Non-fullerene acceptors such as Y6 have enabled high-efficiency organic photovoltaic devices and motivated the development of single-component architectures; however, the microscopic mechanisms governing exciton transport and charge dissociation remain under active investigation. In particular, the interplay between Frenkel and charge-transfer excitations and their coupling to environmental fluctuations complicates the description of light absorption and subsequent exciton dynamics. Here, ultrafast transient absorption spectroscopy is used to probe exciton quenching dynamics in Y6 films interfaced with hole-transport layers. To interpret these measurements, we develop an analytical model based on hybrid Frenkel-charge-transfer states that enables direct extraction of intermolecular electronic couplings, charge-transfer character, and system-bath interaction strengths from experimental data. The analysis reveals a substantial charge-transfer admixture of 20–40 % in the exciton states and identifies delocalization-mediated transport on the short length and time scales probed by the measurements. Consistent with this interpretation, the corresponding quenching dynamics occur on a $\sim 1$ ps timescale within $\sim 4\mathrm{nm}$ of the interface, suggesting a short-range injection mechanism facilitated by exciton delocalization. In addition to providing physical parameters for Y6, these results establish a quantitative framework that connects spectroscopic observables to microscopic transport mechanisms and can be generalized to other non-fullerene acceptors.

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• Chemical Physics & Physical Chemistry
• Photochemistry