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    Magnetic field-induced tetragonal domain alignment and structural distortion in the spin-orbit-coupled insulator Ba2MgReO6

    Toshihiko Muroi1, Daigorou Hirai2, Hajime Sagayama3, Taka-hisa Arima4, and Zenji Hiroi1

    • 1Institute for Solid State Physics, University of Tokyo, Chiba 277-8581, Japan
    • 2Department of Applied Physics, Nagoya University, Aichi 464-8603, Japan
    • 3Institute of Materials Structure Science, High Energy Accelerator Research Organization, Ibaraki 305-0801, Japan
    • 4Department of Advanced Materials Science, University of Tokyo, Chiba 277-8561, Japan

    Phys. Rev. Materials 9, 084415 – Published 26 August, 2025

    DOI: https://doi.org/10.1103/lxnm-s9xl

    Abstract

    We investigate how magnetic fields affect the quadrupolar domains in the 5d transition-metal oxide Ba2MgReO6 (BMRO), which crystallizes in the double-perovskite structure. At Tq=33 K, BMRO undergoes a quadrupolar-order transition, resulting in a cubic-to-tetragonal structural change, followed by a magnetic transition to a canted antiferromagnetic phase at Tm=18 K. These transitions cause the formation of three types of tetragonal domains below Tq and four types of magnetic domains for each tetragonal domain below Tm. One tetragonal domain is preferred when the magnetic field is applied along the cubic [1 1 0] direction, and its volume fraction exceeds 80% at 10 K. The magnetic-field direction has a significant impact on domain selection. It is revealed that a magnetic field induces not only magnetic but also structural domain switching via unique spin–lattice coupling in the spin–orbit-entangled quadrupolar-order state in BMRO.

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