• Accepted Paper

Rare-earth tuning of magnetic entropy and interaction scales in K3L(PO4)2 (L=Yb, Gd) for adiabatic demagnetization refrigeration

Yonglin Wang, Chuandi Zhang, Jianglong Zhang, Zihang Gao, Ziqi Li, Feiran Shen, Lunhua He, Peijie Sun, Hao Deng, Junsen Xiang, and Wentao Jin

Phys. Rev. B - Accepted 30 September, 2026

DOI: https://doi.org/10.1103/gnh9-srtk

Abstract

Adiabatic demagnetization refrigeration (ADR) based on frustrated rare-earth magnets provides a promising route toward helium-free sub-Kelvin cooling, while balancing magnetic entropy and interaction scales is essential for optimizing the ADR functionalities. Here we investigate the low-temperature magnetic and ADR properties of the alkali rare-earth double phosphates K3Ln(PO4)2 (Ln = Yb, Gd), which crystallize in a monoclinic P21/m structure containing distorted isosceles triangular lattices of rare-earth ions. Magnetization and specific heat measurements confirm the absence of long-range magnetic ordering down to 0.1~K in both compounds. Direct quasi-ADR measurements demonstrate strongly contrasting refrigeration behaviors: K3Yb(PO4)2 reaches a minimum temperature of 29.8~mK from an initial state of 2~K and 6~T, whereas K3Gd(PO4)2 exhibits extended hold times below 150~mK associated with its larger magnetic entropy reservoir. Crystal-electric-field calculation confirms a Jeff=1/2 ground-state doublet in K3Yb(PO4)2, while thermodynamic analysis based on magnetic entropy and interaction scales accounts for the distinct ADR performance of the two compounds. These results identify K3Ln(PO4)2 as a chemically robust platform for rare-earth-tunable solid-state ADR.

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