The electronic structure of semiconducting 2D materials such as transition metal dichalcogenides (TMDs) is known to be tunable by its environment, from simple external fields applied with electrical contacts up to complex van der Waals heterostructure assemblies. However, conventional alloying from reference binary TMD compounds to composition-controlled ternary alloys also offers unexplored opportunities. In this work, we use nano-angle resolved photoemission spectroscopy (nano-ARPES) and density functional theory (DFT) calculations to study the structural and electronic properties of different alloy compositions of bulk $\mathrm{W}{\mathrm{S}}_{2(1-x)}\mathrm{S}{\mathrm{e}}_{2x}$. Our results demonstrate the continuous variation of the band structure and the progressive evolution of the valence band splitting at the K points from 420 to 520 meV in bulk $\mathrm{W}{\mathrm{S}}_{2(1-x)}\mathrm{S}{\mathrm{e}}_{2x}$. We also carried out scanning tunneling microscopy (STM) measurements and DFT to understand the possible S or Se substitutions variants in $\mathrm{W}{\mathrm{S}}_{2(1-x)}\mathrm{S}{\mathrm{e}}_{2x}$ alloys, with different local atomic configurations. Our work opens up perspectives for the fine control of the band dispersion in van der Waals materials and demonstrates how the band structure can be tuned in bulk TMDs. The collected information can serve as a reference for future applications.

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• Electronic structure
• Surfaces
• Transition metal dichalcogenides
• Angle-resolved photoemission spectroscopy
• Scanning tunneling microscopy