- Letter
Persistence of charge density wave fluctuations in the absence of long-range order in a hole-doped kagome metal
Phys. Rev. Materials 10, L022001 – Published 5 February, 2026
DOI: https://doi.org/10.1103/fzx6-hd1b
Abstract
The kagome metals (, Rb, Cs) exhibit a complex interplay between charge density wave (CDW) order and superconductivity. In this study, we use ultrafast coherent phonon spectroscopy to probe the evolution of CDW order in hole-doped across a broad range of compositions (). While thermodynamic and diffraction measurements show long-range CDW order vanishes above , we observe persistent signatures of CDW fluctuations up to the highest doping levels, with correlation times on the order of several picoseconds. These results indicate the presence of a robust fluctuating charge order that survives well beyond the established CDW phase boundary. Furthermore, these fluctuations are enhanced near a doping-tuned quantum phase transition at , which coincides with a local minimum in the superconducting double-dome. Additional measurements on Ti- and K-substituted samples confirm that this behavior is intrinsic to hole doping and not tied to disorder. Overall, our findings suggest that CDW fluctuations play a central role in the electronic phase diagram of and may mediate or compete with superconductivity.
Physics Subject Headings (PhySH)
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Quantum Phenomena in Kagome Materials
The Editors of Physical Review Materials are pleased to present the Collection on Quantum Phenomena in Kagome Materials, highlighting cutting-edge advances in theory, synthesis, properties and applications of kagome materials. The Collection is being guest-edited by Mingda Li (MIT), Xiangang Wan (Nanjing University) and Linda Ye (Caltech). Every article published in this collection underwent a rigorous peer review process, adhering to the same high standards applied to all papers. The Physical Review Materials editorial team managed the peer review and made all editorial decisions.