Epitaxial growth and superconductivity of optimally doped cuprate films
Phys. Rev. Materials 7, 074802 – Published 6 July, 2023
DOI: https://doi.org/10.1103/PhysRevMaterials.7.074802
Abstract
Superconducting infinite-layer films at optimal doping () have been epitaxially grown on (001) substrates with oxide molecular beam epitaxy. By combining x-ray diffraction and transport measurements, we have established a narrow window of growth conditions [i.e., ozone pressure, substrate temperature, ()/Cu flux ratio, and postannealing] in which the superconducting infinite-layer structure can be readily achieved while eliminating any unwanted competing phases. A smaller out-of-plane lattice constant () is found to be crucial to prompt superconductivity in the films. Thickness-dependent electrical resistivity measurements reveal superconductivity even when the film thickness is thinned down to 5 nm. Furthermore, the superconducting state of the epitaxial infinite-layer films remains remarkably stable against air exposure, providing an ideal platform to explore the high-temperature superconductivity and unusual properties in cuprates.