A novel rotational spectroscopy method applicable to ions stored in cold traps is presented. In a double resonance scheme, rotational excitation is followed by vibrational excitation into a dissociative resonance. Its general applicability is demonstrated for the ${\mathrm{CH}}_3^{+}\text{−}\mathrm{He}$ complex, which undergoes predissociation through its C-H stretching modes ${\nu }_1$ and ${\nu }_3$. High resolution rotational transitions are recorded for this symmetric top, and small unexpected splittings are resolved for $K=1$. Advantages and potential future applications of this new approach are discussed.

The nonlinear interaction of subcycle electromagnetic radiation with matter is the current frontier in ultrafast nonlinear optics and high-field physics. Here, we investigate nonlinear optical effects induced by intense, subcycle terahertz radiation in a doped semiconductor. We observe a truncation of the half-cycle terahertz pulse and an emission of high-frequency terahertz photons. We attribute our observations to the abrupt current drop caused by strong intervalley scattering effects. By adding an extra half-cycle terahertz pulse with opposite polarity, we monitor the evolution of the nonlinear carrier dynamics during a quasi-single-cycle pulse. Our results demonstrate the differences between nonlinear effects for subcycle and multicycle terahertz pulses. It also suggests a new approach to subcycle control of terahertz waveforms, and the generation of high-order terahertz harmonics could be realized by using multicycle pulses.

Electronic transport properties of warm dense matter, such as electrical or thermal conductivities and nonadiabatic stopping power, are of particular interest to geophysics, planetary science, astrophysics, and inertial confinement fusion (ICF). One example is the $\alpha$-particle stopping power of dense deuterium-tritium (DT) plasmas, which must be precisely known for current small-margin ICF target designs to ignite. We have developed a time-dependent orbital-free density functional theory (TD-OF-DFT) method for ab initio investigations of the charged-particle stopping power of warm dense matter. Our current dependent TD-OF-DFT calculations have reproduced the recently well-characterized stopping power experiment in warm dense beryllium. For $\alpha$-particle stopping in warm and solid-density DT plasmas, the ab initio TD-OF-DFT simulations show a lower stopping power up to $\sim 25\%$ in comparison with three stopping-power models often used in the high-energy-density physics community.

We present results on tagged particle diffusion in a mesoscale lattice model for sheared amorphous material in athermal quasistatic conditions. We find a short time diffusive regime and a long time diffusive regime whose diffusion coefficients depend on system size in dramatically different ways. At short time, we find that the diffusion coefficient, $D$, scales roughly linearly with system length, $D\sim L^{1.05}$. This short time behavior is consistent with particle-based simulations. The long-time diffusion coefficient scales like $D\sim L^{1.6}$, close to previous studies which found $D\sim L^{1.5}$. Furthermore, we show that the near-field details of the interaction kernel do not affect the short time behavior but qualitatively and dramatically affect the long time behavior, potentially causing a saturation of the mean-squared displacement at long times. Our finding of a $D\sim L^{1.05}$ short time scaling resolves a long standing puzzle about the disagreement between the diffusion coefficient measured in particle-based models and mesoscale lattice models of amorphous plasticity.

Grains in crystalline materials usually grow with increased thermal exposure. Classical phenomena such as recrystallization may lead to a purely temporary decrease in the grain size, while recent advances in alloy design can yield thermally stable nanocrystalline materials in which grain growth stagnates. But grains never shrink, since there is a lack of interface-generating mechanisms at high temperatures, which are required to decrease the grain size if such was the system’s thermodynamic tendency. Here we sidestep this paradigm by designing a nanocrystalline alloy having an allotropic phase transformation—an interface-generating mechanism—such that only the high-temperature phase is stabilized against grain growth. We demonstrate that for an Fe-Au alloy cycled through the $\alpha \leftrightarrow \gamma$ transformation, the high-temperature phase ($\gamma \text{−}\mathrm{Fe}$) has a stable fine grain size, smaller than its low-temperature counterpart ($\alpha \text{−}\mathrm{Fe}$). The result is an unusual material in which an increase in temperature leads to finer grains that are stable in size.

We report a method for quantitative phase recovery and simultaneous electron energy loss spectroscopy analysis using ptychographic reconstruction of a data set of “hollow” diffraction patterns. This has the potential for recovering both structural and chemical information at atomic resolution with a new generation of detectors.

Twisted bilayer graphene has recently attracted a lot of attention for its rich electronic properties and tunability. Here we show that for very small twist angles, $\alpha \ll 1°$, the application of a perpendicular electric field is mathematically equivalent to a new kind of artificial gauge field. This identification opens the door for the generation and detection of pseudo-Landau levels in graphene platforms within robust setups, which do not depend on strain engineering and therefore can be realistically harvested for technological applications. Furthermore, this new artificial gauge field leads to the development of highly localized modes associated with flat bands close to charge neutrality, which form an emergent kagome lattice in real space. Our findings indicate that for tiny angles biased twisted bilayer graphene is a promising platform that can realize frustrated lattices of highly localized states, opening a new direction for the investigation of strongly correlated phases of matter.

We consider the effect of coupling between phonons and a chiral Majorana edge in a gapped chiral spin liquid with Ising anyons (e.g., Kitaev’s non-Abelian spin liquid on the honeycomb lattice). This is especially important in the regime in which the longitudinal bulk heat conductivity ${\kappa }_{xx}$ due to phonons is much larger than the expected quantized thermal Hall conductance ${\kappa }_{xy}^q=(\pi T/12)(k_B^2/\hslash )$ of the ideal isolated edge mode, so that the thermal Hall angle, i.e., the angle between the thermal current and the temperature gradient, is small. By modeling the interaction between a Majorana edge and bulk phonons, we show that the exchange of energy between the two subsystems leads to a transverse component of the bulk current and thereby an effective Hall conductivity. Remarkably, the latter is equal to the quantized value when the edge and bulk can thermalize, which occurs for a Hall bar of length $L\gg \ell$, where $\ell$ is a thermalization length. We obtain $\ell \sim T^{-5}$ for a model of the Majorana-phonon coupling. We also find that the quality of the quantization depends on the means of measuring the temperature and, surprisingly, a more robust quantization is obtained when the lattice, not the spin, temperature is measured. We present general hydrodynamic equations for the system, detailed results for the temperature and current profiles, and an estimate for the coupling strength and its temperature dependence based on a microscopic model Hamiltonian. Our results may explain recent experiments observing a quantized thermal Hall conductivity in the regime of small Hall angle, ${\kappa }_{xy}/{\kappa }_{xx}\sim {10}^{-3}$, in $\alpha \text{−}{\mathrm{RuCl}}_3$.

Biological systems are equipped with a diverse repertoire of proteins that regulate DNA topology with precision that is beyond the reach of conventional polymer chemistry. Here, we harness the unique properties of topoisomerases to synthesize Olympic hydrogels formed by topologically interlinked DNA rings. Using dynamic light scattering microrheology to probe the viscoelasticity of DNA topological networks, we show that topoisomerase II enables the facile preparation of active, adenosine triphosphate–driven Olympic hydrogels that can be switched between liquid and solid states on demand. Our results provide a versatile system for engineering switchable topological materials that may be broadly leveraged to model the impact of topological constraints and active dynamics in the physics of chromosomes and other polymeric materials.

Mesoscopic spin ensembles coupled to a cavity offer the exciting prospect of observing complex nonclassical phenomena that pool the microscopic features from a few spins with those of macroscopic spin ensembles. Here, we demonstrate how the collective interactions in an ensemble of as many as a hundred spins can be harnessed to obtain a periodic pulse train of nonclassical light. To unravel the full quantum dynamics and photon statistics, we develop a time-adaptive variational renormalization group method that accurately captures the underlying Lindbladian dynamics of the mesoscopic spin-cavity system.

The spin structure of the valence and conduction bands at the $\overline{K}$ and ${\overline{K}}^{\prime }$ valleys of single-layer ${\mathrm{WS}}_2$ on Au(111) is determined by spin- and angle-resolved photoemission and inverse photoemission. The bands confining the direct band gap of 1.98 eV are out-of-plane spin polarized with spin-dependent energy splittings of 417 meV in the valence band and 16 meV in the conduction band. The sequence of the spin-split bands is the same in the valence and in the conduction bands and opposite at the $\overline{K}$ and the ${\overline{K}}^{\prime }$ high-symmetry points. The first observation explains “dark” excitons discussed in optical experiments; the latter points to coupled spin and valley physics in electron transport. The experimentally observed band dispersions are discussed along with band structure calculations for a freestanding single layer and for a single layer on Au(111).

Using ultrafast $\simeq 2.5\mathrm{fs}$ and $\simeq 25\mathrm{fs}$ self-amplified spontaneous emission pulses of increasing intensity and a novel experimental scheme, we report the concurrent increase of stimulated emission in the forward direction and loss of out-of-beam diffraction contrast for a $\mathrm{Co}/\mathrm{Pd}$ multilayer sample. The experimental results are quantitatively accounted for by a statistical description of the pulses in conjunction with the optical Bloch equations. The dependence of the stimulated sample response on the incident intensity, coherence time, and energy jitter of the employed pulses reveals the importance of increased control of x-ray free electron laser radiation.

Although discussions of structural phase transitions in prototypical ferroelectric systems with the perovskite structure, such as ${\mathrm{BaTiO}}_3$ and ${\mathrm{PbTiO}}_3$, started almost seventy years ago, an atomic-level description of the polar characteristics as a function of temperature, pressure, and composition remains topical. Here we provide a novel quantitative description of the temperature-driven local structural correlations in ${\mathrm{PbTiO}}_3$ via the development of characteristic relative cationic shifts. The results give new insights into the phase transition beyond those reliant on the long-range order. The ferroelectric-to-paraelectric transition of ${\mathrm{PbTiO}}_3$ is realized by the extent of a stochastic polarization instability driven by a progressive misalignment instead of a complete disappearance of the local dipoles, which further suggests that such polarization instability is chemically induced at the morphotropic phase boundary of ${\mathrm{PbTiO}}_3$-based solid solutions with giant piezoelectric effect. As such, our results not only identify the evolving atomistic disorder in a perovskite-based ferroelectric system, but also suggest that polarization instability can serve as a generic fingerprint for phase transitions as well as for better understanding structure-property relationships in ${\mathrm{PbTiO}}_3$-based ferroelectric solid solutions.

The hypothesis that many living systems should exhibit near-critical behavior is well motivated theoretically, and an increasing number of cases have been demonstrated empirically. However, a systematic analysis across biological networks, which would enable identification of the network properties that drive criticality, has not yet been realized. Here, we provide a first comprehensive survey of criticality across a diverse sample of biological networks, leveraging a publicly available database of 67 Boolean models of regulatory circuits. We find all 67 networks to be near critical. By comparing to ensembles of random networks with similar topological and logical properties, we show that criticality in biological networks is not predictable solely from macroscale properties such as mean degree $⟨K⟩$ and mean bias in the logic functions $⟨p⟩$, as previously emphasized in theories of random Boolean networks. Instead, the ensemble of real biological circuits is jointly constrained by the local causal structure and logic of each node. In this way, biological regulatory networks are more distinguished from random networks by their criticality than by other macroscale network properties such as degree distribution, edge density, or fraction of activating conditions.

We demonstrate that a summing up series of Feynman diagrams can yield unbiased accurate results for strongly correlated fermions even when the convergence radius vanishes. We consider the unitary Fermi gas, a model of nonrelativistic fermions in three-dimensional continuous space. Diagrams are built from partially dressed or fully dressed propagators of single particles and pairs. The series is resummed by a conformal-Borel transformation that incorporates the large-order behavior and the analytic structure in the Borel plane, which are found by the instanton approach. We report highly accurate numerical results for the equation of state in the normal unpolarized regime, and reconcile experimental data with the theoretically conjectured fourth virial coefficient.

A key quantity in strongly interacting resonant Fermi gases is the contact $\mathcal{C}$, which characterizes numerous properties such as the momentum distribution at large momenta or the pair correlation function at short distances. The temperature dependence of $\mathcal{C}$ was measured at unitarity, where existing theoretical predictions differ substantially even at the qualitative level. We report accurate data for the contact and the momentum distribution of the unitary gas in the normal phase, obtained by bold diagrammatic Monte Carlo and Borel resummation. Our results agree with experimental data within error bars and provide crucial benchmarks for the development of advanced theoretical treatments and precision measurements.

We identify precision limits for the simultaneous estimation of multiple parameters in multimode interferometers. Quantum strategies to enhance the multiparameter sensitivity are based on entanglement among particles, modes, or combining both. The maximum attainable sensitivity of particle-separable states defines the multiparameter shot-noise limit, which can be surpassed without mode entanglement. Further enhancements up to the multiparameter Heisenberg limit are possible by adding mode entanglement. Optimal strategies that saturate the precision bounds are provided.

The prime candidate sources for the upcoming space-borne gravitational wave (GW) observatory LISA are the numerous Galactic tight binaries of white dwarfs (WDs) and neutron stars (NSs), many of which will coalesce and undergo mass transfer, leading to simultaneous emission of x rays and GWs. Here, detailed and coherent numerical stellar models are explored for the formation and evolution of these systems, including finite-temperature effects and complete calculations of mass transfer from a WD to a NS accretor. Evolutionary tracks of characteristic strain amplitude are computed, and the unique pattern of their evolution in the GW frequency–dynamical chirp mass parameter space enables a firm identification of the nature of the systems. Furthermore, it is demonstrated that a precise detection of the chirp allows determination of the NS mass to an accuracy of a few percent; with applications to constraining its equation of state, in particular for dual-line GW sources observed simultaneously at high and low frequencies.

We present experimental evidence of photon droplets in an attractive (focusing) nonlocal nonlinear medium. Photon droplets are self-bound, finite-sized states of light that are robust to size and shape perturbations due to a balance of competing attractive and repulsive forces. It has recently been shown theoretically, via a multipole expansion of the nonlocal nonlinearity, that the self-bound state arises due to competition between the $s$-wave and $d$-wave nonlinear terms, together with diffraction. The theoretical photon droplet framework encompasses both a solitonlike stationary ground state and the nonsolitonlike dynamics that ensue when the system is displaced from equilibrium, i.e., driven into an excited state. We present numerics and experiments supporting the existence of these photon droplet states and measurements of the dynamical evolution of the photon droplet orbital angular momentum.

We report the first experimental observation of the time-driven phase transition in a canonical quantum chaotic system, the quantum kicked rotor. The transition bears a firm analogy to a thermodynamic phase transition, with the time mimicking the temperature and the quantum expectation of the rotor’s kinetic energy mimicking the free energy. The transition signals a sudden change in the system’s memory behavior: before the critical time, the system undergoes chaotic motion in phase space and its memory of initial states is erased in the course of time; after the critical time, quantum interference enhances the probability for a chaotic trajectory to return to the initial state, and thus the system’s memory is recovered.