Protein adsorption at the solid-liquid interface is an important phenomenon that often can be observed as a first step in biological processes. Despite its inherent importance, still relatively little is known about the underlying microscopic mechanisms. Here, using multivalent ions, we demonstrate the control of the interactions and the corresponding adsorption of net-negatively charged proteins (bovine serum albumin) at a solid-liquid interface. This is demonstrated by ellipsometry and corroborated by neutron reflectivity and quartz-crystal microbalance experiments. We show that the reentrant condensation observed within the rich bulk phase behavior of the system featuring a nonmonotonic dependence of the second virial coefficient on salt concentration $c_s$ is reflected in an intriguing way in the protein adsorption $d(c_s)$ at the interface. Our findings are successfully described and understood by a model of ion-activated patchy interactions within the framework of the classical density functional theory. In addition to the general challenge of connecting bulk and interface behavior, our work has implications for, inter alia, nucleation at interfaces.

An important contribution to the understanding of quantum key distribution has been the discovery of entangled states from which secret bits, but no maximally entangled states, can be extracted [Horodecki et al., Phys. Rev. Lett. 94, 200501 (2005)]. The construction of those states was based on an intuition that the quantum mechanical phenomena of data hiding and privacy might be related. In this Letter we firmly connect these two phenomena and highlight three aspects of this result. First, we simplify the definition of the secret key rate. Second, we give a formula for the one-way distillable entanglement of certain private states. Third, we consider the problem of extending the distance of quantum key distribution with help of intermediate stations, a setting called the quantum key repeater. We show that for protocols that first distill private states, it is essentially optimal to use the standard quantum repeater protocol based on entanglement distillation and entanglement swapping.

The conventional theory of hydrodynamics describes the evolution in time of chaotic many-particle systems from local to global equilibrium. In a quantum integrable system, local equilibrium is characterized by a local generalized Gibbs ensemble or equivalently a local distribution of pseudomomenta. We study time evolution from local equilibria in such models by solving a certain kinetic equation, the “Bethe-Boltzmann” equation satisfied by the local pseudomomentum density. Explicit comparison with density matrix renormalization group time evolution of a thermal expansion in the XXZ model shows that hydrodynamical predictions from smooth initial conditions can be remarkably accurate, even for small system sizes. Solutions are also obtained in the Lieb-Liniger model for free expansion into vacuum and collisions between clouds of particles, which model experiments on ultracold one-dimensional Bose gases.

In this Letter we present a theorem on the dynamics of the generalized Hubbard models. This theorem shows that the symmetry of the single-particle Hamiltonian can protect a kind of dynamical symmetry driven by the interactions. Here the dynamical symmetry refers to the phenomenon that time evolution of certain observables are symmetric between the repulsive and attractive Hubbard models. We demonstrate our theorem with three different examples in which the symmetry involves bipartite lattice symmetry, reflection symmetry, and translation symmetry, respectively. Each of these examples relates to one recent cold atom experiment on the dynamics in the optical lattices where such a dynamical symmetry is manifested. These experiments include expansion dynamics of cold atoms, chirality of atomic motion within a synthetic magnetic field, and melting of charge-density-wave order. Therefore, our theorem provides a unified view of these seemingly disparate phenomena.

Topological phases derived from point degeneracies in photonic band structures show intriguing and unique behavior. Previously identified band degeneracies are based on accidental degeneracies and subject to engineering on a case-by-case basis. Here we show that deterministic pseudo Weyl points with nontrivial topology and hyperconic dispersion exist at the Brillouin zone center of chiral cubic symmetries. This conceivably allows realization of topologically protected frequency isolated surface bands in 3D and $n=0$ properties as demonstrated for a nanoplasmonic system and a photonic crystal.

A communication game consists of distributed parties attempting to jointly complete a task with restricted communication. Such games are useful tools for studying limitations of physical theories. A theory exhibits preparation contextuality whenever its predictions cannot be explained by a preparation noncontextual model. Here, we show that communication games performed in operational theories reveal the preparation contextuality of that theory. For statistics obtained in a particular family of communication games, we show a direct correspondence with correlations in spacelike separated events obeying the no-signaling principle. Using this, we prove that all mixed quantum states of any finite dimension are preparation contextual. We report on an experimental realization of a communication game involving three-level quantum systems from which we observe a strong violation of the constraints of preparation noncontextuality.

We prove that generic quantum local Hamiltonians are gapless. In fact, we prove that there is a continuous density of states above the ground state. The Hamiltonian can be on a lattice in any spatial dimension or on a graph with a bounded maximum vertex degree. The type of interactions allowed for include translational invariance in a disorder (i.e., probabilistic) sense with some assumptions on the local distributions. Examples include many-body localization and random spin models. We calculate the scaling of the gap with the system’s size when the local terms are distributed according to a Gaussian $\beta$ orthogonal random matrix ensemble. As a corollary, there exist finite size partitions with respect to which the ground state is arbitrarily close to a product state. When the local eigenvalue distribution is discrete, in addition to the lack of an energy gap in the limit, we prove that the ground state has finite size degeneracies. The proofs are simple and constructive. This work excludes the important class of truly translationally invariant Hamiltonians where the local terms are all equal.

Engineering entanglement between quantum systems often involves coupling through a bosonic mediator, which should be disentangled from the systems at the operation’s end. The quality of such an operation is generally limited by environmental and control noise. One of the prime techniques for suppressing noise is by dynamical decoupling, where one actively applies pulses at a rate that is faster than the typical time scale of the noise. However, for boson-mediated gates, current dynamical decoupling schemes require executing the pulses only when the boson and the quantum systems are disentangled. This restriction implies an increase of the gate time by a factor of $\sqrt{N}$, with $N$ being the number of pulses applied. Here we propose and realize a method that enables dynamical decoupling in a boson-mediated system where the pulses can be applied while spin-boson entanglement persists, resulting in an increase in time that is at most a factor of $\pi /2$, independently of the number of pulses applied. We experimentally demonstrate the robustness of our entangling gate with fast dynamical decoupling to ${\sigma }_z$ noise using ions in a Paul trap.

In quantum statistical mechanics, it is of fundamental interest to understand how close the bipartite entanglement entropy of eigenstates of quantum chaotic Hamiltonians is to maximal. For random pure states in the Hilbert space, the average entanglement entropy is known to be nearly maximal, with a deviation that is, at most, a constant. Here we prove that, in a system that is away from half filling and divided in two equal halves, an upper bound for the average entanglement entropy of random pure states with a fixed particle number and normally distributed real coefficients exhibits a deviation from the maximal value that grows with the square root of the volume of the system. Exact numerical results for highly excited eigenstates of a particle number conserving quantum chaotic model indicate that the bound is saturated with increasing system size.

We present a general framework for the accurate spectral modeling of the low multipoles of the cosmic microwave background (CMB) as observed in a boosted frame. In particular, we demonstrate how spectral measurements of the low multipoles can be used to separate the motion-induced dipole of the CMB from a possible intrinsic dipole component. In a moving frame, the leakage of an intrinsic dipole moment into the CMB monopole and quadrupole induces spectral distortions with distinct frequency functions that, respectively, peak at 337 and 276 GHz. The leakage into the quadrupole moment also induces a geometrical distortion to the spatial morphology of this mode. The combination of these effects can be used to lift the degeneracy between the motion-induced dipole and any intrinsic dipole that the CMB might possess. Assuming the current peculiar velocity measurements, the leakage of an intrinsic dipole with an amplitude of $\mathrm{\Delta }T=30\mu \mathrm{K}$ into the monopole and quadrupole moments will be detectable by a PIXIE-like experiment at $\sim 40\mathrm{nK}$ ($2.5\sigma$) and $\sim 130\mathrm{nK}$ ($11\sigma$) level at their respective peak frequencies.

Light axionic dark matter, motivated by string theory, is increasingly favored for the “no weakly interacting massive particle era”. Galaxy formation is suppressed below a Jeans scale of $\simeq {10}^8{M}_{\odot }$ by setting the axion mass to $m_B\sim {10}^{-22}\mathrm{eV}$, and the large dark cores of dwarf galaxies are explained as solitons on the de Broglie scale. This is persuasive, but detection of the inherent scalar field oscillation at the Compton frequency ${\omega }_B=(2.5\text{months}{)}^{-1}(m_B/{10}^{-22}\mathrm{eV})$ would be definitive. By evolving the coupled Schrödinger-Poisson equation for a Bose-Einstein condensate, we predict the dark matter is fully modulated by de Broglie interference, with a dense soliton core of size $\simeq 150\mathrm{pc}$, at the Galactic center. The oscillating field pressure induces general relativistic time dilation in proportion to the local dark matter density and pulsars within this dense core have detectably large timing residuals of $\simeq 400\mathrm{nsec}/(m_B/{10}^{-22}\mathrm{eV})$. This is encouraging as many new pulsars should be discovered near the Galactic center with planned radio surveys. More generally, over the whole Galaxy, differences in dark matter density between pairs of pulsars imprints a pairwise Galactocentric signature that can be distinguished from an isotropic gravitational wave background.

Common lore suggests that $N$-color QCD with massive quarks has no useful order parameters that can be nontrivial at zero baryon density. However, such order parameters do exist when there are $n_f$ quark flavors with a common mass and $d\equiv gcd(n_f,N)>1$. These theories have a ${\mathbb{Z}}_d$ color-flavor center symmetry arising from intertwined color center transformations and cyclic flavor permutations. The symmetry realization depends on the temperature, baryon chemical potential, and value of $n_f/N$, with implications for conformal window studies and dense quark matter.

A nonlocal dispersive optical-model analysis has been carried out for neutrons and protons in ${}^{48}\mathrm{Ca}$. Elastic-scattering angular distributions, total and reaction cross sections, single-particle energies, the neutron and proton numbers, and the charge distribution have been fitted to extract the neutron and proton self-energies both above and below the Fermi energy. From the single-particle propagator resulting from these self-energies, we have determined the charge and neutron matter distributions in ${}^{48}\mathrm{Ca}$. A best fit neutron skin of $0.249\pm 0.023\mathrm{fm}$ is deduced, but values up to 0.33 fm are still consistent. The energy dependence of the total neutron cross sections is shown to have a strong sensitivity to the skin thickness.

Few-body nuclear physics often relies upon phenomenological models, with new efforts at the ab initio theory reported recently; both need high-quality benchmark data, particularly at low center-of-mass energies. We use high-energy-density plasmas to measure the proton spectra from ${}^3\mathrm{He}+\mathrm{T}$ and ${}^3\mathrm{He}+{}^3\mathrm{He}$ fusion. The data disagree with $R$-matrix predictions constrained by neutron spectra from $\mathrm{T}+\mathrm{T}$ fusion. We present a new analysis of the ${}^3\mathrm{He}+{}^3\mathrm{He}$ proton spectrum; these benchmarked spectral shapes should be used for interpreting low-resolution data, such as solar fusion cross-section measurements.

The properties of cold Bose gases at unitarity have been extensively investigated in the last few years both theoretically and experimentally. In this Letter we use a family of interactions tuned to two-body unitarity and very weak three-body binding to demonstrate the universal properties of both clusters and matter. We determine the universal properties of finite clusters up to 60 particles and, for the first time, explicitly demonstrate the saturation of energy and density with particle number and compare with bulk properties. At saturation in the bulk we determine the energy, density, two- and three-body contacts, and the condensate fraction. We find that uniform matter is more bound than three-body clusters by nearly 2 orders of magnitude, the two-body contact is very large in absolute terms, and yet the condensate fraction is also very large, greater than 90%. Equilibrium properties of these systems may be experimentally accessible through rapid quenching of weakly interacting boson superfluids.

We propose a new approach to the determination of accurate electronic energies that are equivalent to the results of high-level coupled-cluster (CC) calculations. The approach is based on merging the $\mathrm{CC}(P;Q)$ formalism, which corrects energies obtained with an arbitrary truncation in the cluster operator, with the stochastic configuration interaction and CC ideas. The advantages of the proposed methodology are illustrated by molecular examples, where the goal is to recover the energetics obtained in the CC calculations with a full treatment of singly, doubly, and triply excited clusters.