Non-trivial Berry phase and Shubnikov-de Haas oscillations in single-crystal
Phys. Rev. Materials 10, 014206 – Published 30 January, 2026
DOI: https://doi.org/10.1103/qjm5-dcb7
Abstract
We present a comprehensive study of the electronic transport properties and first-principles calculations of , a parkerite-structured compound, revealing its topological nodal-line semimetal behavior. Shubnikov-de Haas oscillations confirm the presence of Dirac-like fermions, supported by a nontrivial -Berry phase, low effective mass (), and a high Fermi velocity (). Weak-field magnetoconductivity exhibits a characteristic () dependence, indicative of nodal-line features. The longitudinal resistivity fits well with the Bloch-Gruneisen-Mott model, pointing to multiple scattering mechanisms, including electron-phonon and Mott-interband. Hall effect and Boltzmann transport theory analyses suggest coexistence of electron and hole carriers. Density-functional theory calculations show a bulk band inversion between Ni- and Bi- orbitals without spin-orbit coupling, and the surface states merge into the bulk around 0.43 eV, further supporting the topologically nontrivial nature of .