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    Non-trivial Berry phase and Shubnikov-de Haas oscillations in single-crystal Ni3Bi2Se2

    Sanand Kumar Pradhan1, Sharadnarayan Pradhan1, Priyanath Mal2, P. Rambabu1, Archana Lakhani3, Bipul Das4, Bheema Lingam Chittari5, G. R. Turpu1, and Pradip Das1,*

    • *Contact author: pradipd.iitb@gmail.com

    Phys. Rev. Materials 10, 014206 – Published 30 January, 2026

    DOI: https://doi.org/10.1103/qjm5-dcb7

    Abstract

    We present a comprehensive study of the electronic transport properties and first-principles calculations of Ni3Bi2Se2, a parkerite-structured compound, revealing its topological nodal-line semimetal behavior. Shubnikov-de Haas oscillations confirm the presence of Dirac-like fermions, supported by a nontrivial π-Berry phase, low effective mass (m*∼0.18me), and a high Fermi velocity (vF∼2.93×105ms−1). Weak-field magnetoconductivity exhibits a characteristic −ln(B) dependence, indicative of nodal-line features. The longitudinal resistivity fits well with the Bloch-Gruneisen-Mott model, pointing to multiple scattering mechanisms, including electron-phonon and Mott-interband. Hall effect and Boltzmann transport theory analyses suggest coexistence of electron and hole carriers. Density-functional theory calculations show a bulk band inversion between Ni-d and Bi-p orbitals without spin-orbit coupling, and the surface states merge into the bulk around 0.43 eV, further supporting the topologically nontrivial nature of Ni3Bi2Se2.

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