Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Distinction of time-reversal-like degeneracy by electronic transport in Ce3MgBi5

Yi-Yan Wang1,2, Ping Su1, Kai-Yuan Hu1, Yi-Ran Li1, Na Li1, Hui Liang1, Ying Zhou1, Dan-Dan Wu1, Yan Sun1 et al.

Qiu-Ju Li3, Xia Zhao4, Peng-Jie Guo5,*, and Xue-Feng Sun1,†

  • 1Anhui Provincial Key Laboratory of Magnetic Functional Materials and Devices, Institutes of Physical Science and Information Technology, Anhui University, Hefei, Anhui 230601, China
  • 2Key Laboratory of Materials Physics, Ministry of Education, School of Physics, Zhengzhou University, Zhengzhou 450001, China
  • 3School of Physics, Anhui University, Hefei, Anhui 230601, China
  • 4School of Physical Sciences, University of Science and Technology of China, Hefei, Anhui 230026, China
  • 5School of Physics and Key Laboratory of Quantum State Construction and Manipulation (Ministry of Education), Renmin University of China, Beijing 100872, China

  • *Contact author: guopengjie@ruc.edu.cn
  • †Contact author: xfsun@ahu.edu.cn

Phys. Rev. Research 8, 033195 – Published 17 August, 2026

DOI: https://doi.org/10.1103/1zq3-h31c

Abstract

We report the discovery of a compound, Ce3MgBi5, and reveal the hidden time-reversal-like degenerate states within it. Ce3MgBi5 is an antiferromagnet with the distorted kagome lattice of Ce atoms, in which several fractional magnetization plateaus emerge with the increase of magnetic field. At the 1/2 magnetization plateau, obvious hysteresis has been observed in the magnetoresistance and Hall resistivity during the rise and fall of the magnetic field. However, hysteresis vanishes in the corresponding measurements of magnetization, indicating the existence of degenerate states with the same net magnetization but different electronic transport properties. The degenerate states can be connected by the time-reversal-like operation. In addition, by comparing with HoAgGe, it is suggested that the special crystal structure in Ce3MgBi5 may have a shielding effect on the time-reversal-like operation, thereby affecting the distinction of degenerate states. Our work establishes Ce3MgBi5 as an example of utilizing electronic transport properties to identify and distinguish hidden symmetries in frustrated magnetic systems.

View figure in article

Physics Subject Headings (PhySH)

Article Text

Supplemental Material

References (40)

  1. S. K. Ghosh, M. Smidman, T. Shang, J. F. Annett, A. D. Hillier, J. Quintanilla, and H. Yuan, Recent progress on superconductors with time-reversal symmetry breaking, J. Phys.: Condens. Matter 33, 033001 (2021).
  2. C. Herring, Effect of time-reversal symmetry on energy bands of crystals, Phys. Rev. 52, 361 (1937).
  3. M. Z. Hasan and C. L. Kane, Colloquium: Topological insulators, Rev. Mod. Phys. 82, 3045 (2010).
  4. Y. Ando, Topological insulator materials, J. Phys. Soc. Jpn. 82, 102001 (2013).
  5. X. Wan, A. M. Turner, A. Vishwanath, and S. Y. Savrasov, Topological semimetal and Fermi-arc surface states in the electronic structure of pyrochlore iridates, Phys. Rev. B 83, 205101 (2011).
  6. S. Wang, X. Feng, J.-Z. Fang, J.-P. Peng, Z.-T. Sun, J.-J. Yang, L. Xiong, J. Liu, J.-J. Zhao, N. Kang, X.-S. Wu, Z. Zhang, X. Fu, K. T. Law, B.-C. Lin, and D. Yu, Unconventional hysteresis due to time-reversal symmetry breaking superconductivity in RbV3Sb5, Nat. Commun. 17, 1310 (2026).
  7. K. Zhao, Y. Tokiwa, H. Chen, and P. Gegenwart, Discrete degeneracies distinguished by the anomalous Hall effect in a metallic kagome ice compound, Nat. Phys. 20, 442 (2024).
  8. S. Nakatsuji, N. Kiyohara, and T. Higo, Large anomalous Hall effect in a non-collinear antiferromagnet at room temperature, Nature (London) 527, 212 (2015).
  9. H. Chen, Q. Niu, and A. H. MacDonald, Anomalous Hall effect arising from noncollinear antiferromagnetism, Phys. Rev. Lett. 112, 017205 (2014).
  10. K. Zhao, T. Hajiri, H. Chen, R. Miki, H. Asano, and P. Gegenwart, Anomalous Hall effect in the noncollinear antiferromagnetic antiperovskite Mn3Ni1−xCuxN, Phys. Rev. B 100, 045109 (2019).
  11. A. K. Nayak, J. E. Fischer, Y. Sun, B. Yan, J. Karel, A. C. Komarek, C. Shekhar, N. Kumar, W. Schnelle, J. Kübler, C. Felser, and S. S. P. Parkin, Large anomalous Hall effect driven by a nonvanishing Berry curvature in the noncolinear antiferromagnet Mn3Ge, Sci. Adv. 2, e1501870 (2016).
  12. K. Zhao, H. Deng, H. Chen, K. A. Ross, V. Petříček, G. Günther, M. Russina, V. Hutanu, and P. Gegenwart, Realization of the kagome spin ice state in a frustrated intermetallic compound, Science 367, 1218 (2020).
  13. N. Li, Q. Huang, X. Y. Yue, S. K. Guang, K. Xia, Y. Y. Wang, Q. J. Li, X. Zhao, H. D. Zhou, and X. F. Sun, Low-temperature transport properties of the intermetallic compound HoAgGe with a kagome spin-ice state, Phys. Rev. B 106, 014416 (2022).
  14. E. Liu, Electronic transport probes a hidden state, Nat. Phys. 20, 356 (2024).
  15. J. F. Khoury, B. Han, M. Jovanovic, R. Singha, X. Song, R. Queiroz, N.-P. Ong, and L. M. Schoop, A class of magnetic topological material candidates with hypervalent Bi chains, J. Am. Chem. Soc. 144, 9785 (2022).
  16. Z.-K. Yi, Z.-F. Ouyang, P.-J. Guo, H. Liang, Y.-R. Li, P. Su, N. Li, Y. Zhou, D.-D. Wu, Y. Sun, X.-Y. Yue, Q.-J. Li, S.-G. Wang, X.-F. Sun, and Y.-Y. Wang, Extremely large anomalous Hall conductivity and unusual axial diamagnetism in a quasi-1D Dirac material La3MgBi5, Adv. Mater. 36, 2400166 (2024).
  17. J. F. Khoury, B. Han, M. Jovanovic, R. Queiroz, X. Yang, R. Singha, T. H. Salters, C. J. Pollak, S. B. Lee, N. Ong, and L. M. Schoop, Towards 1D transport in 3D materials: SOC-induced charge-transport anisotropy in Sm3ZrBi5, Adv. Mater. 36, 2404553 (2024).
  18. X. Han, H. Pi, D. Yan, R. Zhang, Y. Li, X. Wang, Z. Dun, Z. Wang, H. L. Feng, Q. Wu, and Y. Shi, Quantum oscillations and transport evidence of topological bands in La3MgBi5 single crystals, Phys. Rev. B 108, 075157 (2023).
  19. X. He, Y. Li, Y. Ge, H. Zeng, S.-J. Song, J. Liu, S. Zou, Z. Wang, Y. Li, W. Ding, J. Dai, G.-H. Cao, X.-X. Zhang, T. Zhai, G. Xu, and Y. Luo, Rich unconventional Hall effects in a single quasi-kagome Kondo Weyl semimetal candidate Ce3TiSb5, Commun. Mater. 6, 206 (2025).
  20. Y.-Y. Wang, Z.-K. Yi, N. Li, Y.-R. Li, P. Su, Y. Zhou, D.-D. Wu, Y. Sun, Q.-J. Li, X.-Y. Yue, X. Zhao, X.-F. Sun, and H. Liang, Magnetic and electrical transport properties of quasi-one-dimensional Ln3HfBi5 single crystals (Ln = Pr, Nd, Sm), Phys. Rev. B 110, 134432 (2024).
  21. L. Duan, X. C. Wang, J. Zhang, Z. Hu, J. F. Zhao, Y. G. Feng, H. L. Zhang, H.-J. Lin, C. T. Chen, W. Wu, Z. Li, R. Wang, J. F. Zhang, T. Xiang, and C. Q. Jin, Synthesis, structure, and magnetism in the ferromagnet La3MnAs5: Well-separated spin chains coupled via itinerant electrons, Phys. Rev. B 106, 184405 (2022).
  22. L. Duan, X. Wang, F. Zhan, J. Zhang, Z. Hu, J. Zhao, W. Li, L. Cao, Z. Deng, R. Yu, H.-J. Lin, C.-T. Chen, R. Wang, and C. Jin, High-pressure synthesis, crystal structure and physical properties of a new Cr-based arsenide La3CrAs5, Sci. China Mater. 63, 1750 (2020).
  23. L. Duan, J. Zhang, X. Wang, J. Zhao, L. Cao, W. Li, Z. Deng, R. Yu, Z. Li, and C. Jin, High-pressure synthesis, structure and properties of new ternary pnictides La3TiX5 (X = P, As), J. Alloys Compd. 831, 154697 (2020).
  24. S. Hayami and H. Kusunose, Magnetic toroidal moment under partial magnetic order in hexagonal zigzag-chain compound Ce3TiBi5, J. Phys. Soc. Jpn. 91, 123701 (2022).
  25. C. Ritter, A. Pathak, R. Filippone, A. Provino, S. Dhar, and P. Manfrinetti, Magnetic ground states of Ce3TiSb5, Pr3TiSb5 and Nd3TiSb5 determined by neutron powder diffraction and magnetic measurements, J. Phys.: Condens. Matter 33, 245801 (2021).
  26. Y.-R. Li, Y.-H. Gao, X.-Q. Lu, P. Su, H. Liang, Y. Zhou, D.-D. Wu, Y. Sun, Q.-J. Li, J.-Y. Liu, S.-G. Wang, G. Chen, T.-L. Xia, N. Li, X.-F. Sun, and Y.-Y. Wang, Power-law scaling of low-temperature effective mass in La3ScBi5, Chin. Phys. B 35, 057107 (2026).
  27. M. Matin, R. Kulkarni, A. Thamizhavel, S. Dhar, A. Provino, and P. Manfrinetti, Probing the magnetic ground state of single crystalline Ce3TiSb5, J. Phys.: Condens. Matter 29, 145601 (2017).
  28. N. Gauthier, R. Sibille, V. Pomjakushin, O. S. Fjellvåg, J. Fraser, M. Desmarais, A. D. Bianchi, and J. A. Quilliam, Magnetic structure of Ce3TiBi5 and its relation to current-induced magnetization, Phys. Rev. B 109, L140405 (2024).
  29. M. Shinozaki, G. Motoyama, M. Tsubouchi, M. Sezaki, J. Gouchi, S. Nishigori, T. Mutou, A. Yamaguchi, K. Fujiwara, K. Miyoshi, and Y. Uwatoko, Magnetoelectric effect in the antiferromagnetic ordered state of Ce3TiBi5 with Ce zig-zag chains, J. Phys. Soc. Jpn. 89, 033703 (2020).
  30. K.-Y. Hu, H. Liang, N. Li, D.-D. Wu, Y. Sun, Q.-J. Li, X. Zhao, Y. Zhou, X.-F. Sun, and Y.-Y. Wang, Magnetic and electrical transport properties of Ln3ScBi5 single crystals (Ln = Pr, Nd, Sm), J. Low Temp. Phys. 222, 80 (2026).
  31. X. Han, Y. Li, M. Yang, S. Miao, D. Yan, and Y. Shi, Complex magnetic and transport properties in Pr3MgBi5: A material with distorted kagome lattice, Phys. Rev. Mater. 7, 124406 (2023).
  32. Z. Xu, Y. Wang, C. Zhang, H. Liu, X. Han, L. Wu, X. Zhang, Q. Wu, and Y. Shi, Magnetization plateau and anisotropic magnetoresistance in the frustrated Kondo-lattice compound Ce3ScBi5, Phys. Rev. B 110, 165106 (2024).
  33. K. Gornicka, B. R. Ortiz, H. Zhang, A. D. Christianson, and A. F. May, Anisotropic magnetic behavior of Nd3ScBi5 and Pr3ScBi5 single crystals, Phys. Rev. Mater. 9, 064414 (2025).
  34. Y.-R. Li, N. Li, P. Su, H. Liang, K.-Y. Hu, Y. Zhou, D.-D. Wu, Y. Sun, Q.-J. Li, X. Zhao, X.-F. Sun, and Y.-Y. Wang, Crystal structure, magnetic properties, and tunable Kondo effect in a new compound Nd5ScSb12, Chin. Phys. B 34, 067502 (2025).
  35. G. Kresse and J. Furthmüller, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set, Phys. Rev. B 54, 11169 (1996).
  36. P. E. Blöchl, Projector augmented-wave method, Phys. Rev. B 50, 17953 (1994).
  37. J. P. Perdew, K. Burke, and M. Ernzerhof, Generalized gradient approximation made simple, Phys. Rev. Lett. 77, 3865 (1996).
  38. See Supplemental Material at http://link.aps.org/supplemental/10.1103/1zq3-h31c for some additional data, including the crystallographic parameters, more magnetic and electronic transport data, etc.
  39. F. Gao, J. Sheng, W. Ren, Q. Zhang, X. Luo, J. Qi, M. Cong, B. Li, L. Wu, and Z. Zhang, Incommensurate spin density wave and magnetocaloric effect in the metallic triangular lattice HoAl2Ge2, Phys. Rev. B 106, 134426 (2022).
  40. J. Guo, X. Zhao, S. Ohira-Kawamura, L. Ling, J. Wang, L. He, K. Nakajima, B. Li, and Z. Zhang, Magnetic-field and composition tuned antiferromagnetic instability in the quantum spin-liquid candidate NaYbO2, Phys. Rev. Mater. 4, 064410 (2020).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation