We report the synthesis of bulk, highly oriented, crystalline $4H$ hexagonal silicon ($4H\text{−}\mathrm{Si}$), through a metastable phase transformation upon heating the single-crystalline ${\mathrm{Si}}_{24}$ allotrope. Remarkably, the resulting $4H\text{−}\mathrm{Si}$ crystallites exhibit an orientation relationship with the ${\mathrm{Si}}_{24}$ crystals, indicating a structural relationship between the two phases. Optical absorption measurements reveal that $4H\text{−}\mathrm{Si}$ exhibits an indirect band gap near 1.2 eV, in agreement with first principles calculations. The metastable crystalline transition pathway provides a novel route to access bulk crystalline $4H\text{−}\mathrm{Si}$ in contrast to previous transformation paths that yield only nanocrystalline-disordered materials.

The drag force exerted on an object intruding into granular media is typically assumed to arise from additive velocity and depth dependent contributions. We test this with intrusion experiments and molecular dynamics simulations at constant speed over four orders of magnitude, well beyond the quasistatic regime. For a vertical cylindrical rod we find velocity dependence only right after impact, followed by a crossover to a common, purely depth-dependent behavior for all intrusion speeds. The crossover is set by the timescale for material, forced to well up at impact, to subsequently settle under gravity. These results challenge current models of granular drag.

The physics above and below the yield stress is unified by a simple model for viscoplasticity that accounts for the nonlinear rheology of multiple yield stress fluids. The model has a rate-dependent relaxation time, allows for plastic deformation below the yield stress, and indicates that rapid elastic deformation aids yielding. A range of commonly observed rheological behaviors are predicted, including the smooth overshoot in the loss modulus and the recently discovered contributions from recoverable and unrecoverable strains in amplitude sweeps.

We adapt the robust phase estimation algorithm to the evaluation of energy differences between two eigenstates using a quantum computer. This approach does not require controlled unitaries between auxiliary and system registers or even a single auxiliary qubit. As a proof of concept, we calculate the energies of the ground state and low-lying electronic excitations of a hydrogen molecule in a minimal basis on a cloud quantum computer. The denominative robustness of our approach is then quantified in terms of a high tolerance to coherent errors in the state preparation and measurement. Conceptually, we note that all quantum phase estimation algorithms ultimately evaluate eigenvalue differences.

One of the crucial steps in building a scalable quantum computer is to identify the noise sources which lead to errors in the process of quantum evolution. Different implementations come with multiple hardware-dependent sources of noise and decoherence making the problem of their detection manyfoldly more complex. We develop a randomized benchmarking algorithm which uses Weyl unitaries to efficiently identify and learn a mixture of error models which occur during the computation. We provide an efficiently computable estimate of the overhead required to compute expectation values on outputs of the noisy circuit relying only on the locality of the interactions and no further assumptions on the circuit structure. The overhead decreases with the noise rate and this enables us to compute analytic noise bounds that imply efficient classical simulability. We apply our methods to ansatz circuits that appear in the variational quantum eigensolver and establish an upper bound on classical simulation complexity as a function of noise, identifying regimes when they become classically efficiently simulatable.

An analytic formula is given for the total scattering cross section of an electron and a photon at order ${\alpha }^3$ in QED. This includes both the double-Compton scattering real-emission contribution as well as the virtual Compton scattering part. When combined with the recent analytic result for the pair-production cross section, the complete ${\alpha }^3$ cross section is now known. Both the next-to-leading order calculation as well as the pair-production cross section are computed using modern multiloop calculation techniques, where cut diagrams are decomposed into a set of master integrals that are then computed using differential equations.

We characterize a high-density sample of negatively charged silicon-vacancy (${\mathrm{SiV}}^{-}$) centers in diamond using collinear optical multidimensional coherent spectroscopy. By comparing the results of complementary signal detection schemes, we identify a hidden population of ${\mathrm{SiV}}^{-}$ centers that is not typically observed in photoluminescence and which exhibits significant spectral inhomogeneity and extended electronic $T_2$ times. The phenomenon is likely caused by strain, indicating a potential mechanism for controlling electric coherence in color-center-based quantum devices.

Quantum Monte Carlo simulations of quantum many-body systems are plagued by the Fermion sign problem. The computational complexity of simulating Fermions scales exponentially in the projection time $\beta$ and system size. The sign problem is basis dependent and an improved basis, for fixed errors, leads to exponentially quicker simulations. We show how to use sign-free quantum Monte Carlo simulations to optimize over the choice of basis on large two-dimensional systems. We numerically illustrate these techniques decreasing the “badness” of the sign problem by optimizing over single-particle basis rotations on one- and two-dimensional Hubbard systems. We find a generic rotation which improves the average sign of the Hubbard model for a wide range of $U$ and densities for $L\times 4$ systems. In one example improvement, the average sign (and hence simulation cost at fixed accuracy) for the $16\times 4$ Hubbard model at $U/t=4$ and $n=0.75$ increases by $\exp [8.64(6)\beta ]$. For typical projection times of $\beta ⪆100$, this accelerates such simulation by many orders of magnitude.

Behaving like atomically precise two-dimensional quantum wells with non-negligible dielectric contrast, the layered hybrid organic-inorganic lead halide perovskites (HOIPs) have strong electronic interactions leading to tightly bound excitons with binding energies on the order of 500 meV. These strong interactions suggest the possibility of larger excitonic complexes like trions and biexcitons, which are hard to study numerically due to the complexity of the layered HOIPs. Here, we propose and parametrize a model Hamiltonian for excitonic complexes in layered HOIPs and we study the correlated eigenfunctions of trions and biexcitons using a combination of diffusion Monte Carlo and very large variational calculations with explicitly correlated Gaussian basis functions. Binding energies and spatial structures of these complexes are presented as a function of the layer thickness. The trion and biexciton of the thinnest layered HOIP have binding energies of 35 and 44 meV, respectively, whereas a single exfoliated layer is predicted to have trions and biexcitons with equal binding energies of 48 meV. We compare our findings to available experimental data and to that of other quasi-two-dimensional materials.

We study the transverse self-structuring of cold atomic clouds with effective atomic interactions mediated by a coherent driving beam retroreflected by means of a single mirror. The resulting self-structuring due to optomechanical forces is much richer than that of an effective-Kerr medium, displaying hexagonal, stripe and honeycomb phases depending on the interaction strength parametrized by the linear susceptibility. Phase domains are described by Ginzburg-Landau amplitude equations with real coefficients. In the stripe phase the system recovers inversion symmetry. Moreover, the subcritical character of the honeycomb phase allows for light-density feedback solitons functioning as self-sustained dark atomic traps with motion controlled by phase gradients in the driving beam.

We predict a set of unusual quantum acoustic phenomena resulting from sound-matter interactions in a fully tunable solid-state platform in which an array of solid-state spins in diamond are coupled to quantized acoustic waves in a one-dimensional optomechanical crystal. We find that, by using a spatially varying laser drive that introduces a position-dependent phase in the optomechanical interaction, the mechanical band structure can be tuned in situ, consequently leading to unconventional quantum sound-matter interactions. We show that quasichiral sound-matter interactions can occur, with tunable ranges from bidirectional to quasiunidirectional, when the spins are resonant with the bands. When the solid-state spin frequency lies within the acoustic band gap, we demonstrate the emergence of an exotic polariton bound state that can mediate long-range tunable, odd-neighbor, and complex spin-spin interactions. This work expands the present exploration of quantum phononics and can have wide applications in quantum simulations and quantum information processing.

We study theoretically quantum states of a pair of photons interacting with a finite periodic array of two-level atoms in a waveguide. Our calculation reveals two-polariton eigenstates that have a highly irregular wave function in real space. This indicates the Bethe ansatz breakdown and the onset of quantum chaos, in stark contrast to the conventional integrable problem of two interacting bosons in a box. We identify the long-range waveguide-mediated coupling between the atoms as the key ingredient of chaos and nonintegrability. Our results provide new insights in the interplay between order, chaos, and localization in many-body quantum systems and can be tested in state-of-the-art setups of waveguide quantum electrodynamics.

By using Floquet driving protocols and interlacing them with a judicious reservoir emission engineering, we achieve extreme nonreciprocal thermal radiation. We show that the latter is rooted in an interplay between a direct radiation process occurring due to temperature bias between two thermal baths and the modulation process that is responsible for pumped radiation heat. Our theoretical results are confirmed via time-domain simulations with photonic and rf circuits.

We show that a simple one-dimensional model of spinless fermions with pair hopping displays a phase in which a Luttinger liquid of paired fermions coexists with a Luttinger liquid of unpaired fermions. Our results are based on extensive numerical density-matrix renormalization-group calculations and are supported by a two-fluid model that captures the essence of the coexistence region.

Electromagnonics—the hybridization of spin excitations and electromagnetic waves—has been recognized as a promising candidate for coherent information processing in recent years. Among its various implementations, the lack of available approaches for real-time manipulation on the system dynamics has become a common and urgent limitation. In this work, by introducing a fast and uniform modulation technique, we successfully demonstrate a series of benchmark coherent gate operations in hybrid magnonics, including semiclassical analogies of Landau-Zener transitions, Rabi oscillations, Ramsey interference, and controlled mode swap operations. Our approach lays the groundwork for dynamical manipulation of coherent signals in hybrid magnonics and can be generalized to a broad range of applications.

Melts of multiarm stars of 1,4-polybutadiene (dendrimer arborescent hybrids) with very high branching functionality ($f$) and small arm molar mass behave as jammed colloids and show distinct layers of segmental mobility. Three mobility layers were identified, comprising outer, intermediate, and near-core segments, all displaying a Vogel-Fulcher-Tammann temperature dependence. The respective glass temperatures increase as $f^{1/2}$. Our findings pave the way for further progress in this field by reconsidering previous theoretical treatments based on a single friction coefficient in hybrid nanoparticles such as densely grafted stars.