- Accepted Paper
Rare-earth tuning of magnetic entropy and interaction scales in K(PO) (=Yb, Gd) for adiabatic demagnetization refrigeration
Phys. Rev. B - Accepted 30 September, 2026
DOI: https://doi.org/10.1103/gnh9-srtk
Phys. Rev. B - Accepted 30 September, 2026
DOI: https://doi.org/10.1103/gnh9-srtk
Adiabatic demagnetization refrigeration (ADR) based on frustrated rare-earth magnets provides a promising route toward helium-free sub-Kelvin cooling, while balancing magnetic entropy and interaction scales is essential for optimizing the ADR functionalities. Here we investigate the low-temperature magnetic and ADR properties of the alkali rare-earth double phosphates K(PO) ( = Yb, Gd), which crystallize in a monoclinic structure containing distorted isosceles triangular lattices of rare-earth ions. Magnetization and specific heat measurements confirm the absence of long-range magnetic ordering down to 0.1~K in both compounds. Direct quasi-ADR measurements demonstrate strongly contrasting refrigeration behaviors: KYb(PO) reaches a minimum temperature of 29.8~mK from an initial state of 2~K and 6~T, whereas KGd(PO) exhibits extended hold times below 150~mK associated with its larger magnetic entropy reservoir. Crystal-electric-field calculation confirms a ground-state doublet in KYb(PO), while thermodynamic analysis based on magnetic entropy and interaction scales accounts for the distinct ADR performance of the two compounds. These results identify K(PO) as a chemically robust platform for rare-earth-tunable solid-state ADR.
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