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    Dispersive quasiparticles in the band gap of the intermetallic semiconductor FeGa3 due to an ordered secondary phase

    Quan Ren1,*, Ning Ding1,*, Ruoqi Wang1,*, Haonan Chen2,3, Wenting Lin1, Huayao Li1, Kaidi Xu1, Lulu Han1, Shanshan Wang1 et al.

    Si Zhang1, Guohua Wang4, Taishi Chen1, Cheng Zhang2,3, Xiaoqian Zhang1,†, Shuai Dong1,‡, and Lin Miao1,§

    • 1Key Laboratory of Quantum Materials and Devices of Ministry of Education, School of Physics, Southeast University, Nanjing 211189, China
    • 2State Key Laboratory of Surface Physics and Institute for Nanoelectronic Devices and Quantum Computing, Fudan University, Shanghai 200433, China
    • 3Zhangjiang Fudan International Innovation Center, Fudan University, Shanghai 201210, China
    • 4School of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, China

    • *These authors contributed equally to this work.
    • †Contact author: xqzhang@seu.edu.cn
    • ‡Contact author: sdong@seu.edu.cn
    • §Contact author: lmiao@seu.edu.cn

    Phys. Rev. B 113, 195128 – Published 18 May, 2026

    DOI: https://doi.org/10.1103/xdvv-415q

    Abstract

    The narrow-gap semiconductor FeGa3 has attracted considerable attention due to its colossal thermoelectric Seebeck effect, intriguing magnetic anomaly, and quantum criticality. Although the quasiparticle excitations in the band gap have been probed and proposed to be directly associated with exotic characters of FeGa3, the physical origin of these in-gap states and their direct connection to either of these puzzling properties are under debate. Here, we report the discovery of the dispersive in-gap states in semiconducting FeGa3 through high-resolution angle-resolved photoemission spectroscopy. Combined with first-principles calculations and comprehensive analysis, the observed coherent in-gap states are tentatively identified as a manifestation of slightly off-stoichiometry induced ordered secondary phase, whose formula and exact lattice structure require further clarification. Notably, these dispersive in-gap states provide a consistent explanation for the exotic electronic and magnetic properties of FeGa3, establishing their origin in the previously overlooked secondary phase rather than in strong correlation effects or the trivial disorders.

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