In organic photovoltaic systems, a photogenerated molecular exciton in the donor domain dissociates into a hole and an electron at the donor-acceptor heterojunction, and subsequently separates into free charge carriers that can be extracted as photocurrents. The recombination of the once-separated electron and hole is a major loss mechanism in photovoltaic systems, which controls their performance. Hence, efficient photovoltaic systems need built-in ratchet mechanisms, namely, ultrafast charge separation and retarded charge recombination. In order to obtain insight into the internal working of the experimentally observed ultrafast long-range charge separation and protection against charge recombination, we theoretically investigate a potential ratchet mechanism arising from the combination of quantum delocalization and its destruction by performing numerically accurate quantum-dynamics calculations on a model system. We demonstrate that the non-Markovian effect originating from the slow polaron formation strongly suppresses the electron-transfer reaction back to the interfacial charge-transfer state stabilized at the donor-accepter interface and that it plays a critical role in maintaining the long-range electron-hole separation.

Motivated by recent experiments on Kondo insulators, we theoretically study quantum oscillations from disorder-induced in-gap states in small-gap insulators. By solving a non-Hermitian Landau level problem that incorporates the imaginary part of electron’s self-energy, we show that the oscillation period is determined by the Fermi surface area in the absence of the hybridization gap, and we derive an analytical formula for the oscillation amplitude as a function of the indirect band gap, scattering rates, and temperature. Over a wide parameter range, we find that the effective mass is controlled by scattering rates, while the Dingle factor is controlled by the indirect band gap. We also show the important effect of scattering rates in reshaping the quasiparticle dispersion in connection with angle-resolved photoemission measurements on heavy fermion materials.

A versatile and efficient variational approach is developed to solve in- and out-of-equilibrium problems of generic quantum spin-impurity systems. Employing the discrete symmetry hidden in spin-impurity models, we present a new canonical transformation that completely decouples the impurity and bath degrees of freedom. Combining it with Gaussian states, we present a family of many-body states to efficiently encode nontrivial impurity-bath correlations. We demonstrate its successful application to the anisotropic and two-lead Kondo models by studying their spatiotemporal dynamics and universal behavior in the correlations, relaxation times, and the differential conductance. We compare them to previous analytical and numerical results. In particular, we apply our method to study new types of nonequilibrium phenomena that have not been studied by other methods, such as long-time crossover in the ferromagnetic easy-plane Kondo model. The present approach will be applicable to a variety of unsolved problems in solid-state and ultracold-atomic systems.

We report the experimental observation of commensurability oscillations (COs) in 1D graphene superlattices. The widely tunable periodic potential modulation in hBN-encapsulated graphene is generated via the interplay of nanopatterned few-layer graphene acting as a local bottom gate and a global Si back gate. The longitudinal magnetoresistance shows pronounced COs when the sample is tuned into the unipolar transport regime. We observe up to six CO minima, providing evidence for a long mean free path despite the potential modulation. Comparison to existing theories shows that small-angle scattering is dominant in hBN/graphene/hBN heterostructures. We observe robust COs persisting to temperatures exceeding $T=150\mathrm{K}$. At high temperatures, we find deviations from the predicted $T$ dependence, which we ascribe to electron-electron scattering.

Topological insulators are promising candidates for optically driven spintronic devices, because photoexcitation of spin polarized surface states is governed by angular momentum selection rules. We carry out femtosecond midinfrared spectroscopy on thin films of the topological insulator ${\mathrm{Bi}}_2{\mathrm{Te}}_2\mathrm{Se}$, which has a higher surface state conductivity compared to conventionally studied ${\mathrm{Bi}}_2{\mathrm{Se}}_3$ and ${\mathrm{Bi}}_2{\mathrm{Te}}_3$. Both charge and spin dynamics are probed utilizing circularly polarized light. With a sub-band-gap excitation, clear helicity-dependent dynamics is observed only in thin ($<20\mathrm{nm}$) flakes. On the other hand, such dependence is observed for both thin and thick flakes with above-band-gap excitation. The helicity dependence is attributed to asymmetric excitation of the Dirac-like surface states. The observed long-lasting asymmetry over 10 ps even at room temperature indicates low backscattering of surface state carriers which can be exploited for spintronic devices.

We propose a mechanism whereby disorder can enhance the transition temperature $T_c$ of an unconventional superconductor with pairing driven by exchange of spin fluctuations. The theory is based on a self-consistent real space treatment of pairing in the disordered one-band Hubbard model. It has been demonstrated before that impurities can enhance pairing by softening the spin fluctuations locally; here, we consider the competing effect of pair breaking by the screened Coulomb potential also present. We show that, depending on the impurity potential strength and proximity to magnetic order, this mechanism results in a weakening of the disorder-dependent $T_c$-suppression rate expected from Abrikosov-Gor’kov theory, or even in disorder-generated $T_c$ enhancements.

We theoretically investigate pumping of phonons by the dynamics of a magnetic film into a nonmagnetic contact. The enhanced damping due to the loss of energy and angular momentum shows interference patterns as a function of the resonance frequency and magnetic film thickness that cannot be described by viscous (“Gilbert”) damping. The phonon pumping depends on the magnetization direction as well as geometrical and material parameters and is observable, e.g., in thin films of yttrium iron garnet on a thick dielectric substrate.

Quantum shot noise probes the dynamics of charge transfers through a quantum conductor, reflecting whether quasiparticles flow across the conductor in a steady stream, or in syncopated bursts. We have performed high-sensitivity shot noise measurements in a quantum dot obtained in a silicon metal-oxide-semiconductor field-effect transistor. The quality of our device allows us to precisely associate the different transport regimes and their statistics with the internal state of the quantum dot. In particular, we report on large current fluctuations in the inelastic cotunneling regime, corresponding to different highly correlated, non-Markovian charge transfer processes. We have also observed unusually large current fluctuations at low energy in the elastic cotunneling regime, the origin of which remains to be fully investigated.

We report the measurement of the third moment of current fluctuations in a short metallic wire at low temperature. The data are deduced from the statistics of voltage fluctuations across the conductor using a careful determination of environmental contributions. Our results at low bias agree very well with theoretical predictions for coherent transport with no fitting parameter. By increasing the bias voltage we explore the crossover from elastic to inelastic transport.

We show how a characteristic length scale imprinted in the galaxy two-point correlation function, dubbed the “linear point,” can serve as a comoving cosmological standard ruler. In contrast to the baryon acoustic oscillation peak location, this scale is constant in redshift and is unaffected by nonlinear effects to within 0.5 percent precision. We measure the location of the linear point in the galaxy correlation function of the LOWZ and CMASS samples from the Twelfth Data Release (DR12) of the Baryon Oscillation Spectroscopic Survey (BOSS) Collaboration. We combine our linear-point measurement with cosmic-microwave-background constraints from the Planck satellite to estimate the isotropic-volume distance $D_V(z)$, without relying on a model-template or “reconstruction” method. We find $D_V(0.32)=1264\pm 28\mathrm{Mpc}$ and $D_V(0.57)=2056\pm 22\mathrm{Mpc}$, respectively, consistent with the quoted values from the BOSS Collaboration. This remarkable result suggests that all the distance information contained in the baryon acoustic oscillations can be conveniently compressed into the single length associated with the linear point.

We consider finite superamplitudes of $\mathcal{N}=1$ matter, and use superconformal symmetry to derive powerful first-order differential equations for them. Because of on-shell collinear singularities, the Ward identities have an anomaly, which is obtained from lower-loop information. We show that in the five-particle case, the solution to the equations is uniquely fixed by the expected analytic behavior. We apply the method to a nonplanar two-loop five-particle integral.

Lifetimes of the first excited $2^{+}$ and $4^{+}$ states in the extremely neutron-deficient nuclide ${}^{172}\mathrm{Pt}$ have been measured for the first time using the recoil-distance Doppler shift and recoil-decay tagging techniques. An unusually low value of the ratio $B(E2:4_1^{+}\to 2_1^{+})/B(E2:2_1^{+}\to 0_{\mathrm{gs}}^{+})=0.55(19)$ was found, similar to a handful of other such anomalous cases observed in the entire Segré chart. The observation adds to a cluster of a few extremely neutron-deficient nuclides of the heavy transition metals with neutron numbers $N\approx 90–94$ featuring the effect. No theoretical model calculations reported to date have been able to explain the anomalously low $B(E2:4_1^{+}\to 2_1^{+})/B(E2:2_1^{+}\to 0_{\mathrm{gs}}^{+})$ ratios observed in these cases. Such low values cannot, e.g., be explained within the framework of the geometrical collective model or by algebraic approaches within the interacting boson model framework. It is proposed that the group of $B(E2:4_1^{+}\to 2_1^{+})/B(E2:2_1^{+}\to 0_{\mathrm{gs}}^{+}$) ratios in the extremely neutron-deficient even-even W, Os, and Pt nuclei around neutron numbers $N\approx 90–94$ reveal a quantum phase transition from a seniority-conserving structure to a collective regime as a function of neutron number. Although a system governed by seniority symmetry is the only theoretical framework for which such an effect may naturally occur, the phenomenon is highly unexpected for these nuclei that are not situated near closed shells.

We optically trap freestanding single metallic chiral nanoparticles using a standing-wave optical tweezer. We also incorporate within the trap a polarimetric setup that allows us to perform in situ chiral recognition of single enantiomers. This is done by measuring the $S_3$ component of the Stokes vector of a light beam scattered off the trapped nanoparticle in the forward direction. This unique combination of optical trapping and chiral recognition, all implemented within a single setup, opens new perspectives towards the control, recognition, and manipulation of chiral objects at nanometer scales.

We find that the effects of a localized perturbation in a chaotic classical many-body system—the classical Heisenberg chain at infinite temperature–spread ballistically with a finite speed even when the local spin dynamics is diffusive. We study two complementary aspects of this butterfly effect: the rapid growth of the perturbation, and its simultaneous ballistic (light-cone) spread, as characterized by the Lyapunov exponents and the butterfly speed, respectively. We connect this to recent studies of the out-of-time-ordered commutators (OTOC), which have been proposed as an indicator of chaos in a quantum system. We provide a straightforward identification of the OTOC with a natural correlator in our system and demonstrate that many of its interesting qualitative features are present in the classical system. Finally, by analyzing the scaling forms, we relate the growth, spread, and propagation of the perturbation with the growth of one-dimensional interfaces described by the Kardar-Parisi-Zhang equation.

Topological characteristics of energy bands, such as Dirac and Weyl nodes, have attracted substantial interest in condensed matter systems as well as in classical wave systems. Among these energy bands, the type-II Dirac point is a nodal degeneracy with tilted conical dispersion, leading to a peculiar crossing dispersion in the constant-energy plane. Such nodal points have recently been found in electronic materials. The analogous topological feature in photonic systems remains a theoretical curiosity, with experimental realization expected to be challenging. Here, we experimentally realize the type-II Dirac point using a planar metasurface architecture, where the band degeneracy point is protected by the underlying mirror symmetry of the metasurface. Gapless edge modes are found and measured at the boundary between the different domains of the symmetry-broken metasurface. Our Letter shows that metasurfaces are simple and practical platforms for realizing electromagnetic type-II Dirac points, and their planar structure is a distinct advantage that facilitates applications in two-dimensional topological photonics.

The acceleration of beam ions during edge localized modes (ELMs) in a tokamak is observed for the first time through direct measurements of fast-ion losses in low collisionality plasmas. The accelerated beam-ion population exhibits well-localized velocity-space structures which are revealed by means of tomographic inversion of the measurement, showing energy gains of the order of tens of keV. This suggests that the ion acceleration results from a resonant interaction between the beam ions and parallel electric fields arising during the ELM. Orbit simulations are carried out to identify the mode-particle resonances responsible for the energy gain in the particle phase space. The observation motivates the incorporation of a kinetic description of fast particles in ELM models and may contribute to a better understanding of the mechanisms responsible for particle acceleration, ubiquitous in astrophysical and space plasmas.

We study the structural, electronic, and vibrational properties of single-layer $1T\text{−}{\mathrm{NbSe}}_2$ from first principles. Within the generalized gradient approximation, the $1T$ polytype is highly unstable with respect to the $2H$. The density functional theory with the Hubbard $U$ method improves the stability of the $1T$ phase, explaining its detection in experiments. A charge density wave occurs with a $\sqrt{13}\times \sqrt{13}R30°$ periodicity, in agreement with STM data. At $U=0$, the David-star reconstruction displays a flatband below the Fermi level with a marked $d_{z^2-r^2}$ orbital character of the central Nb. The Hubbard interaction induces a magnetic Mott-insulating state. Magnetism distorts the lattice around the central Nb atom in the star, reduces the hybridization between the central Nb $d_{z^2-r^2}$ orbital and the neighboring Se $p$ states, and lifts in energy the empty $d_{z^2-r^2}$ flatband becoming nonbonding. This cooperative Jahn-Teller and correlation effect amplifies the Mott gap. Our results are relevant for the broad class of correlated insulator in the presence of a strong Jahn-Teller effect.

Flexible long period moiré superlattices form in two-dimensional van der Waals crystals containing layers that differ slightly in lattice constant or orientation. In this Letter we show theoretically that isolated flat moiré bands described by generalized triangular lattice Hubbard models are present in twisted transition metal dichalcogenide heterobilayers. The hopping and interaction strength parameters of the Hubbard model can be tuned by varying the twist angle and the three-dimensional dielectric environment. When the flat moiré bands are partially filled, candidate many-body ground states at some special filling factors include spin-liquid states, quantum anomalous Hall insulators, and chiral $d$-wave superconductors.