- Open Access
Optimization of path-integral tensor-multiplication schemes for open quantum systems
Phys. Rev. B 114, 125302 – Published 4 August, 2026
DOI: https://doi.org/10.1103/ycrc-vtbk
Abstract
Path-integral techniques are a powerful tool for obtaining exact solutions for the non-Markovian dynamics of open quantum systems. However, the exponential scaling of the tensor size with the quantum memory length limits their applicability to systems with long memory times. Here we provide a general optimization of tensor multiplication schemes for systems with pair correlations and finite memory times. This optimization effectively reduces the tensor sizes by using a matrix representation of tensors combined with singular value decomposition to filter out negligible contributions. This approach dramatically reduces both computational time and memory usage of the traditional tensor-multiplication schemes. While more memory-efficient representations exist, this approach enables a consistent extrapolation scheme for the rapid estimation of the exact value. As a demonstration, we apply it to the Trotter decomposition with linked cluster expansion technique and use it to investigate a quantum dot-microcavity system at large coupling strengths. We also apply the optimization in a case where the memory time is very long—specifically in a system containing two spatially separated quantum dots in a common phonon bath.
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References (58)
- H.-P. Breuer and F. Petruccione, The Theory of Open Quantum Systems (Oxford University Press, Oxford, 2002).
- I. de Vega and D. Alonso, Dynamics of non-Markovian open quantum systems, Rev. Mod. Phys. 89, 015001 (2017).
- H.-P. Breuer, E.-M. Laine, J. Piilo, and B. Vacchini, Colloquium: Non-Markovian dynamics in open quantum systems, Rev. Mod. Phys. 88, 021002 (2016).
- B. Krummheuer, V. M. Axt, and T. Kuhn, Theory of pure dephasing and the resulting absorption line shape in semiconductor quantum dots, Phys. Rev. B 65, 195313 (2002).
- U. Hohenester, A. Laucht, M. Kaniber, N. Hauke, A. Neumann, A. Mohtashami, M. Seliger, M. Bichler, and J. J. Finley, Phonon-assisted transitions from quantum dot excitons to cavity photons, Phys. Rev. B 80, 201311(R) (2009).
- E. Stock, M.-R. Dachner, T. Warming, A. Schliwa, A. Lochmann, A. Hoffmann, A. I. Toropov, A. K. Bakarov, I. A. Derebezov, M. Richter, V. A. Haisler, A. Knorr, and D. Bimberg, Acoustic and optical phonon scattering in a single In(Ga)As quantum dot, Phys. Rev. B 83, 041304(R) (2011).
- D. E. Reiter, T. Kuhn, and V. M. Axt, Distinctive characteristics of carrier-phonon interactions in optically driven semiconductor quantum dots, Adv. Phys.: X 4, 1655478 (2019).
- P. Kaer, T. R. Nielsen, P. Lodahl, A.-P. Jauho, and J. Mørk, Non-Markovian model of photon-assisted dephasing by electron-phonon interactions in a coupled quantum-dot–cavity system, Phys. Rev. Lett. 104, 157401 (2010).
- A. Nazir and D. P. S. McCutcheon, Modelling exciton–phonon interactions in optically driven quantum dots, J. Phys.: Condens. Matter 28, 103002 (2016).
- S. Hughes, P. Yao, F. Milde, A. Knorr, D. Dalacu, K. Mnaymneh, V. Sazonova, P. J. Poole, G. C. Aers, J. Lapointe, R. Cheriton, and R. L. Williams, Influence of electron-acoustic phonon scattering on off-resonant cavity feeding within a strongly coupled quantum-dot cavity system, Phys. Rev. B 83, 165313 (2011).
- A. Morreau, C. Joshi, and E. A. Muljarov, Phonon-induced dephasing in quantum dot-cavity QED: Limitations of the polaron master equation, arXiv:2002.01912.
- R. P. Feynman, A. R. Hibbs, and D. F. Styer, Quantum Mechanics and Path Integrals (Dover, Mineola, NY, 2010).
- D. E. Makarov and N. Makri, Path integrals for dissipative systems by tensor multiplication. Condensed phase quantum dynamics for arbitrarily long time, Chem. Phys. Lett. 221, 482 (1994).
- N. Makri and D. E. Makarov, Tensor propagator for iterative quantum time evolution of reduced density matrices. I. Theory, J. Chem. Phys. 102, 4600 (1995).
- N. Makri and D. E. Makarov, Tensor propagator for iterative quantum time evolution of reduced density matrices. II. Numerical methodology, J. Chem. Phys. 102, 4611 (1995).
- N. Makri, Numerical path integral techniques for long time dynamics of quantum dissipative systems, J. Math. Phys. 36, 2430 (1995).
- J. Shao and N. Makri, Iterative path integral calculation of quantum correlation functions for dissipative systems, Chem. Phys. 268, 1 (2001).
- J. Shao and N. Makri, Iterative path integral formulation of equilibrium correlation functions for quantum dissipative systems, J. Chem. Phys. 116, 507 (2002).
- H. F. Trotter, On the product of semi-groups of operators, Proc. Am. Math. Soc. 10, 545 (1959).
- M. Suzuki, Generalized Trotter's formula and systematic approximants of exponential operators and inner derivations with applications to many-body problems, Commun. Math. Phys. 51, 183 (1976).
- A. Morreau and E. A. Muljarov, Phonon-induced dephasing in quantum-dot–cavity QED, Phys. Rev. B 100, 115309 (2019).
- P. Nalbach, A. Ishizaki, G. R. Fleming, and M. Thorwart, Iterative path-integral algorithm versus cumulant time-nonlocal master equation approach for dissipative biomolecular exciton transport, New J. Phys. 13, 063040 (2011).
- M. C. Goorden, M. Thorwart, and M. Grifoni, Entanglement spectroscopy of a driven solid-state qubit and its detector, Phys. Rev. Lett. 93, 267005 (2004).
- M. Thorwart, E. Paladino, and M. Grifoni, Dynamics of the spin-boson model with a structured environment, Chem. Phys. 296, 333 (2004).
- M. Thorwart, J. Eckel, and E. R. Mucciolo, Non-Markovian dynamics of double quantum dot charge qubits due to acoustic phonons, Phys. Rev. B 72, 235320 (2005).
- E. Sim and N. Makri, Filtered propagator functional for iterative dynamics of quantum dissipative systems, Comput. Phys. Commun. 99, 335 (1997).
- E. Sim, Quantum dynamics for a system coupled to slow baths: On-the-fly filtered propagator method, J. Chem. Phys. 115, 4450 (2001).
- R. Lambert and N. Makri, Memory propagator matrix for long-time dissipative charge transfer dynamics, Mol. Phys. 110, 1967 (2012).
- L. Liu, J. Ren, and W. Fang, Improved memory truncation scheme for quasi-adiabatic propagator path integral via influence functional renormalization, J. Chem. Phys. 161, 084101 (2024).
- N. Makri, Blip decomposition of the path integral: Exponential acceleration of real-time calculations on quantum dissipative systems, J. Chem. Phys. 141, 134117 (2014).
- N. Makri, Iterative blip-summed path integral for quantum dynamics in strongly dissipative environments, J. Chem. Phys. 146, 134101 (2017).
- P. Nalbach, D. Braun, and M. Thorwart, Exciton transfer dynamics and quantumness of energy transfer in the Fenna-Matthews-Olson complex, Phys. Rev. E 84, 041926 (2011).
- D. Gribben, A. Strathearn, J. Iles-Smith, D. Kilda, A. Nazir, B. W. Lovett, and P. Kirton, Exact quantum dynamics in structured environments, Phys. Rev. Res. 2, 013265 (2020).
- L. M. J. Hall, L. S. Sirkina, A. Morreau, W. Langbein, and E. A. Muljarov, Controlling dephasing of coupled qubits via shared bath coherence, Phys. Rev. B 112, 045303 (2025).
- M. Cygorek, A. M. Barth, F. Ungar, A. Vagov, and V. M. Axt, Nonlinear cavity feeding and unconventional photon statistics in solid-state cavity QED revealed by many-level real-time path-integral calculations, Phys. Rev. B 96, 201201(R) (2017).
- N. Makri, Small matrix path integral for system-bath dynamics, J. Chem. Theory Comput. 16, 4038 (2020).
- A. M. Barth, A. Vagov, and V. M. Axt, Path integral description of combined Hamiltonian and non-Hamiltonian dynamics in quantum dissipative system, Phys. Rev. B 94, 125439 (2016).
- M. Richter and B. P. Fingerhut, Coarse-grained representation of the quasi adiabatic propagator path integral for the treatment of non-Markovian long-time bath memory, J. Chem. Phys. 146, 214101 (2017).
- V. Link, H.-H. Tu, and W. T. Strunz, Open quantum system dynamics from infinite tensor network contraction, Phys. Rev. Lett. 132, 200403 (2024).
- A. Strathearn, P. Kirton, D. Kilda, J. Keeling, and B. W. Lovett, Efficient non-Markovian quantum dynamics using time-evolving matrix product operators, Nat. Commun. 9, 3322 (2018).
- G. E. Fux, P. Fowler-Wright, J. Beckles, E. P. Butler, P. R. Eastham, D. Gribben, J. Keeling, D. Kilda, P. Kirton, E. D. C. Lawrence, B. W. Lovett, E. O'Neill, A. Strathearn, and R. de Wit, OQuPy: A Python package to efficiently simulate non-Markovian open quantum systems with process tensors, J. Chem. Phys. 161, 124108 (2024).
- M. Richter and S. Hughes, Enhanced TEMPO algorithm for quantum path integrals with off-diagonal system-bath coupling: Applications to photonic quantum networks, Phys. Rev. Lett. 128, 167403 (2022).
- M. R. Jørgensen and F. A. Pollock, Exploiting the causal tensor network structure of quantum processes to efficiently simulate non-Markovian path integrals, Phys. Rev. Lett. 123, 240602 (2019).
- M. Cygorek and E. M. Gauger, ACE: A general-purpose non-Markovian open quantum systems simulation toolkit based on process tensors, J. Chem. Phys. 161, 074111 (2024).
- L. S. Sirkina and E. A. Muljarov, Impact of the phonon environment on the nonlinear quantum-dot–cavity QED: Path-integral approach, Phys. Rev. B 108, 115312 (2023).
- L. S. Sirkina, L. M. J. Hall, A. Morreau, W. Langbein, and E. A. Muljarov, Förster transfer between quantum dots in a shared phonon environment: An exact approach, revealing the role of pure dephasing, arXiv:2509.15418.
- E. V. Denning, M. Bundgaard-Nielsen, and J. Mørk, Optical signatures of electron-phonon decoupling due to strong light-matter interactions, Phys. Rev. B 102, 235303 (2020).
- G. D. Mahan, Many-Particle Physics (Springer US, Boston, MA, 2000).
- A. W. Chin, J. Prior, R. Rosenbach, F. Caycedo-Soler, S. F. Huelga, and M. B. Plenio, The role of non-equilibrium vibrational structures in electronic coherence and recoherence in pigment–protein complexes, Nat. Phys. 9, 113 (2013).
- M. D. Rey, A. W. Chin, S. F. Huelga, and M. B. Plenio, Exploiting structured environments for efficient energy transfer: The phonon antenna mechanism, J. Phys. Chem. Lett. 4, 903 (2013).
- A. Blais, R.-S. Huang, A. Wallraff, S. M. Girvin, and R. J. Schoelkopf, Cavity quantum electrodynamics for superconducting electrical circuits: An architecture for quantum computation, Phys. Rev. A 69, 062320 (2004).
- H. Zheng and H. U. Baranger, Persistent quantum beats and long-distance entanglement from waveguide-mediated interactions, Phys. Rev. Lett. 110, 113601 (2013).
- I. Yeo, P.-L. De Assis, A. Gloppe, E. Dupont-Ferrier, P. Verlot, N. S. Malik, E. Dupuy, J. Claudon, J.-M. Gérard, A. Auffèves, G. Nogues, S. Seidelin, J.-P. Poizat, O. Arcizet, and M. Richard, Strain-mediated coupling in a quantum dot–mechanical oscillator hybrid system, Nat. Nanotechnol. 9, 106 (2014).
- L. Childress, M. V. Gurudev Dutt, J. M. Taylor, A. S. Zibrov, F. Jelezko, J. Wrachtrup, P. R. Hemmer, and M. D. Lukin, Coherent dynamics of coupled electron and nuclear spin qubits in diamond, Science 314, 281 (2006).
- E. A. Muljarov and R. Zimmermann, Dephasing in quantum dots: Quadratic coupling to acoustic phonons, Phys. Rev. Lett. 93, 237401 (2004).
- E. A. Muljarov, T. Takagahara, and R. Zimmermann, Phonon-induced exciton dephasing in quantum dot molecules, Phys. Rev. Lett. 95, 177405 (2005).
- E. A. Zibik, T. Grange, B. A. Carpenter, R. Ferreira, G. Bastard, N. Q. Vinh, P. J. Phillips, M. J. Steer, M. Hopkinson, J. W. Cockburn, M. S. Skolnick, and L. R. Wilson, Intersublevel polaron dephasing in self-assembled quantum dots, Phys. Rev. B 77, 041307(R) (2008).
- L. M. J. Hall, A. Gisdakis, and E. A. Muljarov, Datasets for Figures 9–14, v1.0, Zenodo, 2026, https://doi.org/10.5281/zenodo.19957021.