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    Structural modulation, physical properties, and electronic band structure of the kagome metal UCr6Ge6

    Z. W. Riedel1, P. A. E. Murgatroyd1, C. S. Kengle1, P. M. T. Vianez1, A. Schmidt2, X. Du3, K. Allen1,4, T. K. Kim5, C. Lane1 et al.

    Ying Wai Li1, Jian-Xin Zhu1, J. D. Thompson1, F. Ronning1, S. M. Thomas1, P. F. S. Rosa1, and E. D. Bauer1

    Phys. Rev. Materials 10, 055002 – Published 11 May, 2026

    DOI: https://doi.org/10.1103/pcrk-3225

    Abstract

    The chemical flexibility of the RM6X6 stoichiometry, where an f-block element is intercalated in the CoSn structure type, allows for the tuning of flatbands associated with kagome lattices to the Fermi level and for emergent phenomena due to interactions between the f- and d-electron lattices. Yet, 5f members of the “166” compounds are underrepresented compared with 4f members. Here, we report single-crystal growth of UCr6Ge6, which crystallizes in a monoclinically distorted Y0.5Co3Ge3-type structure. The real-space character of the modulation, which is unique within the RM6X6 family, is approximated by a 3×1×2 supercell of the average monoclinic cell. The compound has kagome-lattice flatbands near the Fermi level and a moderately enhanced electronic heat capacity, as evidenced by its low-temperature Sommerfeld coefficient (γ=86.5 mJ mol−1 K−2) paired with band structure calculations. The small, isotropic magnetization and featureless resistivity of UCr6Ge6 suggest itinerant uranium 5f electrons and Pauli paramagnetism. Angle-resolved photoemission spectroscopy results provide evidence for uranium 5f weight at the Fermi level and for a flatband near the Fermi level associated with the chromium 3d kagome lattice. The isotropic magnetic behavior of the uranium 5f electrons starkly contrasts with localized behavior in other uranium 166 compounds, highlighting the high tunability of the magnetic ground state across the material family.

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