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    Electronic structure of the YCrB4 crystal surface, studied by micro-focused photoemission spectroscopy

    Xiaoni Zhang1, Yuki Tsujikawa1, Masashige Miyamoto1, Kazuki Yamaguchi1, Masahito Niibe1, Daisuke Nishio-Hamane1, Mei Yuan2, Kenichi Ozawa3, Masafumi Horio1 et al.

    Kunio Yubuta4, Takahiro Kondo2, and Iwao Matsuda1

    Phys. Rev. Materials 9, 095001 – Published 2 September, 2025

    DOI: https://doi.org/10.1103/5cpd-ll33

    Abstract

    We have performed a comprehensive electronic characterization of the needle-like single crystal YCrB4 metal boride, prepared by cleavage, characterized using angle-resolved photoemission spectroscopy with a microfocused beam. Our findings reveal the three-dimensional (3D) band structure of YCrB4, with band dispersions closely aligning with the first-principles calculations, confirming it is a topologically trivial insulator with a narrow band gap. Furthermore, a new metallic surface band was observed after cleavage, likely due to a space charge layer of the electron accumulation type. This study highlights the pivotal role of surface phenomena in shaping the electronic structure of YCrB4 and provides insights into the interplay between bulk and surface states, offering a path for exploring its potential applications in surface-sensitive technologies.

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