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    Competing interactions and the effects of uniaxial out-of-plane perturbations in the honeycomb antiferromagnet Na2Co2TeO6

    J. Arneth1,*, R. Kalaivanan2,3, R. Sankar2, K.-Y. Choi4, and R. Klingeler1,†

    • 1Kirchhoff Institute for Physics, Heidelberg University, INF 227, D-69120 Heidelberg, Germany
    • 2Institute of Physics, Academia Sinica, Taipei 11529, Taiwan
    • 3Department of Physics and Chemistry, Prairie View A&M University, Prairie View TX 77446, USA
    • 4Department of Physics, Sungkyunkwan University, Suwon 16419, Republic of Korea

    • *Contact author: jan.arneth@kip.uni-heidelberg.de
    • †Contact author: klingeler@kip.uni-heidelberg.de

    Phys. Rev. Materials 9, 094001 – Published 18 September, 2025

    DOI: https://doi.org/10.1103/gxyn-xqdv

    Abstract

    Despite exhibiting magnetic long-range order below TN=26.7K, the honeycomb cobaltate Na2Co2TeO6 is predicted to enter a Kitaev spin liquid state when subjected to small external perturbations. While most of the reported literature investigates the effects of magnetic fields applied parallel to the honeycomb layers, we present high-resolution capacitance dilatometry studies for fields perpendicular to the Co-planes up to 15 T. Grüneisen analysis reveals the effect of uniaxial out-of-plane strain and shows that antiferromagnetic order in Na2Co2TeO6 is stabilized at a rate of ∂TN/∂pc=0.28(5) K/GPa. Further, failure of the Grüneisen scaling at low temperatures around Tcr≃7.5K demonstrates the presence of competing energy scales. In contrast to an only weak field dependence of the anomaly at TN, a broad hump at Tcr(B=0T) evolves into a sharp peak at high fields applied B∥c. Our magnetostriction data show that a kink in the magnetization at BC≃4.6T is accompanied by an inflection point in the field-induced length changes, which is likely related to weak unequal spin canting. All observed phenomena leave their signatures in the magnetoelastic phase diagram as constructed by our experimental results.

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