Nucleon effective masses in neutron-rich matter are studied with the relativistic Brueckner-Hartree-Fock (RBHF) theory in the full Dirac space. The neutron and proton effective masses for symmetric nuclear matter are 0.80 times rest mass, which agrees well with the empirical values. In neutron-rich matter, the effective mass of the neutron is found to be larger than that of the proton, and the neutron-proton effective mass splittings at the empirical saturation density are predicted as $0.187\alpha$ with $\alpha$ being the isospin asymmetry parameter. The result is compared to other ab initio calculations and is consistent with the constraints from the nuclear reaction and structure measurements, such as the nucleon-nucleus scattering, the giant resonances of ${}^{208}\mathrm{Pb}$, and the Hugenholtz–Van Hove theorem with systematics of nuclear symmetry energy and its slope. The predictions of the neutron-proton effective mass splitting from the RBHF theory in the full Dirac space might be helpful to constrain the isovector parameters in phenomenological density functionals.

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• Nuclear matter
• Isospin violation
• Mass
• Ab initio calculations