Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Dynamics of Superconducting Pairs in the Two-Dimensional Hubbard Model

G. Sordi1,*, E. M. O’Callaghan1, C. Walsh1, M. Charlebois2, P. Sémon3, and A.-M. S. Tremblay3

  • *Contact author: giovanni.sordi@rhul.ac.uk

Phys. Rev. Lett. 136, 256503 – Published 24 June, 2026

DOI: https://doi.org/10.1103/22h2-jxh4

Abstract

The frequency structure of the superconducting correlations in cuprates gives insights on the pairing mechanism. Here we present an exhaustive study of this problem in the two-dimensional Hubbard model with cellular dynamical mean-field theory. To this end, we systematically quantify the dependence on doping δ and interaction strength U of the superconducting gap, of the frequency scales where d-wave pairing occurs, and of their relative contribution to pairing. For all values of U and δ, we find pair-forming processes confined to frequencies set by the superexchange interaction and followed by pair-breaking processes, ruling out both pair-forming and pair-breaking processes on the scale of U. This suggests that at high frequencies, the effect of U is eliminated by the d-wave paring, and that at small frequencies, U generates the superexchange interaction that leads to low-frequency pair-forming processes providing the net contribution to pairing.

View figure in article

Physics Subject Headings (PhySH)

Article Text

Supplemental Material

References (64)

  1. M. R. Norman, The challenge of unconventional superconductivity, Science 332, 196 (2011).
  2. D. J. Scalapino, A common thread: The pairing interaction for unconventional superconductors, Rev. Mod. Phys. 84, 1383 (2012).
  3. B. Keimer, S. A. Kivelson, M. R. Norman, S. Uchida, and J. Zaanen, From quantum matter to high-temperature superconductivity in copper oxides, Nature (London) 518, 179 (2015).
  4. E. van Heumen, E. Muhlethaler, A. B. Kuzmenko, H. Eisaki, W. Meevasana, M. Greven, and D. van der Marel, Optical determination of the relation between the electron-boson coupling function and the critical temperature in high-Tc cuprates, Phys. Rev. B 79, 184512 (2009).
  5. J. P. Carbotte, T. Timusk, and J. Hwang, Bosons in high-temperature superconductors: An experimental survey, Rep. Prog. Phys. 74, 066501 (2011).
  6. S. D. Conte, C. Giannetti, G. Coslovich, F. Cilento, D. Bossini, T. Abebaw, F. Banfi, G. Ferrini, H. Eisaki, M. Greven, A. Damascelli, D. van der Marel, and F. Parmigiani, Disentangling the electronic and phononic glue in a high-Tc superconductor, Science 335, 1600 (2012).
  7. F. Cilento, S. D. Conte, G. Coslovich, F. Banfi, G. Ferrini, H. Eisaki, M. Greven, A. Damascelli, D. v. d. Marel, F. Parmigiani, and C. Giannetti, In search for the pairing glue in cuprates by non-equilibrium optical spectroscopy, J. Phys. Conf. Ser. 449, 012003 (2013).
  8. S. Dal Conte et al., Snapshots of the retarded interaction of charge carriers with ultrafast fluctuations in cuprates, Nat. Phys. 11, 421 (2015).
  9. P. W. Anderson, Is there glue in cuprate superconductors?, Science 316, 1705 (2007).
  10. C. Weber, K. Haule, and G. Kotliar, Strength of correlations in electron- and hole-doped cuprates, Nat. Phys. 6, 574 (2010).
  11. C. Weber, C. Yee, K. Haule, and G. Kotliar, Scaling of the transition temperature of hole-doped cuprate superconductors with the charge-transfer energy, Europhys. Lett. 100, 37001 (2012).
  12. S. Acharya, C. Weber, E. Plekhanov, D. Pashov, A. Taraphder, and M. Van Schilfgaarde, Metal-insulator transition in copper oxides induced by apex displacements, Phys. Rev. X 8, 021038 (2018).
  13. B. Bacq-Labreuil, B. Lacasse, A.-M. S. Tremblay, D. Sénéchal, and K. Haule, Toward an ab initio theory of high-temperature superconductors: A study of multilayer cuprates, Phys. Rev. X 15, 021071 (2025).
  14. Z.-H. Cui, J. Yang, J. Tölle, H.-Z. Ye, S. Yuan, H. Zhai, G. Park, R. Kim, X. Zhang, L. Lin, T. C. Berkelbach, and G. K.-L. Chan, Ab initio quantum many-body description of superconducting trends in the cuprates, Nat. Commun. 16, 1845 (2025).
  15. F. Boschini, M. Zonno, and A. Damascelli, Time-resolved ARPES studies of quantum materials, Rev. Mod. Phys. 96, 015003 (2024).
  16. A. F. Kemper, F. Goto, H. A. Labib, N. Gauthier, E. H. da Silva Neto, and F. Boschini, Observing two-electron interactions with correlation-ARPES, Phys. Rev. B 112, 035168 (2025).
  17. T. P. Devereaux, M. Claassen, X.-X. Huang, M. Zaletel, J. E. Moore, D. Morr, F. Mahmood, P. Abbamonte, and Z.-X. Shen, Angle-resolved pair photoemission theory for correlated electrons, Phys. Rev. B 108, 165134 (2023).
  18. C. Stahl and M. Eckstein, Noise correlations in time- and angle-resolved photoemission spectroscopy, Phys. Rev. B 99, 241111(R) (2019).
  19. Y. Su and C. Zhang, Coincidence angle-resolved photoemission spectroscopy: Proposal for detection of two-particle correlations, Phys. Rev. B 101, 205110 (2020).
  20. P. W. Anderson, The resonating valence bond state in La2CuO4 and superconductivity, Science 235, 1196 (1987).
  21. A.-M. S. Tremblay, Strongly correlated superconductivity, in Emergent Phenomena in Correlated Matter Modeling and Simulation, edited by E. Pavarini, E. Koch, and U. Schollwöck (Verlag des Forschungszentrum, Jülich, 2013), Vol. 3, Chap. 10.
  22. P. Morel and P. W. Anderson, Calculation of the superconducting state parameters with retarded electron-phonon interaction, Phys. Rev. 125, 1263 (1962).
  23. G. Kotliar and J. Liu, Superexchange mechanism and d-wave superconductivity, Phys. Rev. B 38, 5142 (1988).
  24. T. A. Maier, M. Jarrell, T. Pruschke, and M. H. Hettler, Quantum cluster theories, Rev. Mod. Phys. 77, 1027 (2005).
  25. A.-M. S. Tremblay, B. Kyung, and D. Sénéchal, Pseudogap and high-temperature superconductivity from weak to strong coupling. Towards a quantitative theory, Low Temp. Phys. 32, 424 (2006).
  26. M. Qin, T. Schäfer, S. Andergassen, P. Corboz, and E. Gull, The Hubbard model: A computational perspective, Annu. Rev. Condens. Matter Phys. 13, 275 (2022).
  27. G. Kotliar, S. Y. Savrasov, K. Haule, V. S. Oudovenko, O. Parcollet, and C. A. Marianetti, Electronic structure calculations with dynamical mean-field theory, Rev. Mod. Phys. 78, 865 (2006).
  28. A. Georges, G. Kotliar, W. Krauth, and M. J. Rozenberg, Dynamical mean-field theory of strongly correlated fermion systems and the limit of infinite dimensions, Rev. Mod. Phys. 68, 13 (1996).
  29. T. A. Maier, D. Poilblanc, and D. J. Scalapino, Dynamics of the pairing interaction in the Hubbard and t−J models of high-temperature superconductors, Phys. Rev. Lett. 100, 237001 (2008).
  30. B. Kyung, D. Sénéchal, and A.-M. S. Tremblay, Pairing dynamics in strongly correlated superconductivity, Phys. Rev. B 80, 205109 (2009).
  31. M. Civelli, Evolution of the dynamical pairing across the phase diagram of a strongly correlated high-temperature superconductor, Phys. Rev. Lett. 103, 136402 (2009).
  32. D. Sénéchal, A. G. R. Day, V. Bouliane, and A.-M. S. Tremblay, Resilience of d-wave superconductivity to nearest-neighbor repulsion, Phys. Rev. B 87, 075123 (2013).
  33. E. Gull and A. J. Millis, Pairing glue in the two-dimensional Hubbard model, Phys. Rev. B 90, 041110(R) (2014).
  34. A. Reymbaut, M. Charlebois, M. F. Asiani, L. Fratino, P. Sémon, G. Sordi, and A.-M. S. Tremblay, Antagonistic effects of nearest-neighbor repulsion on the superconducting pairing dynamics in the doped Mott insulator regime, Phys. Rev. B 94, 155146 (2016).
  35. X. Dong, L. Del Re, A. Toschi, and E. Gull, Mechanism of superconductivity in the Hubbard model at intermediate interaction strength, Proc. Natl. Acad. Sci. U.S.A. 119, e2205048119 (2022).
  36. X. Dong, E. Gull, and A. J. Millis, Quantifying the role of antiferromagnetic fluctuations in the superconductivity of the doped Hubbard model, Nat. Phys. 18, 1293 (2022).
  37. K. Haule, Quantum Monte Carlo impurity solver for cluster dynamical mean-field theory and electronic structure calculations with adjustable cluster base, Phys. Rev. B 75, 155113 (2007).
  38. P. Werner, A. Comanac, L. de Medici, M. Troyer, and A. J. Millis, Continuous-time solver for quantum impurity models, Phys. Rev. Lett. 97, 076405 (2006).
  39. E. Gull, A. J. Millis, A. I. Lichtenstein, A. N. Rubtsov, M. Troyer, and P. Werner, Continuous-time Monte Carlo methods for quantum impurity models, Rev. Mod. Phys. 83, 349 (2011).
  40. P. Sémon, C.-H. Yee, K. Haule, and A.-M. S. Tremblay, Lazy skip-lists: An algorithm for fast hybridization-expansion quantum Monte Carlo, Phys. Rev. B 90, 075149 (2014).
  41. P. Sémon, G. Sordi, and A.-M. S. Tremblay, Ergodicity of the hybridization-expansion Monte Carlo algorithm for broken-symmetry states, Phys. Rev. B 89, 165113 (2014).
  42. S. Sakai, Nonperturbative calculations for spectroscopic properties of cuprate high-temperature superconductors, J. Phys. Soc. Jpn. 92, 092001 (2023).
  43. J. Liu, D.-X. Yao, and W. Wu, Interplay between the pseudogap and superconductivity in doped Mott insulators: A cluster dynamical mean-field theory study, Chin. Phys. Lett. 42, 080711 (2025).
  44. S. S. Kancharla, B. Kyung, D. Sénéchal, M. Civelli, M. Capone, G. Kotliar, and A.-M. S. Tremblay, Anomalous superconductivity and its competition with antiferromagnetism in doped Mott insulators, Phys. Rev. B 77, 184516 (2008).
  45. K. Haule and G. Kotliar, Strongly correlated superconductivity: A plaquette dynamical mean-field theory study, Phys. Rev. B 76, 104509 (2007).
  46. G. Sordi, P. Sémon, K. Haule, and A.-M. S. Tremblay, Strong coupling superconductivity, pseudogap, and Mott transition, Phys. Rev. Lett. 108, 216401 (2012).
  47. L. Fratino, P. Sémon, G. Sordi, and A.-M. S. Tremblay, An organizing principle for two-dimensional strongly correlated superconductivity, Sci. Rep. 6, 22715 (2016).
  48. C.-D. Hébert, P. Sémon, and A.-M. S. Tremblay, Superconducting dome in doped quasi-two-dimensional organic Mott insulators: A paradigm for strongly correlated superconductivity, Phys. Rev. B 92, 195112 (2015).
  49. D. Sénéchal, P.-L. Lavertu, M.-A. Marois, and A.-M. S. Tremblay, Competition between antiferromagnetism and superconductivity in high-Tc cuprates, Phys. Rev. Lett. 94, 156404 (2005).
  50. M. Civelli, M. Capone, A. Georges, K. Haule, O. Parcollet, T. D. Stanescu, and G. Kotliar, Nodal-antinodal dichotomy and the two gaps of a superconducting doped Mott insulator, Phys. Rev. Lett. 100, 046402 (2008).
  51. C. Walsh, M. Charlebois, P. Sémon, A.-M. S. Tremblay, and G. Sordi, Superconductivity in the two-dimensional Hubbard model with cellular dynamical mean-field theory: A quantum impurity model analysis, Phys. Rev. B 108, 075163 (2023).
  52. F. Carbone, A. B. Kuzmenko, H. J. A. Molegraaf, E. van Heumen, V. Lukovac, F. Marsiglio, D. van der Marel, K. Haule, G. Kotliar, H. Berger, S. Courjault, P. H. Kes, and M. Li, Doping dependence of the redistribution of optical spectral weight in Bi2Sr2CaCu2O8+δ, Phys. Rev. B 74, 064510 (2006).
  53. C. Walsh, M. Charlebois, P. Sémon, G. Sordi, and A.-M. S. Tremblay, Information-theoretic measures of superconductivity in a two-dimensional doped Mott insulator, Proc. Natl. Acad. Sci. U.S.A. 118, e2104114118 (2021).
  54. D. Bergeron and A.-M. S. Tremblay, Algorithms for optimized maximum entropy and diagnostic tools for analytic continuation, Phys. Rev. E 94, 023303 (2016).
  55. A. Reymbaut, D. Bergeron, and A.-M. S. Tremblay, Maximum entropy analytic continuation for spectral functions with nonpositive spectral weight, Phys. Rev. B 92, 060509(R) (2015).
  56. See Supplemental Material at http://link.aps.org/supplemental/10.1103/22h2-jxh4 for the calculation of Aan(ω) by performing only a single analytical continuation, the consistency checks for Aan(ω), extended data for Anor(ω), Aan(ω), IF(ω), and the computation of Aan(t) in the time domain.
  57. This neglects Kosterlitz-Thouless physics.

  58. C. Walsh, P. Sémon, D. Poulin, G. Sordi, and A.-M. S. Tremblay, Thermodynamic and information-theoretic description of the Mott transition in the two-dimensional Hubbard model, Phys. Rev. B 99, 075122 (2019).
  59. A. Paramekanti, M. Randeria, and N. Trivedi, High- Tc superconductors: A variational theory of the superconducting state, Phys. Rev. B 70, 054504 (2004).
  60. E. Gull, O. Parcollet, and A. J. Millis, Superconductivity and the pseudogap in the two-dimensional Hubbard model, Phys. Rev. Lett. 110, 216405 (2013).
  61. J. A. Sobota, Y. He, and Z.-X. Shen, Angle-resolved photoemission studies of quantum materials, Rev. Mod. Phys. 93, 025006 (2021).
  62. G. Sordi, K. Haule, and A.-M. S. Tremblay, Finite doping signatures of the Mott transition in the two-dimensional Hubbard model, Phys. Rev. Lett. 104, 226402 (2010).
  63. G. Sordi, K. Haule, and A.-M. S. Tremblay, Mott physics and first-order transition between two metals in the normal-state phase diagram of the two-dimensional Hubbard model, Phys. Rev. B 84, 075161 (2011).
  64. G. Sordi, P. Sémon, K. Haule, and A.-M. S. Tremblay, Pseudogap temperature as a Widom line in doped Mott insulators, Sci. Rep. 2, 547 (2012).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation