Three high-spin phases recently discovered in the spin-crossover system Mn(taa) are identified through analysis by a combination of first-principles calculations and Monte Carlo simulation as a low-temperature Jahn-Teller ordered (solid) phase, an intermediate-temperature dynamically correlated (liquid) phase, and an uncorrelated (gas) phase. In particular, the Jahn-Teller liquid phase arises from competition between mixing with low-spin impurities, which drive the disorder, and intermolecular strain interactions. The latter are a key factor in both the spin-crossover phase transition and the magnetoelectric coupling. Jahn-Teller liquids may exist in other spin-crossover materials and materials that have multiple equivalent Jahn-Teller axes.

Hybrid quantum registers, such as electron-nuclear spin systems, have emerged as promising hardware for implementing quantum information and computing protocols in scalable systems. Nevertheless, the coherent control of such systems still faces challenges. Particularly, the lower gyromagnetic ratios of the nuclear spins cause them to respond slowly to control fields, resulting in gate times that are generally longer than the coherence time of the electron. Here, we demonstrate a scheme for circumventing this problem by indirect control: we apply a small number of short pulses only to the electron and let the full system undergo free evolution under the hyperfine coupling between the pulses. Using this scheme, we realize robust quantum gates in an electron-nuclear spin system, including a Hadamard gate on the nuclear spin and a controlled-NOT gate with the nuclear spin as the target qubit. The durations of these gates are shorter than the electron coherence time, and thus additional operations to extend the system coherence time are not needed. Our demonstration serves as a proof of concept for achieving efficient coherent control of electron-nuclear spin systems, such as nitrogen vacancy centers in diamond. Our scheme is still applicable when the nuclear spins are only weakly coupled to the electron.

Effective field theory provides a way of parametrizing strong-field deviations from general relativity that might be observable in the gravitational waves emitted in a black hole merger. To perform numerical simulations of mergers in such theories it is necessary that the equations be written in a form that admits a well-posed initial value formulation. We study gravity coupled to a scalar field including the leading (four-derivative) effective field theory corrections. We introduce a new class of “modified harmonic” gauges and gauge-fixed equations of motion, such that, at weak coupling, the equations are strongly hyperbolic and therefore admit a well-posed initial value formulation.

Quantum effects can stabilize wormhole solutions in general relativity, allowing information and matter to be transported between two connected spacetimes. Here we study the revival dynamics of signals sent between two weakly coupled quantum chaotic systems, represented as identical Sachdev-Ye-Kitaev models, that realize holographically a traversable wormhole in anti–de Sitter spacetime ${\mathrm{AdS}}_2$ for large number $N$ of particles. In this limit we find clear signatures of wormhole behavior: an excitation created in one system is quickly scrambled under its unitary dynamics, and is reassembled in the other system after a characteristic time consistent with holography predictions. This leads to revival oscillations that at low but finite temperature decay as a power law in time. For small $N$ we also observe revivals and show that they arise from a different, nongravitational mechanism.

We discuss the interaction of a mobile quantum impurity with a Bose-Einstein condensate of atoms at finite temperature. To describe the resulting Bose polaron formation we develop a dynamical variational approach applicable to an initial thermal gas of Bogoliubov phonons. We study the polaron formation after switching on the interaction, e.g., by a radio-frequency (rf) pulse from a noninteracting to an interacting state. To treat also the strongly interacting regime, interaction terms beyond the Fröhlich model are taken into account. We calculate the real-time impurity Green’s function and discuss its temperature dependence. Furthermore we determine the rf absorption spectrum and find good agreement with recent experimental observations. We predict temperature-induced shifts and a substantial broadening of spectral lines. The analysis of the real-time Green’s function reveals a crossover to a linear temperature dependence of the thermal decay rate of Bose polarons as unitary interactions are approached.

Unlike conventional jet and drop breakup, which forms a cylindrical liquid column, the dripping of a viscous film will form a liquid annulus, which then ruptures and heals due to surface tension and the inner surface forms a retracting tip. We apply a one-dimensional model to analyze the thinning dynamics, which predicts a universal thinning curve and shows good agreement with experimental measurements. The shape of the tip is documented to be conical and the retraction speed is determined by the balance of viscous and capillary stresses. We also show that the drop contains an entrained bubble and possible formation of satellite bubbles in the healed thread.

This Letter focuses on the dynamics of a liquid jet impacting the surface of a confined, immersed granular bed. Although previous works have considered the erosion process and surface morphology, less attention has been given to the jet hydrodynamics. Based on laboratory experiments, we show that when the liquid jet forms a crater, two situations arise. For weak or no erosion and for open craters, the jet is stationary. For vertical or overhanging crater walls, the jet displays a wide range of behaviors, from quasiperiodic oscillations to symmetry breaking and exploration of different states in time. An analysis of the different system states leads to the emergence of a bifurcation diagram depending on a dimensionless parameter, $J$, comparing the jet impact force to the force necessary to eject a grain. The frequency of the jet oscillations depends on the inertial velocity, the jet dispersion and the ratio between the injector cross section and the confinement length.

A key question in glass physics is what the origin of slow glassy dynamics is. The liquid structure is a natural candidate; however, an apparently severe counterexample has been known. Two model glass-forming liquids, with the standard Lennard–Jones interaction potential and its Weeks–Chandler–Andersen variation without the attractive tail, exhibit very similar structures at the two-body level but drastically different dynamical behaviors in the supercooled states. Here we look at the liquid structure through a (many-body) structural order parameter $\mathrm{\Theta }$ characterizing the packing capability of local particle arrangements. We show that the structures of these two systems seen by $\mathrm{\Theta }$ are actually very different at a many-body level, but, quite surprisingly, the macroscopic structure ($\mathrm{\Theta }$)-dynamics (${\tau }_{\alpha }$) relationships commonly follow a Vogel–Fulcher–Tammann-like function. Furthermore, the mutual information analysis reveals strong local structure-dynamics correlations. Therefore, we conclude that attractive interactions affect the liquid structure in a nonperturbative manner, but a general structural origin of slow dynamics holds for these systems.

The effect of a magnetic field on the optical absorption in semiconductors has been measured experimentally and modeled theoretically for various systems in previous decades. We present a new first-principles approach to systematically determine the response of excitons to magnetic fields, i.e., exciton $g$ factors. By utilizing the $GW$-Bethe-Salpeter equation methodology we show that $g$ factors extracted from the Zeeman shift of electronic bands are strongly renormalized by many-body effects which we trace back to the extent of the excitons in reciprocal space. We apply our approach to monolayers of transition metal dichalcogenides (${\mathrm{MoS}}_2$, ${\mathrm{MoSe}}_2$, ${\mathrm{MoTe}}_2$, ${\mathrm{WS}}_2$, and ${\mathrm{WSe}}_2$) with strongly bound excitons for which $g$ factors are weakened by about 30%.

Second-order topological superconductors host Majorana corner and hinge modes in contrast to conventional edge and surface modes in two and three dimensions. However, the realization of such second-order corner modes usually demands unconventional superconducting pairing or complicated junctions or layered structures. Here we show that Majorana corner modes could be realized using a 2D quantum spin Hall insulator in proximity contact with an $s$-wave superconductor and subject to an in-plane Zeeman field. Beyond a critical value, the in-plane Zeeman field induces opposite effective Dirac masses between adjacent boundaries, leading to one Majorana mode at each corner. A similar paradigm also applies to 3D topological insulators with the emergence of Majorana hinge states. Avoiding complex superconductor pairing and material structure, our scheme provides an experimentally realistic platform for implementing Majorana corner and hinge states.

We consider a Josephson junction hosting a Kramers pair of helical edge states of a quantum spin Hall bar in contact with a normal-metal probe. In this hybrid system, the orbital phase, induced by a small magnetic field threading the junction known as a Doppler shift, combines with the conventional Josephson phase difference and originates an effect akin to a Zeeman field in the spectrum. As a consequence, when a temperature bias is applied to the superconducting terminals, a thermoelectric current is established in the normal probe. We argue that this purely nonlocal thermoelectric effect is a unique signature of the helical nature of the edge states coupled to superconducting leads and it can constitute a useful tool for probing the helical nature of the edge states in systems where the Hall bar configuration is difficult to achieve. We fully characterize thermoelectric response and performance of this hybrid junction in a wide range of parameters, demonstrating that the external magnetic flux inducing the Doppler shift can be used as a knob to control the thermoelectric response and the heat flow in a novel device based on topological junctions.

In situ measurements of the free energy difference between the open and closed states of ion channels are challenging due to hysteresis effects and inactivation. Exploiting recent developments in statistical physics, we present a general formalism to extract the free energy difference $\mathrm{\Delta }F$ between the closed and open states of mechanosensitive ion channels from nonequilibrium work distributions associated with the opening and closing of the channels (gating) in response to ramp stimulation protocols recorded in native patches. We show that the work distributions obtained from the gating of MscS channels in E. coli membrane satisfy the strong symmetry relation predicted by the Crooks fluctuation theorem. Our approach enables the determination of $\mathrm{\Delta }F$ using patch-clamp experiments, which are often inherently restricted to the nonequilibrium regime.

We prove that the quantum Gibbs states of spin systems above a certain threshold temperature are approximate quantum Markov networks, meaning that the conditional mutual information decays rapidly with distance. We demonstrate the exponential decay for short-ranged interacting systems and power-law decay for long-ranged interacting systems. Consequently, we establish the efficiency of quantum Gibbs sampling algorithms, a strong version of the area law, the quasilocality of effective Hamiltonians on subsystems, a clustering theorem for mutual information, and a polynomial-time algorithm for classical Gibbs state simulations.

The QCD axion provides an elegant solution to the strong $CP$ problem. While the minimal realization is vulnerable to the so-called “axion quality problem,” we will consider a more robust realization in the presence of a mirror sector related to the standard model by a (softly broken) ${\mathbb{Z}}_2$ symmetry. We point out that the resulting “heavy” axion, while satisfying all theoretical and observational constraints, has a large and uncharted parameter space, which allows it to be probed at the LHC as a long-lived particle (LLP). The small defining axionic coupling to gluons results in a challenging hadronic decay signal which we argue can be distinguished against the background in such a long-lived regime, and yet, the same coupling allows for sufficient production at the hadron colliders thanks to the large gluon-parton luminosity. Our study opens up a new window towards accelerator observable axions and, more generally, singly produced LLPs.

Here we present new information on the shape evolution of the very neutron-rich ${}^{92,94}\mathrm{Se}$ nuclei from an isomer-decay spectroscopy experiment at the Radioactive Isotope Beam Factory at RIKEN. High-resolution germanium detectors were used to identify delayed $\gamma$ rays emitted following the decay of their isomers. New transitions are reported extending the previously known level schemes. The isomeric levels are interpreted as originating from high-$K$ quasineutron states with an oblate deformation of $\beta \sim 0.25$, with the high-$K$ state in ${}^{94}\mathrm{Se}$ being metastable and $K$ hindered. Following this, ${}^{94}\mathrm{Se}$ is the lowest-mass neutron-rich nucleus known to date with such a substantial $K$ hindrance. Furthermore, it is the first observation of an oblate $K$ isomer in a deformed nucleus. This opens up the possibility for a new region of $K$ isomers at low $Z$ and at oblate deformation, involving the same neutron orbitals as the prolate orbitals within the classic $Z\sim 72$ deformed hafnium region. From an interpretation of the level scheme guided by theoretical calculations, an oblate deformation is also suggested for the ${}^{94}{\mathrm{Se}}_{60}$ ground-state band.

The beta decay of tritium in the form of molecular ${\mathrm{T}}_2$ is the basis of sensitive experiments to measure neutrino mass. The final-state electronic, vibrational, and rotational excitations modify the beta spectrum significantly and are obtained from theory. We report measurements of the branching ratios to specific ionization states for the isotopolog HT. Two earlier, concordant measurements gave branching ratios of HT to the bound ${\mathrm{HHe}}^{+}$ ion of 89.5% and 93.2%, in sharp disagreement with the theoretical prediction of 55%–57%, raising concerns about the theory’s reliability in neutrino mass experiments. Our result, 56.5(6)%, is compatible with the theoretical expectation and disagrees strongly with the previous measurements.

Solid-state color centers with manipulatable spin qubits and telecom-ranged fluorescence are ideal platforms for quantum communications and distributed quantum computations. In this work, we coherently control the nitrogen-vacancy (NV) center spins in silicon carbide at room temperature, in which telecom-wavelength emission is detected. We increase the NV concentration sixfold through optimization of implantation conditions. Hence, coherent control of NV center spins is achieved at room temperature, and the coherence time $T_2$ can be reached to around $17.1\mu \mathrm{s}$. Furthermore, an investigation of fluorescence properties of single NV centers shows that they are room-temperature photostable single-photon sources at telecom range. Taking advantage of technologically mature materials, the experiment demonstrates that the NV centers in silicon carbide are promising platforms for large-scale integrated quantum photonics and long-distance quantum networks.