Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Generation of picosecond ion pulses using laser-stimulated desorption from a tungsten nanotip

Alexander Redl1,*, Markus Goldberger1, Christoph Pachlinger1, Franz I. Pfanner2, and Richard A. Wilhelm1,†

  • *Contact author: redl@iap.tuwien.ac.at
  • †Contact author: wilhelm@iap.tuwien.ac.at

Phys. Rev. Research 7, 043317 – Published 19 December, 2025

DOI: https://doi.org/10.1103/7wdx-97pf

Abstract

We present an experimental approach to the formation of sub-100 ps ion pulses at 4.5−8.5 keV energies using laser-stimulated desorption from a tungsten nanotip at room temperature. The illumination of the tip apex with femtosecond ultraviolet laser pulses results in the ionization of adsorbed atomic and molecular species through the enhancement of a localized electric field. Unlike photoionization of atoms and molecules in the gas phase in extended volumes, determined by a typical laser focal volume, our approach naturally exploits a nanometric ionization region from tungsten nanotips with tip radii of 15−150nm and operates at a moderate optical fluence of 1011W/cm2. Time-of-flight measurements demonstrate stable and well-timed ion pulses. A systematic exploration of the ion pulse characteristics on laser parameters and loading gas pressures has been conducted. Our compact, yet simple, source design renders time-resolved ion-solid interaction studies practically possible, paving the way for future pump-probe studies.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (57)

  1. G. Dearnaley, Ion implantation, Nature (London) 256, 701 (1975).
  2. M. A. Hughes, Y. Fedorenko, B. Gholipour, J. Yao, T.-H. Lee, R. M. Gwilliam, K. P. Homewood, S. Hinder, D. W. Hewak, S. R. Elliott, and R. J. Curry, N-type chalcogenides by ion implantation, Nat. Commun. 5, 5346 (2014).
  3. J. van Donkelaar, C. Yang, A. D. C. Alves, J. C. McCallum, C. Hougaard, B. C. Johnson, F. E. Hudson, A. S. Dzurak, A. Morello, D. Spemann, and D. N. Jamieson, Single atom devices by ion implantation, J. Phys.: Condens. Matter 27, 154204 (2015).
  4. M. N. Bui, S. Rost, M. Auge, J.-S. Tu, L. Zhou, I. Aguilera, S. Blügel, M. Ghorbani-Asl, A. V. Krasheninnikov, A. Hashemi, H.-P. Komsa, L. Jin, L. Kibkalo, E. N. O'Connell, Q. M. Ramasse, U. Bangert, H. C. Hofsäss, D. Grützmacher, and B. E. Kardynal, Low-energy Se ion implantation in MoS2 monolayers, npj 2D Mater. Appl. 6, 42 (2022).
  5. B. Schmidt and K. Wetzig, Ion Beams in Materials Processing and Analysis (Springer, Vienna, 2013).
  6. S. Kretschmer and A.V. Krasheninnikov, Atomistic simulations of low energy ion irradiation of 2D materials: From ab-initio molecular dynamics to simple binary collision model, Phys. Rev. Mater. 8, 114003 (2024).
  7. K. Nordlund, Historical review of computer simulation of radiation effects in materials, J. Nucl. Mater. 520, 273 (2019).
  8. M. C. Fischer, J. W. Wilson, F. E. Robles, and W. S. Warren, Invited review article: Pump-probe microscopy, Rev. Sci. Instrum. 87, 031101 (2016).
  9. A. Duvenbeck, B. Weidtmann, and A. Wucher, Predicting kinetic electron emission in molecular dynamics simulations of sputtering, J. Phys. Chem. C 114, 5715 (2010).
  10. A. Wucher and A. Duvenbeck, Kinetic excitation of metallic solids: Progress towards a microscopic model, Nucl. Instrum. Methods Phys. Res. Sect. B 269, 1655 (2011).
  11. P. Kung, H.-c. Lihn, H. Wiedemann, and D. Bocek, Generation and measurement of 50-fs (rms) electron pulses, Phys. Rev. Lett. 73, 967 (1994).
  12. H. Niikura, F. Légaré, R. Hasbani, A. D. Bandrauk, M. Y. Ivanov, D. M. Villeneuve, and P. B. Corkum, Sub-laser-cycle electron pulses for probing molecular dynamics, Nature (London) 417, 917 (2002).
  13. C. Höhr, D. Fischer, R. Moshammer, A. Dorn, and J. Ullrich, A subnanosecond pulsed ion source for micrometer focused ion beams, Rev. Sci. Instrum. 79, 053102 (2008).
  14. B. Dromey, M. Coughlan, L. Senje, M. Taylor, S. Kuschel, B. Villagomez-Bernabe, R. Stefanuik, G. Nersisyan, L. Stella, J. Kohanoff, M. Borghesi, F. Currell, D. Riley, D. Jung, C.-G. Wahlström, C. Lewis, and M. Zepf, Picosecond metrology of laser-driven proton bursts, Nat. Commun. 7, 10642 (2016).
  15. L. Kalkhoff, A. Golombek, M. Schleberger, K. Sokolowski-Tinten, A. Wucher, and L. Breuer, Path to ion-based pump-probe experiments: Generation of 18 picosecond KeV Ne ion pulses from a cooled supersonic gas beam, Phys. Rev. Res. 5, 033106 (2023).
  16. A. Golombek, L. Danzig, and A. Wucher, Characterization of a supersonic gas jet via laser-induced photoelectron ionization, Nucl. Instrum. Methods Phys. Res. Sect. B 480, 1 (2020).
  17. E. Ntemou, R. Holeňák, D. Wessman, and D. Primetzhofer, Picosecond pulsed beams of light and heavy keV ions at the time-of-flight medium energy ion scattering system at Uppsala University, Nucl. Instrum. Methods Phys. Res. Sect. B 556, 165494 (2024).
  18. M. C. C. Mihaila, G. L. Szabo, A. Redl, M. Goldberger, A. Niggas, and R. A. Wilhelm, Generation of ultrashort ion pulses from ultrafast electron-stimulated desorption, Phys. Rev. Res. 6, L032066 (2024).
  19. R. F. Haglund, Mechanisms of laser-induced desorption and ablation, in Laser Ablation and Desorption, edited by J. C. Miller and R.F. Haglund (Academic Press, Nashville, Tennessee, 1997), Vol. 30, pp. 15–138.
  20. B. Gault, A. Chiaramonti, O. Cojocaru-Mirédin, P. Stender, R. Dubosq, C. Freysoldt, S. K. Makineni, T. Li, M. Moody, and J. M. Cairney, Atom probe tomography, Nat. Rev. Methods Prim. 1, 51 (2021).
  21. D. A. Cremers and L. J. Radziemski, Handbook of Laser‐Induced Breakdown Spectroscopy (John Wiley & Sons Ltd, England, 2006).
  22. A.W. Miziolek, V. Palleschi, and I. Schechter, Laser-Induced Breakdown Spectroscopy (LIBS) (Cambridge University Press, New York, 2006).
  23. M. Krüger, M. Schenk, and P. Hommelhoff, Attosecond control of electrons emitted from a nanoscale metal tip, Nature (London) 475, 78 (2011).
  24. P. Hommelhoff, Y. Sortais, A. Aghajani-Talesh, and M. A. Kasevich, Field emission tip as a nanometer source of free electron femtosecond pulses, Phys. Rev. Lett. 96, 077401 (2006).
  25. H. Yanagisawa, T. Greber, C. Hafner, and J. Osterwalder, Laser-induced field emission from a tungsten nanotip by circularly polarized femtosecond laser pulses, Phys. Rev. B 101, 045406 (2020).
  26. L. Bartolini, A. Poletti, R. Marks, E. Verlato, F. Paolucci, S. Rapino, and C. Albonetti, Revised electrochemical etching system for a reproducible fabrication of ultra-sharp tungsten tips, J. Appl. Electrochem. 51, 551 (2021).
  27. Monaco 1035 Datasheet, Coherent Corp. (2023), accessed 17 April 2025.
  28. L.-H. Hong, B.-Q. Chen, C.-Y. Hu, and Z.-Y. Li, Spatial–temporal evolution of ultrashort laser pulse second Harmonic generation in β-barium borate (β-BBO) crystal, J. Appl. Phys. 129, 233102 (2021).
  29. D. J. Manura and D. A. Dahl, SIMION Software Package, Version 8.1 (2014).
  30. T. Engel and R. Gomer, Adsorption of inert gases on tungsten: Measurements on single crystal planes, J. Chem. Phys. 52, 5572 (1970).
  31. D. Nguyen-Manh and S. Dudarev, Trapping of he clusters by inert-gas impurities in tungsten: First-principles predictions and experimental validation, Nucl. Instrum. Methods Phys. Res. Sect. B 352, 86 (2015).
  32. J. Byskov-Nielsen, J.-M. Savolainen, M. S. Christensen, and P. Balling, Ultra-short pulse laser ablation of metals: Threshold fluence, incubation coefficient and ablation rates, Appl. Phys. A 101, 97 (2010).
  33. T. Genieys, M. Sentis, and O. Utéza, Measurement of ultrashort laser ablation of four metals (Al, Cu, Ni, W) in the single-pulse regime, Adv. Opt. Technol. 9, 131 (2020).
  34. S. Mittelmann, J. Riedlinger, B. Buchner, T. Schwarz-Selinger, M. Mayer, and G. Pretzler, Ablation characteristics of tungsten with ultra-short laser pulses, J. Appl. Phys. 136, 103103 (2024).
  35. J. Byskov-Nielsen, J.-M. Savolainen, M. S. Christensen, and P. Balling, Ultra-short pulse laser ablation of copper, silver and tungsten: Experimental data and two-temperature model simulations, Appl. Phys. A 103, 447 (2011).
  36. P. Lickschat, D. Metzner, and S. Weißmantel, Fundamental investigations of ultrashort pulsed laser ablation on stainless steel and cemented tungsten carbide, Int. J. Adv. Manuf. Technol. 109, 1167 (2020).
  37. T. T. Tsong and T. J. Kinkus, Energy distributions of pulsed-laser field-desorbed gaseous ions and field-evaporated metal ions: A direct time-of-flight measurement, Phys. Rev. B 29, 529 (1984).
  38. D. Biswas, A universal formula for the field enhancement factor, Phys. Plasmas 25, 043113 (2018).
  39. D. J. Harvey, Mass spectrometric detectors for gas chromatography, in Gas Chromatography, Handbooks in Separation Science, edited by C.F. Poole, 2nd ed. (Academic Press, Amsterdam, 2021), Chapter 14, pp. 399–424.
  40. S. E. Egorov, V. S. Letokhov, and E. V. Moskovets, Laser-stimulated field desorption of molecular ions from a tungsten emitter, Appl. Phys. B 45, 53 (1988).
  41. H. Zacharias, G. Eichhorn, R. Schliesing, and K. Al-Shamery, Polarization dependence in the UV laser desorption of NO from NiO (100), Appl. Phys. B: Lasers Opt. 68, 605 (1999).
  42. K.W. Kolasinski, Surface Science (John Wiley & Sons Ltd, United Kingdom, 2012).
  43. I. Langmuir, The adsorption of gases on plane surfaces of glass, MICA and platinum, J. Am. Chem. Soc. 40, 1361 (1918).
  44. A. Rodríguez-Fernández, L. Bonnet, P. Larrégaray, and R. D. Muiño, Ab initio molecular dynamics of hydrogen on tungsten surfaces, Phys. Chem. Chem. Phys. 23, 7919 (2021).
  45. J. J. Yeh, Atomic Calculation of Photoionization Cross-sections and Asymmetry Parameters (Gordon and Breach Science Publishers, Langhorne, PE, USA, 1993).
  46. J. J. Yeh and I. Lindau, Atomic subshell photoionization cross sections and asymmetry parameters: 1≦Z≦103, At. Data Nucl. Data Tables 32, 1 (1985).
  47. K. Irikura, Electron-impact cross section for ionization and excitation, NIST Standard Reference Database 107 (1997), doi: 10.18434/T4KK5C.
  48. P. J. Estrup and J. Anderson, Chemisorption of hydrogen on tungsten (100), J. Chem. Phys. 45, 2254 (1966).
  49. H. F. Busnengo and A. E. Martínez, H2 chemisorption on W(100) and W(110) surfaces, J. Phys. Chem. C 112, 5579 (2008).
  50. J.K. Roberts, Adsorption of nitrogen on tungsten, Nature (London) 137, 659 (1936).
  51. A. Mazumdar and H.-W. Wassmuth, Mass-spectrometric study of the chemisorption of oxygen on tungsten under transient and steady-state desorption conditions, Surf. Sci. 30, 617 (1972).
  52. E. Zaremba and W. Kohn, Theory of helium adsorption on simple and noble-metal surfaces, Phys. Rev. B 15, 1769 (1977).
  53. P. Linstrom and W. Mallard, NIST chemistry webbook (standard reference database number 69) (2025), doi: 10.18434/T4D303.
  54. R.W. Boyd, Nonlinear Optics, 4th ed. (Elsevier, United Kingdom, 2020).
  55. C. Oberdorfer, S. M. Eich, and G. Schmitz, A full-scale simulation approach for atom probe tomography, Ultramicroscopy 128, 55 (2013).
  56. G. Hlawacek, V. Veligura, R. van Gastel, and B. Poelsema, Helium Ion microscopy, J. Vac. Sci. Technol. B 32, 020801 (2014).
  57. A. Redl, M. Goldberger, C. Pachlinger, F. Pfanner, and R. A. Wilhelm, Generation of Picosecond Ion Pulses Using Laser-Stimulated Desorption from a Tungsten Nanotip - Dataset [Data set], TU Wien, (2025), https://doi.org/10.48436/71sdw-ezf55.

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation