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    Antiferromagnetic order and crystalline electric field in noncentrosymmetric hexagonal RERu6As4 (RE=Sm and Yb)

    Yusuke Hirose1,2,*, Hiroki Tsukui3, Yuta Kato3, Rina Shono3, Fuminori Honda4, Dai Aoki5, and Rikio Settai2

    • *Contact author: hirose.yusuke@jaea.go.jp

    Phys. Rev. Materials 10, 084407 – Published 24 August, 2026

    DOI: https://doi.org/10.1103/nr4t-wypp

    Abstract

    We investigated the electronic properties of RERu6As4(RE=La, Ce, Sm, and Yb) using single-crystalline samples grown by the Bi-flux method. These compounds crystallize in the noncentrosymmetric hexagonal LiCo6P4-type structure, featuring chain-like and triangular arrangements of magnetic RE ions. From the electrical resistivity, magnetic susceptibility, and specific heat measurements, we have found that SmRu6As4 and YbRu6As4 order antiferromagnetically below the Néel temperature of 1.5 and 9.5 K, respectively. Despite the relatively high transition temperature of YbRu6As4, its magnetic field-temperature phase diagram reveals that the antiferromagnetic state collapses at a low field of μ0Hc=1.7T, accompanied by an unusual nonlinear magnetization. The small critical field and characteristic magnetization curve in YbRu6As4 suggest an important role of competing interactions associated with magnetic frustration.

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