• Accepted Paper

Anisotropic spin correlations and single-ion anisotropy in triangular lattice KBaGd(BO3)2 probed by electron spin resonance

Y. C. Huo, Y. J. Chen, Z. R. Li, W. J. Zhang, J. J. Cao, L. Wang, C. W. Hou, L. L. Song, Z. X. Wang, Z. C. Xia, H. Nojiri, W. Tong, and Z. W. Ouyang

Phys. Rev. B - Accepted 16 October, 2026

DOI: https://doi.org/10.1103/lhj7-vqvw

Abstract

We present a systematic investigation into the magnetic anisotropy of triangular-lattice KBaGd(BO3)2, a high- performance magnetic refrigeration candidate, utilizing magnetic characterization and electron spin resonance (ESR) techniques. KBaGd(BO3)2 exhibits an easy-plane magnetic anisotropy, and the anisotropic shift behavior of the resonance field at low temperatures was observed from temperature-dependent ESR, which is attributed to the collective resonance mode associated with anisotropic spin correlations. To probe the single-ion properties of Gd[3+], we performed measurements on magnetically diluted system KBaGd0.005Y0.995(BO3)2, which successfully revealed an easy-plane single-ion anisotropy arising from the crystal electric field effect. The anisotropy parameter for Gd[3+] was determined to be D = 0.053 K, with its energy scale comparable to antiferromagnetic exchange interaction and dipole-dipole interaction. This strongly suggests that the magnetism of in KBaGd(BO3)2 is collectively determined by the interplay of antiferromagnetic exchange, dipole-dipole interaction, and the easy-plane single-ion anisotropy.

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