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    Hidden frustration in the triangular-lattice antiferromagnet NdCd3P3

    Juan R. Chamorro1,*, Steven J. Gomez Alvarado1, Dibyata Rout1, Sarah Schwarz1, Allen Scheie2, Ganesh Pokharel1,3, Alexander I. Kolesnikov4, Lukas Keller5, and Stephen D. Wilson1,†

    • *Present address: Department of Materials Science and Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA.
    • †Contact author: stephendwilson@ucsb.edu

    Phys. Rev. Materials 9, 104414 – Published 27 October, 2025

    DOI: https://doi.org/10.1103/2dcv-nkz7

    Abstract

    We report a study of the magnetic ground state and crystal electric field (CEF) scheme in the triangular-lattice antiferromagnet NdCd3P3. Combined neutron scattering, magnetization, and heat capacity measurements demonstrate that the Nd3+ moments occupying the triangular lattice in this material harbor hidden signs of frustration not detected in typical Curie-Weiss-based parametrization of the frustration index (f=ΘCW/TN). This is evidenced by a zero-field splitting of the Kramers' ground state and first excited state doublets at temperatures far in excess of TN as well as signatures of low-energy fluctuations for T≫TN. A suppression of the zero-field ordered moment relative to its field saturation value is observed, and the impacts of this magnetic frustration as well as the coexisting bond frustration in the CdP honeycomb network on the physical properties of NdCd3P3 are discussed.

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