Femtosecond laser induced desorption of CO from a CO-covered Pd(111) surface is investigated with ab initio molecular dynamics with electronic friction that incorporates effects due to the excited electronic and phononic systems, as well as out-of-phase coadsorbate interactions. Our simulations show evidence of an important electron-phonon synergy in promoting CO desorption that has largely been neglected in other similar systems. At the saturated coverage of 0.75 ML, effects due to CO-CO interadsorbate energy exchange are also important. Our dynamics simulations, in concert with site-specific desorption energy calculations, allow us to understand the large coverage dependence of the desorption yields observed in experiments.

Colloids with short range attractions self-assemble into sample-spanning structures, whose dynamic nature results in a thermokinematic memory of the deformation history, also referred to as “thixotropy.” Here, we study the origins of the thixotropic effect in these time- and rate-dependent materials by investigating hysteresis across different length scales: from particle-level local measurements of coordination number (microscale), to the appearance of density and velocity fluctuations (mesoscale), and up to the shear stress response to an imposed deformation (macroscale). The characteristic time constants at each scale become progressively shorter, and hysteretic effects become more significant as we increase the strength of the interparticle attraction. There are also strong correlations between the thixotropic effects we observe at each scale.

In the path integral formulation of the evolution of an open quantum system coupled to a Gaussian, noninteracting environment, the dynamical contribution of the latter is encoded in an object called the influence functional. Here, we relate the influence functional to the process tensor—a more general representation of a quantum stochastic process—describing the evolution. Then, we use this connection to motivate a tensor network algorithm for the simulation of multitime correlations in open systems, building on recent work where the influence functional is represented in terms of time evolving matrix product operators. By exploiting the symmetries of the influence functional, we are able to use our algorithm to achieve orders-of-magnitude improvement in the efficiency of the resulting numerical simulation. Our improved algorithm is then applied to compute exact phonon emission spectra for the spin-boson model with strong coupling, demonstrating a significant divergence from spectra derived under commonly used assumptions of memorylessness.

We present the fully integrated form of the two-loop four-gluon amplitude in $\mathcal{N}=2$ supersymmetric quantum chromodynamics with gauge group $\mathrm{SU}(N_c)$ and with $N_f$ massless supersymmetric quarks (hypermultiplets) in the fundamental representation. Our result maintains full dependence on $N_c$ and $N_f$, and relies on the existence of a compact integrand representation that exhibits the duality between color and kinematics. Specializing to the $\mathcal{N}=2$ superconformal theory, where $N_f=2N_c$, we obtain remarkably simple amplitudes that have an analytic structure close to that of $\mathcal{N}=4$ super-Yang-Mills theory, except that now certain lower-weight terms appear. We comment on the corresponding results for other gauge groups.

By engineering and manipulating quantum entanglement between incoming photons and experimental apparatus, we construct single-photon detectors which cannot distinguish between photons of very different wavelengths. These color-erasure detectors enable a new kind of intensity interferometry, with potential applications in microscopy and astronomy. We demonstrate chromatic interferometry experimentally, observing robust interference using both coherent and incoherent photon sources.

We prove that optimal control of light energy storage in disordered media can be reached by wave front shaping. For this purpose, we build an operator for dwell times from the scattering matrix and characterize its full eigenvalue distribution both numerically and analytically in the diffusive regime, where the thickness $L$ of the medium is much larger than the mean free path $\ell$. We show that the distribution has a finite support with a maximal dwell time larger than the most likely value by a factor $(L/\ell {)}^2\gg 1$. This reveals that the highest dwell-time eigenstates deposit more energy than the open channels of the medium. Finally, we show that the dwell-time operator can be used to store energy in resonant targets buried in complex media, without any need for guide stars.

We quantitatively report on the rotational mechanical effect of wave orbital angular momentum on matter by nondissipative vortex mode conversion. Our experiments consist of ultrasonic waves reflected off freely spinning helical acoustic mirrors that are capillary trapped at a curved air-water interface. Considering helical mirrors with integer topological charges these results represent the demonstration of the experiment proposed by Allen et al. originally introduced in the optical domain [Phys. Rev. A 45, 8185 (1992)], whose quantitative implementation remains elusive to date whatever the nature of the wave. The study is further generalized to helical mirrors with fractional charges.

Dense emulsions, colloidal gels, microgels, and foams all display a solidlike behavior at rest characterized by a yield stress, above which the material flows like a liquid. Such a fluidization transition often consists of long-lasting transient flows that involve shear-banded velocity profiles. The characteristic time for full fluidization ${\tau }_f$ has been reported to decay as a power law of the shear rate $\dot{\gamma }$ and of the shear stress $\sigma$ with respective exponents $\alpha$ and $\beta$. Strikingly, the ratio of these exponents was empirically observed to coincide with the exponent of the Herschel-Bulkley law that describes the steady-state flow behavior of these complex fluids. Here we introduce a continuum model, based on the minimization of a “free energy,” that captures quantitatively all the salient features associated with such transient shear banding. More generally, our results provide a unified theoretical framework for describing the yielding transition and the steady-state flow properties of yield stress fluids.

Dense suspensions of hard particles in a Newtonian liquid can be jammed by shear when the applied stress exceeds a certain threshold. However, this jamming transition from a fluid into a solidified state cannot be probed with conventional steady-state rheology because the stress distribution inside the material cannot be controlled with sufficient precision. Here we introduce and validate a method that overcomes this obstacle. Rapidly propagating shear fronts are generated and used to establish well-controlled local stress conditions that sweep across the material. Exploiting such transient flows, we can track how a dense suspension approaches its shear-jammed state dynamically and quantitatively map out the onset stress for solidification in a state diagram.

We study first passage behaviors in the flow through three-dimensional random fracture networks. Network and flow heterogeneity lead to the emergence of heavy-tailed first passage time distributions that evolve with increasing distance between the start and target planes, and transition toward stable laws. Analysis of the spatial memory of the first passage process shows that particle motion can be quantified stochastically by a time domain random walk conditioned on the initial velocity data. This approach identifies advective tortuosity, the velocity point distribution and the average fracture link length as key quantities for the prediction of first passage times. Using this approach, we develop a theory for the evolution of first passage times with increasing distance between the start and target planes and the convergence towards stable laws.

The first amplitude analysis of the $B^{\pm }\to {\pi }^{\pm }{K}^{+}{K}^{-}$ decay is reported based on a data sample corresponding to an integrated luminosity of $3.0{\mathrm{fb}}^{-1}$ of $pp$ collisions recorded in 2011 and 2012 with the LHCb detector. The data are found to be best described by a coherent sum of five resonant structures plus a nonresonant component and a contribution from $\pi \pi \leftrightarrow KK$ $S$-wave rescattering. The dominant contributions in the ${\pi }^{\pm }$ $K^{\mp }$ and $K^{+}$ $K^{-}$ systems are the nonresonant and the $B^{\pm }\to \rho (1450{)}^0{\pi }^{\pm }$ amplitudes, respectively, with fit fractions around 30%. For the rescattering contribution, a sizable fit fraction is observed. This component has the largest $CP$ asymmetry reported to date for a single amplitude of $(-66\pm 4\pm 2)\%$, where the first uncertainty is statistical and the second systematic. No significant $CP$ violation is observed in the other contributions.

We investigate the fundamental phenomenon of the spontaneous, noise-induced modulational instability (MI) of a plane wave. The statistical properties of the noise-induced MI, observed previously in numerical simulations and in experiments, have not been explained theoretically. In this Letter, using the inverse scattering transform (IST) formalism, we propose a theoretical model of the asymptotic stage of the noise-induced MI based on $N$-soliton solutions of the focusing one-dimensional nonlinear Schrödinger equation. Specifically, we use ensembles of $N$-soliton bound states having a special semiclassical distribution of the IST eigenvalues, together with random phases for norming constants. To verify our model, we employ a recently developed numerical approach to construct an ensemble of $N$-soliton solutions with a large number of solitons, $N\sim 100$. Our investigation reveals a remarkable agreement between spectral (Fourier) and statistical properties of the long-term evolution of the MI and those of the constructed multisoliton, random-phase bound states. Our results can be generalized to a broad class of strongly nonlinear integrable turbulence problems.

In head-on collisions between two droplets, reflexive separation is frequently formed, showing tentative coalescence followed by disintegration into two primary drops. With higher impact inertia relative to surface tension, characterized by a Weber number (We), more satellite droplets are created between the primary drops. In the symmetric configuration, the existing phenomenological models indicate the absence of satellite droplets at the onset We when the coalesced drops start to break. Supported by experimental and simulation evidence, here we demonstrate the exclusive formation of at least one droplet after pinch of the thread connecting the colliding drops. In accordance with the universal features of a thinning liquid filament approaching singularity as predicted by scaling theories of pinch-off, the mechanism of satellite droplet formation in the symmetrical impact of droplets is clarified. Via slight breaking of the symmetry, no satellite droplet can be observed, thus providing a possible interpretation for the discrepancy in the literature and implications for controlling undesirable drop formation.

The transverse emittance of the electron beam is a fundamental parameter in linac-based x-ray free-electron lasers (FELs). We present results of emittance measurements carried out at SwissFEL, a compact x-ray FEL facility at the Paul Scherrer Institute in Switzerland, including a description of the novel high-resolution measurement techniques and the optimization procedure. We obtained slice emittance values at the undulator entrance down to 200 nm for an electron beam with a charge of 200 pC and an rms duration of 30–40 fs. Furthermore, we achieved slice emittances as low as 100 nm for 10 pC beams with few fs duration. These values set new standards for electron linear accelerators. The quality, verification, and control of our electron beams allowed us to generate high-power FEL radiation for a wavelength as short as 0.1 nm using an electron beam with an energy of only 6 GeV. The emittance values demonstrated at SwissFEL would allow producing hard x-ray FEL pulses with even lower-energy beams, thus paving the way for even more compact and cost-effective FEL facilities.

The propagation of electrons in an orbital multiplet dispersing on a lattice can support anomalous transport phenomena deriving from an orbitally induced Berry curvature. In striking contrast to the related situation in graphene, we find that anomalous transport for an $L=1$ multiplet on the primitive 2D triangular lattice is activated by easily implemented on site and optically tunable potentials. We demonstrate this for dynamics in a Bloch band where point degeneracies carrying opposite winding numbers are generically offset in energy, allowing both an anomalous charge Hall conductance with the sign selected by off-resonance coupling to circularly polarized light and a related anomalous orbital Hall conductance activated by layer buckling.

Manipulating building-block nanomaterials to form an ordered superstructure in a dilute and spacer-free solution phase challenges the existing 5-nm node lithography and nanorobotics. The cooperative nature of nanocrystals, polymers, and cells can lead to superarrays or colloidal crystals. For known highly ordered systems, the characteristic length of materials, defined as the shortest dimension of objects, is generally larger than their separations. A spacer (small-molecule surfactant or polymer) is typically required to diminish short range van der Waals attraction, which results in a glassy or liquid state. Herein we propose a new concept of achieving highly ordered nano-objects in a dilute and spacer-free system via the synergistic effects of excellent solvation and appropriate constraints on rotational motion. As a proof of concept, this study demonstrates that aluminosilicate nanotubes (AlSiNTs) suspended in water under dilute conditions (e.g., 1.0 wt%) can spontaneously form hexagonal arrays with an intertubular distance as large as tens of nanometers. The separation distance of the ordered superstructure is also tunable via controlling the concentration and length of nanotubes. These superaligned structures are probed using small-angle x-ray scattering and cryo-TEM characterizations, with underlying mechanisms investigated at an atomic level using molecular dynamics simulations. The concept and discovery of this work can open up opportunities to a variety of applications including visible-UV photonics and nanolithography, and may be generalizable to other nano-object systems that fulfill similar requirements.