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    First-principles prediction of a multiferroic semiconductor with switchable spin-polarized Berry curvature dipole: PbMnO3:PbVO3

    Arpita Paul

    Umesh V. Waghmare*

    • *Contact author: waghmare@jncasr.ac.in

    Phys. Rev. B 113, 214114 – Published 24 June, 2026

    DOI: https://doi.org/10.1103/zmr8-mb6k

    Abstract

    With first-principles theoretical and symmetry analysis, we establish that (PbMnO3)1/(PbVO3)1 superlattice is a multiferroic with coexisting ferromagnetism, ferroelectricity, and Berry curvature dipole. Transfer of electronic charge from V4+ to Mn4+ is shown to drive (a) polar (Γ5− symmetry) distortion dominated by V5+ (d0) displacements, and (b) Jahn-Teller distortion of Mn3+O6 octahedra to open up a gap. Berry curvature and associated spin-polarized Berry curvature dipole are of magnitude comparable to that of Weyl semimetals composed of heavy elements with strong spin-orbit coupling. Integrating Berry curvature dipole with magnetoelectric multiferroic behavior of the heterostructure PbMnO3:PbVO3 gives a combination of magnetoelectric coupling and electrically switchable anomalous Hall effects. The sign and spin-polarization of dc nonlinear transverse Hall voltage, generated by a longitudinal ac electric field, encodes nonvolatile four-state memory in a Hall device, making it useful for oxide electronics and spintronics.

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