The electronic states of many Mott insulators, including iridates, are often conceptualized in terms of localized atomic states such as the famous “$J_{\mathrm{eff}}=1/2$ state.” Although orbital hybridization can strongly modify such states and dramatically change the electronic properties of materials, probing this process is highly challenging. In this Letter, we directly detect and quantify the formation of dimer orbitals in an iridate material ${\mathrm{Ba}}_5{\mathrm{AlIr}}_2{\mathrm{O}}_{11}$ using resonant inelastic x-ray scattering. Sharp peaks corresponding to the excitations of dimer orbitals are observed and analyzed by a combination of density functional theory calculations and theoretical simulations based on an Ir-Ir cluster model. Such partially delocalized dimer states lead to a redefinition of the angular momentum of the electrons and changes in the magnetic and electronic behaviors of the material. We use this to explain the reduction of the observed magnetic moment with respect to predictions based on atomic states. This study opens new directions to study dimerization in a large family of materials, including solids, heterostructures, molecules, and transient states.

We show that the interplay between antiferromagnetic interaction and hole motion gives rise to a topological superconducting phase. This is captured by the one dimensional anisotropic $t-J$ model which can be experimentally achieved with ultracold polar molecules trapped onto an optical lattice. As a function of the anisotropy strength we find that different quantum phases appear, ranging from a gapless Luttinger liquid to spin gapped conducting and superconducting regimes. In the presence of appropriate $z$ anisotropy, we also prove that a phase characterized by nontrivial topological order takes place. The latter is described uniquely by a finite nonlocal string parameter and presents robust edge spin fractionalization. These results allow us to explore quantum phases of matter where topological superconductivity is induced by the interaction.

Ordinary doping by electrons (holes) generally means that the Fermi level shifts towards the conduction band (valence band) and that the conductivity of free carriers increases. Recently, however, some peculiar doping characteristics were sporadically recorded in different materials without noting the mechanism: electron doping was observed to cause a portion of the lowest unoccupied band to merge into the valance band, leading to a decrease in conductivity. This behavior, that we dub as “antidoping,” was seen in rare-earth nickel oxides ${\mathrm{SmNiO}}_3$, cobalt oxides ${\mathrm{SrCoO}}_{2.5}$, Li-ion battery materials, and even MgO with metal vacancies. We describe the physical origin of antidoping as well as its inverse problem—the “design principles” that would enable an intelligent search of materials. We find that electron antidoping is expected in materials having preexisting trapped holes and is caused by the annihilation of such “hole polarons” via electron doping. This may offer an unconventional way of controlling conductivity.

The plethora of recent discoveries in the field of topological electronic insulators has inspired a search for boson systems with similar properties. There are predictions that ferromagnets on a two-dimensional honeycomb lattice may host chiral edge magnons. In such systems, we theoretically study how magnons and phonons couple. We find topological magnon polarons around the avoided crossings between phonons and topological magnons. Exploiting this feature along with our finding of Rayleigh-like edge phonons in armchair ribbons, we demonstrate the existence of chiral edge modes with a phononic character. We predict that these modes mediate a chirality in the coherent phonon response and suggest measuring this effect via elastic transducers. These findings reveal a possible approach towards heat management in future devices.

Permeability is one of the most fundamental transport properties in soft matter physics, material engineering, and nanofluidics. Here, we report by means of Langevin simulations of ideal penetrants in a nanoscale membrane made of a fixed lattice of attractive interaction sites, how the permeability can be massively tuned, even minimized or maximized, by tailoring the potential energy landscape for the diffusing penetrants, depending on the membrane attraction, topology, and density. Supported by limiting scaling theories we demonstrate that the observed nonmonotonic behavior and the occurrence of extreme values of the permeability is far from trivial and triggered by a strong anticorrelation and substantial (orders of magnitude) cancellation between penetrant partitioning and diffusivity, especially within dense and highly attractive membranes.

Bell state measurements, of which the eigenvectors are in an entangled form, are crucial resources in the construction of quantum networks. Therefore, device-independent certification of a Bell state measurement has significance in the quantum information process because it satisfies the exact demand on security. In this study, we implement a proof-of-concept experiment to certify a Bell state measurement device independently in an entanglement swapping process, namely, self-testing. Instead of preparing a tensor product of two singlets with four photons, multiplex encoding in polarization and spatial modes is utilized to produce two pairs of entangled qubits. As a result, we implement a full Bell state measurement and achieve a high degree of Bell violation on the remaining two qubits, which are required for nontrivial self-testing of a Bell state measurement. Furthermore, our results combine the correlations before and after the swapping; thus, the quality of the performed Bell state measurement can be precisely inferred.

For a long periodic chain of Bose condensates prepared in the free space, the subsequent evolution and interference dramatically depend on the difference between the phases of the adjacent and more distant condensates. If the phases are equal, the initial periodic density distribution reappears at later times, which is known as the Talbot effect. For randomly related phases, we have found that a spatial order also appears in the interference, while the evolution of the fringes differs with the Talbot effect qualitatively. Even a small phase disorder is sufficient for qualitatively altering the interference, though maybe at long evolution times. This effect may be used for measuring the amount of coherence between adjacent condensates and the correlation length along the chain.

We derive a state-dependent error-disturbance trade-off based on a statistical distance in the sequential measurements of a pair of noncommutative observables and experimentally verify the relation with a photonic qubit system. We anticipate that this Letter may further stimulate the study on the quantum uncertainty principle and related applications in quantum measurements.

It is difficult to calculate the energy levels and eigenstates of a large physical system on a classical computer because of the exponentially growing size of the Hilbert space. In this work, we experimentally demonstrate a quantum algorithm which could solve this problem via simulated resonant transitions. Using a four-qubit quantum simulator in which two qubits are used as ancillas for control and measurement, we obtain the energy spectrum of a 2-qubit low-energy effective Hamiltonian of the water molecule. The simulated transitions allow the state of the quantum simulator to transform and access large regions of the Hilbert space, including states that have no overlap with the initial state. Furthermore, we make use of this algorithm to efficiently prepare specific eigenstates on the simulator according to the measured eigenenergies.

The inherently unstable nature of domain walls makes their detection in laboratory experiments extremely challenging. We propose a method to stabilize domain walls inside a cavity. The method requires domain walls coupled to matter, a condition that is fulfilled by the symmetron model. We suggest two ways in which the walls could be detected once stabilized: studying the trajectories of ultracold neutrons either via the deflection angle of a neutron beam induced by the attraction towards the wall or through the time difference of these particles passing through the wall. We give realistic estimates for these effects and expect that they should be detectable experimentally.

We propose and implement a novel, robust, and nonparametric test of statistical isotropy of the expansion of the Universe and apply it to around 1000 type Ia supernovae from the Pantheon sample. We calculate the angular clustering of supernova magnitude residuals and compare it to the noise expected under the isotropic assumption. We also test for systematic effects and demonstrate that their effects are negligible or are already accounted for in our procedure. We express our constraints as an upper limit on the rms spatial variation in the Hubble parameter at late times. For the sky smoothed with a Gaussian with $\mathrm{FWHM}=60°$, less than 1% rms spatial variation in the Hubble parameter is allowed at 99.7% confidence.

We have investigated the double electron capture process in the ${\mathrm{H}}^{+}+{\mathrm{H}}^{-}$ collision system for energies from 60 eV to 20 keV. Despite the apparent simplicity of this highly correlated system, all previous calculations fail to reproduce the experimental total cross sections. Moreover, the latter exhibit oscillations that have been previously attributed to quantum interferences between the gerade and ungerade ionic states of the transient molecule formed during the collision. For this process, we present the absolute cross sections obtained from a fully correlated two-active-electron semiclassical atomic-orbital close-coupling approach. Our results reproduce well the experimental data in both magnitude and shape. Furthermore, we demonstrate that the oscillations stem from coherence effects between double electron capture and other two-electron inelastic channels, namely the transfer-excitation processes. This alternative interpretation is supported by a Rosenthal-like model based on a molecular treatment of the collision. Our results shed new light on this old but challenging problem.

We demonstrate the existence of a collective excitation branch in the pair-breaking continuum of superfluid Fermi gases and BCS superconductors. At zero temperature, we analytically continue the equation on the collective mode energy in Anderson’s Random Phase Approximation or Gaussian fluctuations through its branch cut associated with the continuum, and obtain the full complex dispersion relation, including in the strong coupling regime. The branch exists as long as the chemical potential $\mu$ is positive and the wave number below $\sqrt{2m\mu }/\hslash$ (with $m$ the fermion mass). In the long wavelength limit, the branch varies quadratically with the wave number, with a complex effective mass that we compute analytically for an arbitrary interaction strength.

Stimulated adiabatic passage utilizes radiation pulses to efficiently and selectively transfer population between quantum states, via an intermediate state that is normally decaying. In this Letter, we propose the analog of stimulated adiabatic passage in an acoustic system. It is realized with cavities that correlate through adiabatically time-varying couplings, where the cavities and time-varying couplings mimic discrete states and radiation pulses, respectively. With appropriate arrangements of coupling actions, an acoustic wave can be efficiently transferred from the initial excited cavity to the target cavity in the forward direction, immune to the intermediate dark cavity. On the other hand, for the backward propagation, the acoustic energy is perfectly localized in the intermediate dark cavity and completely dissipated. We analytically, numerically, and experimentally demonstrate such unidirectional sound localization and unveil the essential role of zero-eigenvalue eigenstates in the adiabatic passage process.

We report the observation of spin domain walls bounded by half-quantum vortices (HQVs) in a spin-1 Bose-Einstein condensate with antiferromagnetic interactions. A spinor condensate is initially prepared in the easy-plane polar phase, and then, suddenly quenched into the easy-axis polar phase. Domain walls are created via the spontaneous ${\mathbb{Z}}_2$ symmetry breaking in the phase transition and the walls dynamically split into composite defects due to snake instability. The end points of the defects are identified as HQVs for the polar order parameter and the mass supercurrent in their proximity is demonstrated using Bragg scattering. In a strong quench regime, we observe that singly charged quantum vortices are formed with the relaxation of free wall-vortex composite defects. Our results demonstrate a nucleation mechanism for composite defects via phase transition dynamics.

Topological boundary and interface modes are generated in an acoustic waveguide by simple quasiperiodic patterning of the walls. The procedure opens many topological gaps in the resonant spectrum and qualitative as well as quantitative assessments of their topological character are supplied. In particular, computations of the bulk invariant for the continuum wave equation are performed. The experimental measurements reproduce the theoretical predictions with high fidelity. In particular, acoustic modes with high $Q$ factors localized in the middle of a breathable waveguide are engineered by a simple patterning of the walls.

The migration of oxygen vacancies ($V_{\mathrm{O}}$) in ceria-based systems is crucial to their functionality in applications. Yet, although the $V_{\mathrm{O}}$’s structure and the distribution of the ${\mathrm{Ce}}^{3+}$ polarons at the ${\mathrm{CeO}}_2(111)$ surface has received extensive attention, the dynamic behaviors of $V_{\mathrm{O}}$’s and polarons are not fully understood. By combining density functional theory calculations and ab initio molecular dynamics simulations, we show that the movements of $V_{\mathrm{O}}$’s and polarons exhibit very distinct entanglement characteristics within a temperature range of 300–900 K, and that the positions of the ${\mathrm{Ce}}^{3+}$ polarons play a key role in the $V_{\mathrm{O}}$ migration. Long-distance vacancy migration occurs at moderate temperatures when the “suitable” ${\mathrm{Ce}}^{3+}$ distribution remains long enough to promote oxygen migration. This study provides microscopic insight into the interplay between the electronic and ionic charge transport in ceria that will be beneficial for the rational design of conductive ceria-based materials.

The clear-cut experimental identification of Majorana bound states in transport measurements still poses experimental challenges. We here show that the zero-energy Majorana state formed at a junction of three topological superconductor wires is directly responsible for giant shot noise amplitudes, in particular at low voltages and for small contact transparency. The only intrinsic noise limitation comes from the current-induced dephasing rate due to multiple Andreev reflection processes.

We report the first measurement of low-energy proton-capture cross sections of ${}^{124}\mathrm{Xe}$ in a heavy-ion storage ring. ${{}^{124}\mathrm{Xe}}^{54+}$ ions of five different beam energies between 5.5 and 8 AMeV were stored to collide with a windowless hydrogen target. The ${}^{125}\mathrm{Cs}$ reaction products were directly detected. The interaction energies are located on the high energy tail of the Gamow window for hot, explosive scenarios such as supernovae and x-ray binaries. The results serve as an important test of predicted astrophysical reaction rates in this mass range. Good agreement in the prediction of the astrophysically important proton width at low energy is found, with only a 30% difference between measurement and theory. Larger deviations are found above the neutron emission threshold, where also neutron and $\gamma$ widths significantly impact the cross sections. The newly established experimental method is a very powerful tool to investigate nuclear reactions on rare ion beams at low center-of-mass energies.