• Accepted Paper

Photoemission tomography of excitons: Momentum-space signatures of correlated electron-hole wave functions

Siegfried Kaidisch, Amir Kleiner, Sivan Refaely-Abramson, Peter Puschnig, and Christian S. Kern

Phys. Rev. B - Accepted 3 September, 2026

DOI: https://doi.org/10.1103/z2w9-2q3c

Abstract

The momentum-space signatures of excitons can be experimentally accessed through time-resolved (pump-probe) photoelectron spectroscopy. In this work, we develop a computational framework for exciton photoemission orbital tomography (exPOT) in periodic systems, enabling the simulation and interpretation of experimental observables within many-body perturbation theory. By connecting the GW+Bethe-Salpeter equation (BSE) approach to photoemission tomography, our formalism captures exciton photoemission in periodic systems, explicitly incorporating photoemission matrix element effects induced by the light-matter interaction via the probe pulse. The correlated nature of electrons and holes introduces distinct consequences for excitonic photoemission. Using the prototypical two-dimensional material hexagonal boron nitride, we demonstrate these effects, including a dependence of the photoemission angular distribution on the pump pulse polarization. Moreover, our framework extends to excitons with finite center-of-mass momentum, making it well-suited to studying momentum-dark excitons. This provides valuable insights into the microscopic nature of excitonic phenomena in quantum materials.

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