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    Canted ferromagnetic order in a distorted triangular-lattice magnet Na2SrCo(VO4)2

    Tengfei Peng1, Xiaobai Ma2, Xinyang Liu1,3, Feiran Shen4, Lunhua He3,4,5, Junsen Xiang3, Wenyun Yang6, and Wentao Jin1,*

    • *Contact author: wtjin@buaa.edu.cn

    Phys. Rev. Materials 10, 014407 – Published 23 January, 2026

    DOI: https://doi.org/10.1103/npb4-kvrh

    Abstract

    Triangular-lattice cobaltates with glaserite-type X2YCo(TO4)2 structure provide an ideal platform to investigate intriguing quantum magnetism. Here we report a comprehensive study of the structural and magnetic properties of a triangular-lattice cobalt vanadate Na2SrCo(VO4)2. Room-temperature x-ray and neutron powder diffraction confirm that Na2SrCo(VO4)2 crystallizes in the monoclinic P21/c space group with slightly distorted triangular layers of Co2+ ions. Magnetization measurements reveal a ferromagnetic transition at TC≈3.4K, where a sharp λ-type anomaly is observed in the specific heat. The magnetic entropy recovered up to 55 K approaches 90% of Rln2, supporting an effective spin-1/2 state of Co2+ ions at low temperature. Neutron diffraction at 2.3 K (below TC) further confirms a long-range canted ferromagnetic order with the Co2+ moments aligned in the ac plane and the ordered moment size of ∼ 2.6 μB. Comparing with its sister compounds with a trigonal symmetry, Na2BaCo(VO4)2 with a collinear ferromagnetic structure and the recently discovered spin supersolid candidate Na2BaCo(PO4)2 with a distinct Y-like antiferromagnetic ground state, this study indicates the decisive role of the TO4 tetrahedra in tuning exchange interactions and contrasting magnetic behaviors of these glaserite-structure compounds.

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