A sub-GeV dark sector fermion can have baryon-number-violating interactions induced by high-scale physics, leading to nucleon decay into and . Such processes can mimic standard search modes containing a neutrino, but have different kinematics and may have escaped detection. If a dark force mediated by a light vector acts on , depending on parameters, can be important. In typical scenarios, decays into , where , with an order unity branching fraction. Nucleon decay searches can potentially uncover new dark states that are otherwise inaccessible, due to their negligible coupling to ordinary matter or cosmological abundance.