We demonstrate coherent control over the photoelectron circular dichroism in randomly oriented chiral molecules, based on quantum interference between multiple photoionization pathways. To significantly enhance the chiral signature, we use a finite manifold of indistinguishable ($1+1^{\prime }$) resonantly enhanced multiphoton ionization pathways interfering at a common photoelectron energy but probing different intermediate states. We show that this coherent control mechanism maximizes the number of molecular states that constructively contribute to the dichroism at an optimal photoelectron energy and thus outperforms other schemes, including interference between opposite-parity pathways driven by bichromatic ($\omega$, $2\omega$) fields as well as sequential pump-probe ionization.

We present a protocol to selectively decouple, recouple, and engineer effective interactions in mesoscopic dipolar spin networks. In particular, we develop a versatile protocol that relies upon magic angle spinning to perform Hamiltonian engineering. By using global control fields in conjunction with a local actuator, such as a diamond nitrogen vacancy center located in the vicinity of a nuclear spin network, both global and local control over the effective couplings can be achieved. We show that the resulting effective Hamiltonian can be well understood within a simple, intuitive geometric picture, and corroborate its validity by performing exact numerical simulations in few-body systems. Applications of our method are in the emerging fields of two-dimensional room temperature quantum simulators in diamond platforms, as well as in molecular magnet systems.

Optically induced breaking of symmetries plays an important role in nonlinear photonics, with applications ranging from optical switching in integrated photonic circuits to soliton generation in ring lasers. In this work we study for the first time the interplay of two types of spontaneous symmetry breaking that can occur simultaneously in optical ring resonators. Specifically we investigate a ring resonator that is synchronously pumped with short pulses of light. In this system we numerically study the interplay and transition between regimes of temporal symmetry breaking (in which pulses in the resonator either run ahead or behind the seed pulses) and polarization symmetry breaking (in which the resonator spontaneously generates elliptically polarized light out of linearly polarized seed pulses). We find ranges of pump parameters for which each symmetry breaking can be independently observed, but also a regime in which a dynamical interplay takes place. Besides the fundamentally interesting physics of the interplay of different types of symmetry breaking, our work contributes to a better understanding of the nonlinear dynamics of optical ring cavities which are of interest for future applications including all-optical logic gates, synchronously pumped optical frequency comb generation, and resonator-based sensor technologies.

We report an experimental measurement of the rms temperature (${\sigma }_T$) profiles in two regions inside a large aspect ratio ($\mathrm{\Gamma }=4.2$) rectangular convection cell. It is found that, in the region where the boundary layer is sheared by a large-scale wind, ${\sigma }_T$ has a power-law dependence on the vertical distance ($z$) from the plate, whereas in the region where plumes are abundant, ${\sigma }_T$ has a logarithmic dependence on $z$. The power-law profile may be understood by balancing the inertia force and the viscous force in the equations of motion, and the logarithmic profile may be understood in terms of the balance between the buoyancy and the inertia forces. When normalized by a convective temperature scale, ${\theta }_{*}$, the profiles of ${\sigma }_T$ collapse onto a single curve for different values of the Rayleigh number. This shows that the convective temperature first proposed by Deardorff is the suitable temperature scale outside the thermal boundary layer for both logarithmic and power-law profiles. Our finding suggests a strong connection between plumes and the logarithmic rms temperature profile. The present Letter reveals that multiple force balance mechanisms can coexist in the bulk of highly turbulent flows.

We report the experimental generation of highly energetic carbon ions up to 48 MeV per nucleon by shooting double-layer targets composed of well-controlled slightly underdense plasma and ultrathin foils with ultraintense femtosecond laser pulses. Particle-in-cell simulations reveal that carbon ions are ejected from the ultrathin foils due to radiation pressure and then accelerated in an enhanced sheath field established by the superponderomotive electron flow. Such a cascaded acceleration is especially suited for heavy ion acceleration with femtosecond laser pulses. The breakthrough of heavy ion energy up to many tens of $\mathrm{MeV}/\mathrm{u}$ at a high repetition rate would be able to trigger significant advances in nuclear physics, high energy density physics, and medical physics.

An approach for accelerating a quasimonoenergetic proton bunch via a hemispherically converging collisionless shock created in laser-cluster interactions at the relativistically induced transparency (RIT) regime is studied using three-dimensional particle-in-cell simulations. By the action of focusing a petawatt class laser pulse onto a micron-size spherical hydrogen cluster, a crescent-shaped collisionless shock is launched at the laser-irradiated hemisphere and propagates inward. The shock converges at the sphere center in concurrence with the onset of the RIT, thereby allowing the proton bunch to be pushed out from the shock surface in the laser propagation direction. The proton bunch experiences further acceleration both inside and outside of the cluster to finally exhibit a quasimonoenergetic spectral peak around 300 MeV while maintaining a narrow energy spread ($\sim 10\%$) and a small half-divergence angle ($\sim 5°$) via the effect of the RIT. This mechanism works for finite ranges of parameters with threshold values concerning the laser peak intensity and the cluster radius, resulting from the synchronization of the multiple processes in a self-consistent manner. The present scheme utilizing the internal and external degrees of freedom ascribed to the spherical cluster leads to the proton bunch alternative to the plain target, which allows the operation with a high repetition rate and impurity free.

Contemporary models of bounded plasmas assume that the target plasma electron temperature far exceeds the temperature of the cold electrons emitted from the target, $T_{\text{emit}}$. We show that when the sheath facing a collisional plasma becomes inverted, the target plasma electron temperature has to equal $T_{\text{emit}}$ even if the upstream plasma is hotter by orders of magnitude. This extreme cooling effect can alter the plasma properties and the heat transmission to thermionically emitting surfaces in many applications. It also opens a possibility of using thermionic divertor plates to induce detachment in tokamaks.

Acoustic emission (AE) measurements performed during the compressive loading of concrete samples with three different microstructures (aggregate sizes and porosity) and four sample sizes revealed that failure is preceded by an acceleration of the rate of fracturing events, power law distributions of AE energies and durations near failure, and a divergence of the fracturing correlation length and time towards failure. This argues for an interpretation of compressive failure of disordered materials as a critical transition between an intact and a failed state. The associated critical exponents were found to be independent of sample size and microstructural disorder and close to mean-field depinning values. Although compressive failure differs from classical depinning in several respects, including the nature of the elastic redistribution kernel, an analogy between the two processes allows deriving (finite-) sizing effects on strength that match our extensive data set. This critical interpretation of failure may have also important consequences in terms of natural hazards forecasting, such as volcanic eruptions, landslides, or cliff collapses.

Recent studies on a quasi-one-dimensional (quasi-1D) charge-density-wave (CDW) system, In atomic wires on Si(111), have brought intriguing issues on topological solitons in quasi-1D systems: the existence of few-atom-sized solitons, chirality of solitons, and the realization of logic exploiting the chirality switching. Using scanning tunneling microscopy and first-principles calculations, we show that the previously reported “short” phase-flip defects are In adatoms and thus have nonsolitonic nature, resolving the controversy over the existence of highly localized solitons. The observed “long” phase-flip and phase-slip defects are genuine solitons with and without chirality, respectively. While achiral solitons (phase-slip defects) can exist on the pristine CDW ($8\times 2$) surface, chiral solitons (phase-flip defects) cannot due to their breakage of $8\times 2$ ordering. The chiral solitons can exist only when they are trapped by In adatoms and constitute a part of a closed-loop domain wall. The intertwinement of chiral solitons and In adatoms implies the limitations of the previously proposed logic utilizing soliton chirality, but it provides an opportunity to realize this by controlling the In-adatom defect.

The thermodynamic properties of subsystems in strong interaction with the neighborhood can largely differ from the standard behavior. Here we study the thermodynamic properties of rings and triplets in equilibrated disordered 2D silica. Their statistics follows a Boltzmann behavior, albeit with a strongly reduced temperature. This effective temperature strongly depends on the length scale of the chosen subsystem. From a systematic analysis of the 1D Ising model and an analytically solvable model, we suggest that these observations reflect the presence of strong local positive energy correlations.

We propose the concept of a “hybridization-switching induced Mott transition” which is relevant to a broad class of $AB{\mathrm{O}}_3$ perovskite materials including ${\mathrm{BiNiO}}_3$ and ${\mathrm{PbCrO}}_3$ that feature extended $6s$ orbitals on the $A$-site cation (Bi or Pb), and a strong $A\text{−}\mathrm{O}$ covalency induced ligand hole. Using ab initio electronic structure and slave rotor theory calculations, we show that such systems exhibit a breathing phonon driven $A$-site to oxygen hybridization-wave instability which conspires with strong correlations on the $B$-site transition metal ion (Ni or Cr) to trigger a Mott insulating state. This class of systems is shown to undergo a pressure induced insulator to metal transition accompanied by a colossal volume collapse due to ligand hybridization switching.

Time-resolved vibrational spectroscopy constitutes an invaluable experimental tool for monitoring hot-carrier-induced surface reactions. However, the absence of a full understanding of the precise microscopic mechanisms causing the transient spectral changes has limited its applicability. Here we introduce a robust first-principles theoretical framework that successfully explains both the nonthermal frequency and linewidth changes of the CO internal stretch mode on Cu(100) induced by femtosecond laser pulses. Two distinct processes engender the changes: electron-hole pair excitations underlie the nonthermal frequency shifts, while electron-mediated vibrational mode coupling gives rise to linewidth changes. Furthermore, the origin and precise sequence of coupling events are finally identified.

We investigate the nature of the phase transition between the period-three charge-density wave and the disordered phase of a hard-boson model proposed in the context of cold-atom experiments. Building on a density-matrix renormalization group algorithm that takes full advantage of the hard-boson constraints, we study systems with up to 9000 sites and calculate the correlation length and the wave vector of the incommensurate short-range correlations with unprecedented accuracy. We provide strong numerical evidence that there is an intermediate floating phase far enough from the integrable Potts point, while in its vicinity, our numerical data are consistent with a unique transition in the Huse-Fisher chiral universality class.

In forced wetting, a rapidly moving surface drags with it a thin layer of trailing fluid as it is plunged into a second fluid bath. Using high-speed interferometry, we find characteristic structure in the thickness of this layer with multiple thin flat triangular structures separated by much thicker regions. These features, depending on liquid viscosity and penetration velocity, are robust and occur in both wetting and dewetting geometries. Their presence clearly shows the importance of motion in the transverse direction. We present a model using the assumption that the velocity profile is robust to thickness fluctuations that gives a good estimate of the gap thickness in the thin regions.

We consider a quantum communication task between two users Alice and Bob, in which Alice and Bob exchange their respective quantum information by means of local operations and classical communication assisted by shared entanglement. Here, we assume that Alice and Bob may have quantum side information, not transferred, and classical communication is free. In this work, we derive general upper and lower bounds for the least amount of entanglement which is necessary to perfectly perform this task, called the state exchange with quantum side information. Moreover, we show that the optimal entanglement cost can be negative when Alice and Bob make use of their quantum side information. We finally provide conditions on the initial state for the state exchange with quantum side information which give the exact optimal entanglement cost.