High-order perturbative ab initio calculations are challenging due to the rapidly growing configuration space and the difficulty of assessing convergence. In this letter, we introduce perturbation theory quantum Monte Carlo (PTQMC), a stochastic approach designed to compute high-order many-body perturbative corrections. By representing the perturbative wave function with random walkers in configuration space, PTQMC avoids the exponential scaling inherent to conventional constructions of high-rank excitation operators. Benchmark calculations for the Richardson pairing model demonstrate that PTQMC accurately reproduces exact many-body perturbation theory (MBPT) coefficients up to 16th order, even in strongly divergent regimes. We further show that combining PTQMC with series resummation techniques yields stable and precise energy estimates in cases where the straightforward perturbative series fails. Finally, we propose the effective number of configurations, $e^S$, as a global measure of perturbative wave-function complexity that can be directly extracted within PTQMC. We demonstrate that the saturation behavior of $e^S$ provides a more reliable indicator of the validity of perturbative expansions than energy convergence alone.

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• Ab initio calculations
• Nuclear many-body theory
• Quantum Monte Carlo