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Correlations Enable Lossless Ergotropy Transport
Phys. Rev. Lett. 134, 010408 – Published 7 January, 2025
DOI: https://doi.org/10.1103/PhysRevLett.134.010408
Abstract
“A battery powers a device” can be read as “work stored in the battery is being transported to the device.” In quantum batteries, the total amount of stored work can be measured by ergotropy, which is the maximal work extractable by unitary operations. Transporting ergotropy is fundamentally different from transporting energy, and here we find that ergotropy can be gained even when the transmission channel is strictly energy conserving. We show that, generically, ergotropy transport is lossy whenever the two systems start uncorrelated. In contrast, for a large class of correlated initial states, transport can be gainful. Furthermore, a single correlated state can be used multiple times, allowing to transport without losses an order of magnitude more work than the battery capacity. Correlations are thus a useful resource for ergotropy transport, and we quantify how this resource is consumed during gainful transport.
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References (99)
- R. Alicki and M. Fannes, Entanglement boost for extractable work from ensembles of quantum batteries, Phys. Rev. E 87, 042123 (2013).
- M. Perarnau-Llobet, K. V. Hovhannisyan, M. Huber, P. Skrzypczyk, N. Brunner, and A. Acín, Extractable work from correlations, Phys. Rev. X 5, 041011 (2015).
- G. M. Andolina, M. Keck, A. Mari, M. Campisi, V. Giovannetti, and M. Polini, Extractable work, the role of correlations, and asymptotic freedom in quantum batteries, Phys. Rev. Lett. 122, 047702 (2019).
- S. Tirone, R. Salvia, S. Chessa, and V. Giovannetti, Quantum work capacitances: Ultimate limits for energy extraction on noisy quantum batteries, SciPost Phys. 17, 041 (2024).
- X. Yang, Y.-H. Yang, M. Alimuddin, R. Salvia, S.-M. Fei, L.-M. Zhao, S. Nimmrichter, and M.-X. Luo, Battery capacity of energy-storing quantum systems, Phys. Rev. Lett. 131, 030402 (2023).
- K. V. Hovhannisyan, M. Perarnau-Llobet, M. Huber, and A. Acín, Entanglement generation is not necessary for optimal work extraction, Phys. Rev. Lett. 111, 240401 (2013).
- F. C. Binder, S. Vinjanampathy, K. Modi, and J. Goold, Quantacell: Powerful charging of quantum batteries, New J. Phys. 17, 075015 (2015).
- F. Campaioli, F. A. Pollock, F. C. Binder, L. Céleri, J. Goold, S. Vinjanampathy, and K. Modi, Enhancing the charging power of quantum batteries, Phys. Rev. Lett. 118, 150601 (2017).
- D. Ferraro, M. Campisi, G. M. Andolina, V. Pellegrini, and M. Polini, High-power collective charging of a solid-state quantum battery, Phys. Rev. Lett. 120, 117702 (2018).
- J.-Y. Gyhm, D. Šafránek, and D. Rosa, Quantum charging advantage cannot be extensive without global operations, Phys. Rev. Lett. 128, 140501 (2022).
- J.-Y. Gyhm and U. R. Fischer, Beneficial and detrimental entanglement for quantum battery charging, AVS Quantum Sci. 6, 012001 (2024).
- A. C. Santos, B. Çakmak, S. Campbell, and N. T. Zinner, Stable adiabatic quantum batteries, Phys. Rev. E 100, 032107 (2019).
- D. Farina, G. M. Andolina, A. Mari, M. Polini, and V. Giovannetti, Charger-mediated energy transfer for quantum batteries: An open-system approach, Phys. Rev. B 99, 035421 (2019).
- F. Barra, Dissipative charging of a quantum battery, Phys. Rev. Lett. 122, 210601 (2019).
- J. Liu, D. Segal, and G. Hanna, Loss-free excitonic quantum battery, J. Phys. Chem. C 123, 18303 (2019).
- F. Pirmoradian and K. Mølmer, Aging of a quantum battery, Phys. Rev. A 100, 043833 (2019).
- K. V. Hovhannisyan, F. Barra, and A. Imparato, Charging assisted by thermalization, Phys. Rev. Res. 2, 033413 (2020).
- S. Gherardini, F. Campaioli, F. Caruso, and F. C. Binder, Stabilizing open quantum batteries by sequential measurements, Phys. Rev. Res. 2, 013095 (2020).
- J. Q. Quach and W. J. Munro, Using dark states to charge and stabilize open quantum batteries, Phys. Rev. Appl. 14, 024092 (2020).
- F. H. Kamin, F. T. Tabesh, S. Salimi, F. Kheirandish, and A. C. Santos, Non-Markovian effects on charging and self-discharging process of quantum batteries, New J. Phys. 22, 083007 (2020).
- F. Barra, K. V. Hovhannisyan, and A. Imparato, Quantum batteries at the verge of a phase transition, New J. Phys. 24, 015003 (2022).
- W.-L. Song, H.-B. Liu, B. Zhou, W.-L. Yang, and J.-H. An, Remote charging and degradation suppression for the quantum battery, Phys. Rev. Lett. 132, 090401 (2024).
- F. Campaioli, S. Gherardini, J. Q. Quach, M. Polini, and G. M. Andolina, Colloquium: Quantum batteries, Rev. Mod. Phys. 96, 031001 (2024).
- J. Monsel, M. Fellous-Asiani, B. Huard, and A. Auffèves, The energetic cost of work extraction, Phys. Rev. Lett. 124, 130601 (2020).
- S. Tirone, R. Salvia, and V. Giovannetti, Quantum energy lines and the optimal output ergotropy problem, Phys. Rev. Lett. 127, 210601 (2021).
- M. Łobejko, P. Mazurek, and M. Horodecki, The asymptotic emergence of the second law for a repeated charging process, arXiv:2209.05339.
- D. Gelbwaser-Klimovsky, R. Alicki, and G. Kurizki, Work and energy gain of heat-pumped quantized amplifiers, Europhys. Lett. 103, 60005 (2013).
- W. Niedenzu, D. Gelbwaser-Klimovsky, A. G. Kofman, and G. Kurizki, On the operation of machines powered by quantum non-thermal baths, New J. Phys. 18, 083012 (2016).
- S. Seah, S. Nimmrichter, and V. Scarani, Work production of quantum rotor engines, New J. Phys. 20, 043045 (2018).
- W. Niedenzu, M. Huber, and E. Boukobza, Concepts of work in autonomous quantum heat engines, Quantum 3, 195 (2019).
- B. Çakmak, Ergotropy from coherences in an open quantum system, Phys. Rev. E 102, 042111 (2020).
- S. Seah, M. Perarnau-Llobet, G. Haack, N. Brunner, and S. Nimmrichter, Quantum speed-up in collisional battery charging, Phys. Rev. Lett. 127, 100601 (2021).
- A. E. Allahverdyan, R. Balian, and T. M. Nieuwenhuizen, Maximal work extraction from finite quantum systems, Europhys. Lett. 67, 565 (2004).
- M. H. Partovi, Quantum thermodynamics, Phys. Lett. A 137, 440 (1989).
- A. B. Brailovskii, V. L. Vaks, and V. V. Mityugov, Quantum models of relaxation, Phys. Usp. 39, 745 (1996).
- D. Janzing, P. Wocjan, R. Zeier, R. Geiss, and T. Beth, Thermodynamic cost of reliability and low temperatures: Tightening Landauer’s principle and the second law, Int. J. Theor. Phys. 39, 2717 (2000).
- F. G. S. L. Brandão, M. Horodecki, J. Oppenheim, J. M. Renes, and R. W. Spekkens, Resource theory of quantum states out of thermal equilibrium, Phys. Rev. Lett. 111, 250404 (2013).
- G. Chiribella and Y. Yang, Optimal quantum operations at zero energy cost, Phys. Rev. A 96, 022327 (2017).
- J. Åberg, Catalytic coherence, Phys. Rev. Lett. 113, 150402 (2014).
- J. A. Vaccaro, S. Croke, and S. M. Barnett, Is coherence catalytic?, J. Phys. A 51, 414008.
- M. P. Woods, R. Silva, and J. Oppenheim, Autonomous quantum machines and finite-sized clocks, Ann. Henri Poincaré 20, 125 (2019).
- M. H. Partovi, Entanglement versus stosszahlansatz: Disappearance of the thermodynamic arrow in a high-correlation environment, Phys. Rev. E 77, 021110 (2008).
- D. Jennings and T. Rudolph, Entanglement and the thermodynamic arrow of time, Phys. Rev. E 81, 061130 (2010).
- S. Jevtic, D. Jennings, and T. Rudolph, Maximally and minimally correlated states attainable within a closed evolving system, Phys. Rev. Lett. 108, 110403 (2012).
- I. Henao and R. M. Serra, Role of quantum coherence in the thermodynamics of energy transfer, Phys. Rev. E 97, 062105 (2018).
- G. M. Andolina, D. Farina, A. Mari, V. Pellegrini, V. Giovannetti, and M. Polini, Charger-mediated energy transfer in exactly solvable models for quantum batteries, Phys. Rev. B 98, 205423 (2018).
- P. Lipka-Bartosik, G. F. Diotallevi, and P. Bakhshinezhad, Fundamental limits on anomalous energy flows in correlated quantum systems, Phys. Rev. Lett. 132, 140402 (2024).
- M. Łobejko, P. Mazurek, and M. Horodecki, Thermodynamics of minimal coupling quantum heat engines, Quantum 4, 375 (2020).
- T. Biswas, M. Łobejko, P. Mazurek, K. Jałowiecki, and M. Horodecki, Extraction of ergotropy: Free energy bound and application to open cycle engines, Quantum 6, 841 (2022).
- A. Mukherjee, A. Roy, S. S. Bhattacharya, and M. Banik, Presence of quantum correlations results in a nonvanishing ergotropic gap, Phys. Rev. E 93, 052140 (2016).
- M. Alimuddin, T. Guha, and P. Parashar, Bound on ergotropic gap for bipartite separable states, Phys. Rev. A 99, 052320 (2019).
- K. Sen and U. Sen, Local passivity and entanglement in shared quantum batteries, Phys. Rev. A 104, L030402 (2021).
- S. Puliyil, M. Banik, and M. Alimuddin, Thermodynamic signatures of genuinely multipartite entanglement, Phys. Rev. Lett. 129, 070601 (2022).
- W. Pusz and S. L. Woronowicz, Passive states and KMS states for general quantum systems, Commun. Math. Phys. 58, 273 (1978).
- A. Lenard, Thermodynamical proof of the Gibbs formula for elementary quantum systems, J. Stat. Phys. 19, 575 (1978).
- See Supplemental Material at http://link.aps.org/supplemental/10.1103/PhysRevLett.134.010408, which includes Refs. [57–82], for further details on the relation of ergotropy transport with quantum marginal problem, specifics of our numerical simulations, proof of concentration bounds for and , numerics for higher-dimensional systems, bounds on for two qubits, and calculations for the multiple transport scenario.
- V. Trávníček, K. Bartkiewicz, A. Černoch, and K. Lemr, Experimental measurement of the Hilbert–Schmidt distance between two-qubit states as a means for reducing the complexity of machine learning, Phys. Rev. Lett. 123, 260501 (2019).
- N. Liu and P. Wittek, Vulnerability of quantum classification to adversarial perturbations, Phys. Rev. A 101, 062331 (2020).
- M. Cerezo, A. Arrasmith, R. Babbush, S. C. Benjamin, S. Endo, K. Fujii, J. R. McClean, K. Mitarai, X. Yuan, L. Cincio, and P. J. Coles, Variational quantum algorithms, Nat. Rev. Phys. 3, 625 (2021).
- V. V. Dodonov, O. V. Man’ko, V. I. Man’ko, and A. Wünsche, Hilbert–Schmidt distance and non-classicality of states in quantum optics, J. Mod. Opt. 47, 633 (2000).
- P. Pandya, O. Sakarya, and M. Wieśniak, Hilbert–Schmidt distance and entanglement witnessing, Phys. Rev. A 102, 012409 (2020).
- D. Pérez-García, M. M. Wolf, D. Petz, and M. B. Ruskai, Contractivity of positive and trace-preserving maps under norms, J. Math. Phys. (N.Y.) 47, 083506 (2006).
- M. Ozawa, Entanglement measures and the Hilbert–Schmidt distance, Phys. Lett. A 268, 158 (2000).
- F. Mezzadri, How to generate random matrices from the classical compact groups, Not. Am. Math. Soc. 54, 592 (2007).
- D. Bures, An extension of Kakutani’s theorem on infinite product measures to the tensor product of semifinite -algebras, Trans. Am. Math. Soc. 135, 199 (1969).
- A. Uhlmann, The “transition probability” in the state space of a -algebra, Rep. Math. Phys. 9, 273 (1976).
- D. Petz, Monotone metrics on matrix spaces, Linear Algebra Appl. 244, 81 (1996).
- S. L. Braunstein and C. M. Caves, Statistical distance and the geometry of quantum states, Phys. Rev. Lett. 72, 3439 (1994).
- S.-i. Amari and H. Nagaoka, Methods of Information Geometry (Oxford University Press, New York, 2000).
- D. Petz and C. Sudár, Geometries of quantum states, J. Math. Phys. (N.Y.) 37, 2662 (1996).
- H.-J. Sommers and K. Życzkowski, Bures volume of the set of mixed quantum states, J. Phys. A 36, 10083 (2003).
- P. B. Slater, Quantum Fisher–Bures information of two-level systems and a three-level extension, J. Phys. A 29, L271 (1996).
- P. B. Slater, Comparative noninformativities of quantum priors based on monotone metrics, Phys. Lett. A 247, 1 (1998).
- J. Dittmann, On the Riemannian metric on the space of density matrices, Rep. Math. Phys. 36, 309 (1995).
- M. J. W. Hall, Random quantum correlations and density operator distributions, Phys. Lett. A 242, 123 (1998).
- A. Sarkar and S. Kumar, Bures–Hall ensemble: Spectral densities and average entropies, J. Phys. A 52, 295203 (2019).
- P. B. Slater, Numerical and exact analyses of Bures and Hilbert–Schmidt separability and PPT probabilities, Quantum Inf. Process. 18, 312 (2019).
- L. Wei and N. Witte, Quantum interpolating ensemble: Bi-orthogonal polynomials and average entropies, Random Matrices Theory Appl. 12, 2250055 (2023).
- A. R. Willms, Uniform sampling on the standard simplex, Missouri J. Math. Sci. 33, 119 (2021).
- L. Devroye, Non-Uniform Random Variate Generation (Springer-Verlag, New York, 1986).
- A. Edelman and N. R. Rao, Random matrix theory, Acta Numerica 14, 233 (2005).
- G. T. Toussaint, Solving geometric problems with the rotating calipers, in Proceedings of the MELECON’83, Athens, Greece (1983).
- R. Horodecki, P. Horodecki, M. Horodecki, and K. Horodecki, Quantum entanglement, Rev. Mod. Phys. 81, 865 (2009).
- P. Horodecki, Separability criterion and inseparable mixed states with positive partial transposition, Phys. Lett. A 232, 333 (1997).
- M. A. Nielsen and I. L. Chuang, Quantum Computation and Quantum Information (Cambridge University Press, Cambridge, England, 2010).
- V. D. Milman and G. Schechtman, Asymptotic Theory of Finite Dimensional Normed Spaces, Lecture Notes in Mathematics Vol. 1200 (Springer, Berlin, 2001).
- J. Watrous, The Theory of Quantum Information (Cambridge University Press, Cambridge, England, 2018).
- I. Bengtsson and K. Życzkowski, Geometry of Quantum States: An Introduction to Quantum Entanglement (Cambridge University Press, New York, 2006).
- K. Życzkowski and H.-J. Sommers, Induced measures in the space of mixed quantum states, J. Phys. A 34, 7111 (2001).
- P. Sekatski, J.-D. Bancal, X. Valcarce, E. Y.-Z. Tan, R. Renner, and N. Sangouard, Device-independent quantum key distribution from generalized CHSH inequalities, Quantum 5, 444 (2021).
- K. V. Hovhannisyan, R. P. A. Simon, and J. Anders, Concentration of ergotropy in many-body systems, arXiv:2412.19801.
- M. Huber, M. Perarnau-Llobet, K. V. Hovhannisyan, P. Skrzypczyk, C. Klöckl, N. Brunner, and A. Acín, Thermodynamic cost of creating correlations, New J. Phys. 17, 065008 (2015).
- M. N. Bera, A. Riera, M. Lewenstein, and A. Winter, Generalized laws of thermodynamics in the presence of correlations, Nat. Commun. 8, 2180 (2017).
- G. Vitagliano, C. Klöckl, M. Huber, and N. Friis, Trade-off between work and correlations in quantum thermodynamics, in Thermodynamics in the Quantum Regime (Springer International Publishing, New York, 2018), pp. 731–750.
- F. Bakhshinezhad, F. Clivaz, G. Vitagliano, P. Erker, A. Rezakhani, M. Huber, and N. Friis, Thermodynamically optimal creation of correlations, J. Phys. A 52, 465303 (2019).
- B. Dakić, V. Vedral, and Č. Brukner, Necessary and sufficient condition for nonzero quantum discord, Phys. Rev. Lett. 105, 190502 (2010).
- S. Bravyi, Requirements for compatibility between local and multipartite quantum states, Quantum Inf. Comput. 4, 12 (2004).
- A. A. Klyachko, Quantum marginal problem and N-representability, J. Phys. Conf. Ser. 36, 72 (2006).
- M. Christandl and G. Mitchison, The spectra of quantum states and the Kronecker coefficients of the symmetric group, Commun. Math. Phys. 261, 789 (2005).