Hydrodynamic Fingering Instability Induced by a Precipitation Reaction
Y. Nagatsu, Y. Ishii, Y. Tada, and A. De Wit
Phys. Rev. Lett. 113, 024502 (2014) - Published 7 July, 2014
We experimentally demonstrate that a precipitation reaction at the miscible interface between two reactive solutions can trigger a hydrodynamic instability due to the buildup of a locally adverse mobility gradient related to a decrease in permeability. The precipitate results from an type of reaction when a solution containing one of the reactants is injected into a solution of the other reactant in a porous medium or a Hele-Shaw cell. Fingerlike precipitation patterns are observed upon displacement, the properties of which depend on whether displaces or vice versa. A mathematical modeling of the underlying mobility profile confirms that the instability originates from a local decrease in mobility driven by the localized precipitation. Nonlinear simulations of the related reaction-diffusion-convection model reproduce the properties of the instability observed experimentally. In particular, the simulations suggest that differences in diffusivity between and may contribute to the asymmetric characteristics of the fingering precipitation patterns.





