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    Network topology uniquely determines glass fragility

    D. L. Sidebottom* and D. Olabode

    • *Contact author: sidebottom@creighton.edu

    Phys. Rev. Materials 9, 105601 – Published 8 October, 2025

    DOI: https://doi.org/10.1103/2m4g-w4yk

    Abstract

    The fragility of several network-forming glasses is shown to display a single dependence on the average bond density of the topological network—a network that reflects both coarse-graining for oxide polyhedra and topological corrections for larger super-structural units. Unlike previous efforts to confirm this result, which relied on adjustable modeling, the current demonstration—involving dynamic light scattering in (Bi2O3)x(NaPO3)100−x glass melts—is achieved in the absence of any such modeling biases.

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