Antiferromagnetic order and crystalline electric field in noncentrosymmetric hexagonal
Phys. Rev. Materials 10, 084407 – Published 24 August, 2026
DOI: https://doi.org/10.1103/nr4t-wypp
Abstract
We investigated the electronic properties of using single-crystalline samples grown by the Bi-flux method. These compounds crystallize in the noncentrosymmetric hexagonal -type structure, featuring chain-like and triangular arrangements of magnetic ions. From the electrical resistivity, magnetic susceptibility, and specific heat measurements, we have found that and order antiferromagnetically below the Néel temperature of 1.5 and 9.5 K, respectively. Despite the relatively high transition temperature of , its magnetic field-temperature phase diagram reveals that the antiferromagnetic state collapses at a low field of , accompanied by an unusual nonlinear magnetization. The small critical field and characteristic magnetization curve in suggest an important role of competing interactions associated with magnetic frustration.