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    Multiple charge density wave ordering and quantum coupling of collective excitations in layered GdTe3

    Divya Rawat1, Prabir Dutta2, Devesh Negi3, Ivy Maria2, Surajit Saha3, Kanishka Biswas2, and Ajay Soni1,*

    • *Contact author: ajay@iitmandi.ac.in

    Phys. Rev. B 110, 075155 – Published 27 August, 2024

    DOI: https://doi.org/10.1103/PhysRevB.110.075155

    Abstract

    Rare-earth tritellurides represent quasi-two-dimensional systems that exhibit multiple charge density wave (CDW) transitions alongside magnetic ordering. However, the interplay between the phonon dynamics of collective excitations and local magnetism remains unclear. GdTe3 is an interesting material having an incommensurate CDW (ICDW), at TICDW∼380 K, an antiferromagnetic transition at TN∼13 K, and with an expectation of another CDW ordering. We emphasize electron-spin-phonon and mode coupling in GdTe3 through temperature dependent Raman spectroscopy complemented by heat capacity and magnetization measurements. Disappearance of zone-folded mode (Z*) and observed coupling behavior of amplitude mode suggest the existence of another ordering at ∼240 K, in addition to known ICDW. By employing phonon renormalization, we estimated significant strength of spin-phonon coupling, (λs−ph∼0.234) and accentuated on the phonon dynamics associated with CDW instabilities in GdTe3.

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