumoto, and R. D. Kamien, Colloquium: Disclination loops, point defects, and all that in nematic liquid crystals, Rev. Mod. Phys. 84, 497 (2012).
- V. Poenaru and G. Toulouse, The crossing of defects in ordered media and the topology of 3-manifolds, J. Phys. France 38, 887 (1977).
- T. Machon, Contact topology and the structure and dynamics of cholesterics, New J. Phys. 19, 113030 (2017).
- H. Geiges, An Introduction to Contact Topology (Cambridge University Press, Cambridge, 2008), Vol. 109.
- Y. Hu and T. Machon, Stability of highly-twisted skyrmions from contact topology, arXiv:2102.13126.
- P. G. de Gennes, The Physics of Liquid Crystals (Oxford University Press, Oxford, 1974).
- A. Majumdar, Equilibrium order parameters of nematic liquid crystals in the Landau–de Gennes theory, Euro. J. Appl. Math. 21, 181 (2010).
- J. Fukuda and S. Žumer, Cholesteric blue phases: effect of strong confinement, Liq. Cryst. 37, 875 (2010).
- The splay term contains bend distortions also.
- E. Priestly, Introduction to Liquid Crystals (Springer Science & Business Media, New York, 2012).
- N. J. Mottram and C. J. Newton, Introduction to q-tensor theory, arXiv preprint arXiv:1409.3542.
- C. F. Dietrich, P. J. Collings, T. Sottmann, P. Rudquist, and F. Giesselmann, Extremely small twist elastic constants in lyotropic nematic liquid crystals, Proc. Natl. Acad. Sci. USA 117, 27238 (2020).
- S. S. Tenishchev, A. D. Kiselev, A. V. Ivanov, and V. M. Uzdin, Multiple minimum-energy paths and scenarios of unwinding transitions in chiral nematic liquid crystals, Phys. Rev. E 100, 062704 (2019).
- S. S. Tenishchev, I. M. Tambovtcev, A. D. Kiselev, and V. M. Uzdin, Hysteresis and Fréedericksz thresholds for twisted states in chiral nematic liquid crystals: Minimum-energy path approach, J. Mol. Liq. 325, 115242 (2021).
- G. Barbero, W. Zheng, and B. Zappone, Twist transitions and force generation in cholesteric liquid crystal films, J. Mol. Liq. 267, 242 (2018).
- D. C. Wright and N. D. Mermin, Crystalline liquids: the blue phases, Rev. Mod. Phys. 61, 385 (1989).
- A. D. Kiselev and T. J. Sluckin, Twist of cholesteric liquid crystal cells: stability of helical structures and anchoring energy effects, Phys. Rev. E 71, 031704 (2005).
- A. V. Ivanov, P. F. Bessarab, E. V. Aksenova, V. P. Romanov, and V. M. Uzdin, Energy surface and minimum energy paths for Fréedericksz transitions in bistable cholesteric liquid crystals, Phys. Rev. E 93, 042708 (2016).
- K. Honda, On the classification of tight contact structures I. Geom. Topol. 4, 309 (2000).
- K. Yutaka, The classification of tight contact structures on the 3-torus, Commun. Anal. Geom. 5, 413 (1997).
- See Supplemental Material at http://link.aps.org/supplemental/10.1103/PhysRevResearch.4.L032018 for proofs of Theorems 1 and 2, details of numerical methods and optical modelling.
- P. J. Ackerman and I. I. Smalyukh, Reversal of helicoidal twist handedness near point defects of confined chiral liquid crystals, Phys. Rev. E 93, 052702 (2016).
- D. Golovaty, M. Novack, and P. Sternberg, A one-dimensional variational problem for cholesteric liquid crystals with disparate elastic constants, J. Diff. Equ. 286, 785 (2021).
- J. Pollard and G. P. Alexander, Intrinsic geometry and director reconstruction for three-dimensional liquid crystals, New J. Phys. 23, 063006 (2021).
- L. C. da Silva and E. Efrati, Moving frames and compatibility conditions for three-dimensional director fields, New J. Phys. 23, 063016 (2021).
- J. V. Selinger, Director deformations, geometric frustration, and modulated phases in liquid crystals, Annu. Rev. Condens. Matter Phys. 13, 49 (2022).
- J. V. Selinger, Interpretation of saddle-splay and the Oseen-Frank free energy in liquid crystals, Liq. Cryst. Rev. 6, 129 (2018).
- T. Machon and G. P. Alexander, Umbilic Lines in Orientational Order, Phys. Rev. X 6, 011033 (2016).
- X. Tang and J. V. Selinger, Minimization principle for shear alignment of liquid crystals, Phys. Rev. E 101, 032701 (2020).
- P. Pieranski and M. H. Godinho, Tropisms of the dowser texture, Materials 13, 4681 (2020).
- S. Čopar, Ž. Kos, T. Emeršič, and U. Tkalec, Microfluidic control over topological states in channel-confined nematic flows, Nat. Commun. 11, 1 (2020).
- A. Majumdar and A. Zarnescu, Landau–de Gennes theory of nematic liquid crystals: the Oseen–Frank limit and beyond, Arch. Ration. Mech. Anal. 196, 227 (2010).
- J. Milnor, Morse Theory (Princeton University Press, Princeton, NJ, 1963).
- J. Yin, L. Zhang, and P. Zhang, High-index optimization-based shrinking dimer method for finding high-index saddle points, SIAM J. Sci. Comput. 41, A3576 (2019).
- J. Yin, Y. Wang, J. Z. Y. Chen, P. Zhang, and L. Zhang, Construction of a Pathway Map on a Complicated Energy Landscape, Phys. Rev. Lett. 124, 090601 (2020).
- D. Henao, A. Majumdar, and A. Pisante, Uniaxial versus biaxial character of nematic equilibria in three dimensions, Calc. Var. Partial Differ. Equ. 56, 55 (2017).
- Z.-g. Zheng, Y. Li, H. K. Bisoyi, L. Wang, T. J. Bunning, and Q. Li, Three-dimensional control of the helical axis of a chiral nematic liquid crystal by light, Nature (London) 531, 352 (2016).
- P. Goldbart and P. Ao, Intrinsic Torsional Viscosity of Nematic Liquid Crystals, Phys. Rev. Lett. 64, 910 (1990).
- P. Goldbart and P. Ao, Intrinsic torsional viscosity in a narrow tube of nematic liquid crystal, Mol. Cryst. Liq. Cryst. 198, 455 (1991).
- C. Blanc, G. Durey, R. D. Kamien, T. Lopez-Leon, M. O. Lavrentovich, and L. Tran, Helfrich-Hurault elastic instabilities driven by geometrical frustration, arXiv:2109.14668.