• Accepted Paper

Emergence of novel ferromagnetic coupling in RE2Fe17 (RE=Gd, Dy and Ho) induced by dense hydrogenation under high pressures

Yoshimasa Date, Naoki Ishimatsu, Kouji Sakaki, Yumiko Nakamura, Naomi Kawamura, Hirokazu Kadobayashi, Saori Kawaguchi, Satoshi Nakano, Sayako Inoué, and Nobuo Nakajima

Phys. Rev. Materials - Accepted 6 November, 2026

DOI: https://doi.org/10.1103/72z3-fyfb

Abstract

Hydrogenation effects on the magnetic structure and crystal structure of ferrimagnetic iron-rich compounds, RE2Fe17 (RE=Gd, Dy, and Ho), were investigated by using X-ray powder diffraction and X-ray magnetic circular dichroism (XMCD) as a function of pressure in a hydrogen atmosphere. Before hydrogenation, iron 3d moments of RE2Fe17 align parallel to the external magnetic field, whereas RE 4f moments align antiparallel. Hydrogenation-induced reversal of the RE 4f magnetic moments was observed as changes in the sign of XMCD spectra at the RE L2,3 edges. On the other hand, XMCD spectra at the Fe K-edge indicated that Fe magnetic moments preserve their direction parallel to the magnetic field. Consequently, hydrogenation induces the ferromagnetic coupling, where both RE 4f and iron 3d moments aligned parallel to the external magnetic field. Dense hydrogen content exceeding two hydrogen atoms per metal atom was estimated when the ferromagnetic coupling appeared. The hydrogenation effect on the magnetic coupling of the interatomic Fe 3d-RE 5d electron orbitals plays an important role in the reversal of the RE 4f magnetic moments.

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